Alkali metal salts
Ammonium salts
Nitrate salts
Halide salts
Sulfate salts
Frequently INSOLUBLE salts
Carbonate salts
Chromate salts
Phosphate salts
Fluoride salts
Largely INSOLUBLE salts
Silver salts
Hydroxide salts
Sulfide salts
The solubility of salts and minerals in aqueous solution
Largely SOLUBLE salts
Rule: Salts of Group I elements are soluble, including Li+, Na+, K+, Cs+, and Rb+.
Exceptions: Rare.
Rule: Salts containing ammonium ion (NH4+) are also soluble.
Rule: Salts containing nitrate ion (NO3-) are soluble.
Rule: Salts of Group VII elements are soluble, including Cl-, Br-, and I-.
Exceptions: Halide salts of silver, lead(II), and mercury(I) are insoluble, including AgCl, PbBr2, and Hg2Cl2.
Rule: Sulfate salts are soluble.
Exceptions: Sulfate salts BaSO4, PbSO4, Ag2SO4, and CaSO4 are insoluble.
Rule: Carbonates are frequently insoluble, including Group II carbonates CaCO3, SrCO3, and BaCO3 and others FeCO3 and PbCO3.
Rule: Chromate salts are frequently insoluble, including PbCrO4 and BaCrO4.
Exception: Group I chromate salts are soluble.
Rule: Phosphates are often frequently insoluble, including Ca3(PO4)2, Ag2PO4.
Rule: Fluoride salts are frequently insoluble, including BaF2, MgF2 and PbF2.
Exception: Group I fluoride salts are soluble.
Rule: Silver salts are insoluble.
Exceptions: Silver salts AgNO3 and Ag(C2H3O2) are soluble.
Rule I: Hydroxide salts of Group II elements are slightly soluble, including Ca(OH)2, Sr(OH)2, and Ba(OH)2.
Rule II: Hydroxide salts of transition metals are insoluble, including Fe(OH)3, Al(OH)3, and Co(OH)2.
Exceptions: Hydroxide salts of Group I elements are soluble.
Rule: Sulfide salts of transition metals are insoluble, including CdS, FeS, ZnS, Ag2S. Arsenic, antimony, bismuth, and lead sulfides are also insoluble.