General and Quantitative Analytical Chemistry CH109

(Fall 2015)


Expect this course outline to evolve during the semester. Feel free to comment on those topics listed that are of particular interest. If a topic of interest does not appear on the outline, feel free to suggest it.


Quantum Mechanics of atoms and molecules [Chapter 1: The Quantum World]

2 and 4 September
Introduction to the course and a bit of background
Electromagnetic waves, particle waves and the Schrödinger Equation

9 and 11 September
Particle-in-a-box (energies and wave functions)
Particle-in-a-box (spectroscopy and applications)


Quantum Mechanics of atoms and molecules [Chapter 2: Quantum Mechanics in Action: Atoms]

14, 16 and 18 September
One electron atom (spectra and energies)
One electron atom (wave functions orbitals)

21 September
Multielectron atom (electron configurations)
Multielectron atom (periodic properties and the Periodic Table)


Building molecules from atoms (molecular physiology) [Chapter 3: Chemical Bonds]

23 and 25 September
More multielectron atoms and periodic properties
Ions and ionic bonds

28 September Exam #1

30 September
Covalent bonds and Lewis structures
Bond lengths, strengths and polarity


Quantum Mechanics of atoms and molecules [Chapter 4: Molecular Shape and Structure]

2 October
More Lewis structures, molecular shape and VSEPR

5 October
Valence bond theory

7 and 9 October
Molecular orbital theory (diatomic molecules)
Molecular orbital theory (polyatomic molecules)


Quantum Mechanics of atoms and molecules [Chapter 4: Molecular Shape and Structure]

9 October
IR and UV-vis spectroscopy and beyond


Building quantitative MACROSCOPIC models of gases [Chapter 5: The Properties of Gases]

13 October
Ideal gas law (equation of state and Absolute Zero of temperature)


Building quantitative MICROSCOPIC models of gases and liquids [Chapter 5: The Properties of Gases]

14, 16 and 19 October
Kinetic theory (mean speed, mean free path and collision frequency)
Diffusion and effusion

21 October Exam #2


Building quantitative MICROSCOPIC models of gases and liquids [Chapter 5: The Properties of Gases]

23 October
Keepin' it real (gases)


Character of interacting atoms and molecules (molecular psychology) [Chapter 6: Liquids and Solids]

26 and 28 October
Intermolecular forces


Chemical reactions and ``phases'' of matter (molecular sociology) [Chapter 6: Liquids and Solids]

28 October
Phases of matter and intermolecular forces
Hydrogen bonding and life on Earth


Exploring the Laws of Thermodynamics [Chapter 8: Thermodynamics - The First Law]

30 October, 2 and 4 November
Energy, heat and work
Enthalpy and calorimetry
Enthalpy and physical changes

6, 9 and 11 November
Heats of reaction, enthalpies of formation, thermodynamic cycles, and Hess's Law


Exploring the Laws of Thermodynamics [Chapter 9: Thermodynamics - The Second and Third Laws]

13 and 16 November
Entropy and physical changes
Entropy changes for ideal gas processes, heating and cooling, and phase changes

18 November Exam #3

20 November
Microscopic theory of entropy
Standard entropies and entropies of reaction

23 November
Entropy changes in the surroundings and overall


Exploring the Laws of Thermodynamics [Chapter 9: Thermodynamics - The Second and Third Laws]

30 November
Free energy
Thermodynamics and life on Earth ... and other Big Ideas


Properties of solutions and intermolecular interactions [Chapter 10: Physical Equilibria]

2, 4 and 7 December
Vapor pressure and intermolecular forces
Phase transitions and phase diagrams
Solubility and thermodynamics of solutions
Chromatography

9 December
Review of the semester

17 December Final Exam