Marking transitions in acid/base reactions


Three water soluble compounds used as indicators of transitions of hydrogen ion concentration in acid/base reactions are examined.

Ingredients: concentrated acid solution, concentrated base solution, phenolphthalein, thymol blue, phenol red

Procedure: A partial recipe follows.

1. Prepare solutions of distilled water and indicator, for each of the indicators.

2. Add drops of concentrated acid or base to each of the solutions.

3. Observe the color changes.

Understanding: The changes in hydrogen ion concentration are quantified using the concept of pH - the negative base ten logarithm of the molarity of the hydrogen ion concentration. A special set of chemical compounds called "indicators" can be used to visually indicate the transition in concentration of hydrogen ion in a solution. The special property of these molecules is that as the concentration of hydrogen ion changes, the molecules change their charged state, the wavelengths of light that they absorb, and the color of the solution. In the titration of solutions, the indicators are particularly helpful in marking the transition between one range of pH and another.

The range of transitions in pH for the various indicators are thymol blue, phenol red, and phenolphthalein. The ranges of transition vary widely.

      thymol blue           red   1.2-2.8  yellow  8.0-9.6   blue
      phenol red                    yellow     6.4-8.0   red     
      phenolphthalein                      clear     8.2     red
The wide variety of indicators provides many choices for the proper indicator of a transition between ranges of pH varying from the more acidic conditions, 1.2-2.8 for thymol blue, to the more basic conditions, 12.0-13.4 for trinitrobenzoic acid. For some reason, the names of indicators often appear in the "finals" of spelling bees (see image).

Universal indicators

Question: The juice of the red cabbage is a universal indicator that marks the general range of pH over a wide range of hydrogen ion concentration - from acidic to neutral to basic solutions. Why wouldn't one always select a general purpose universal indicator like red cabbage juice?