ALS 98-10-2A
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba++ Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba++
Pk - Bg Intensities
BHVO 298.8 899459.4 24909.73 7035.14 293535.64 242725.79 108163.91 81906.93 580904.29 102204.37 15089 8783.23 10766.5 7674.49 3228.95 121082.7 5718.87 23417.75 6119.03 227.28 5142.9 33940.52 4135.81 13073.15 1851.05 644.26 1413.42 320 255.16 400.01 380.01 377.58 166.67 280 173.34 140 84.24 106.67 100 200 220 140 126.67 240 120 120 1,035.80
Sample 265.01 337419.2 14670.36 3897.42 216819.76 189877.78 52746.72 28299.78 303245.84 63771.97 7508.88 6652.58 9864.4 2760.36 4699.34 144967.79 4917.68 18366.77 9748.73 -1.67 7773.94 51864.89 6815.11 14609.35 1890.13 610.02 1250.06 200 163.34 341.67 211.67 300 211.67 170 101.67 211.67 10 90 50 170 300 770.03 720.03 1470.09 230 80 835
Sample 1 287.42 449507 20753.99 4818.35 284760.31 219729.12 52293.58 18149.89 437459.68 77892.78 9212.15 8305.21 23988.66 4538.1 6541.74 244511.49 5090.5 19239.1 18342.1 151.06 18683.46 115047.14 12780.84 33754.34 4002.05 1067.88 2636.62 428.68 337.77 365.04 537.78 563.65 328.68 327.28 218.18 163.64 100 45.45 27.27 254.55 500.01 509.11 354.56 881.9 300 163.64 1,445.60
Sample 2 268.14 118502.09 6532.96 1512.92 97679.72 85520.06 24348.36 9943.69 130670.78 23940 3341.52 1591.24 3722.66 1070.41 2524.54 59429.3 1822.13 7432.57 4219.52 120.88 2871.84 17610.33 3011.49 5593.84 849.49 284.62 520.89 128.57 98.9 114.29 220.88 92.31 28.57 114.29 28.57 85.71 20.88 42.86 28.57 100 171.43 2886.06 1957.29 4450.22 142.86 28.57 283.5
Sample 3 141.82 359734.36 16179.14 4572.05 201356.47 159749.78 47198.7 27081.26 313660.9 113873.97 7032.56 4902.28 6351.14 2779.69 3244.17 140201.57 3657.02 12500.87 7224.22 173.64 6350.1 41132.44 4966.54 11846.92 1791.07 602.75 1210.07 142.73 160.91 360.92 460.02 330.01 200 250 170 160 80 90 50 130 300 1510.13 930.04 2311.16 230 80 932.8
Sample 4 233.82 304240.87 13482.85 3078.04 182258.94 142519.33 35350.79 13535.22 303429.2 43276.86 4752.19 3494.92 2281.69 4167 9132.06 219335.15 5542.23 22389.73 21303.25 230.48 21920.97 138028.23 13024.51 34043.87 3865.81 1118.62 2079.69 305.72 320 453.34 599.54 446.68 186.67 300.01 126.67 153.33 80 86.67 60 233.34 713.36 133.33 46.67 226.67 380.01 233.34 1,636.30
Sample 5 362.83 351218.77 13959.42 3026.25 282095.38 228822.92 35703.04 4298.64 671543.13 64518.21 3705.63 2402.92 1428.32 4994.06 4911.94 288458.69 7196.25 19985.62 16243.67 178.85 28147.19 176572.98 16604.48 46224.09 5551.3 1652.69 3533.84 566.68 450.65 916.7 833.36 791.69 475.01 400.01 367.31 300 75 141.67 17.31 192.31 641.69 166.67 108.33 391.68 391.67 250 1,975.20
Sample 6 195.11 1138376.31 7772.46 1365.09 113025.12 99874.28 46226.3 86900.76 326878.7 90174.82 15029.74 13224.49 2948.01 3208.17 1972.91 84700.03 1681.94 7509.98 4740.04 -2.1 3273.18 24025.62 2936 9322.76 1101.45 309.8 528.68 127.27 118.18 130.07 181.82 109.09 81.82 145.46 63.64 72.73 36.36 18.18 45.45 109.09 209.09 27.27 27.27 63.64 163.64 63.64 361.5
Sample 7 232.06 292478.31 18275.18 3730.5 330448.16 243126.16 93462.52 12706.91 393441.94 74266.47 9766.91 6234.74 6242.61 4965.16 2423.35 249124.84 4398.29 15809.98 9570.47 223.08 12028.24 74620.46 7529.49 20461.62 2684.91 867.98 1483.41 200 333.34 292.31 350 483.35 208.98 175.64 233.34 150 33.33 100 42.31 166.67 450.01 616.69 483.35 1533.5 233.34 150 1,342.40
BHVO2 338.25 712628.95 19933.72 6372.74 215752.86 183290.42 82987.97 66793.57 430672.84 85834.53 11625.13 8129.53 8148.76 5467.51 2952.37 98770.47 4411.04 16138 4693.49 99.02 4060.94 29215.88 3439.18 11225.72 1615.3 519.62 1082.4 147.06 188.24 242.16 388.24 300 288.24 200 188.24 176.47 141.18 117.65 41.18 182.35 223.53 70.59 123.53 247.06 141.18 58.82 705.4
Normalized Pk Intensities Select Stds
BHVO 1 0.01 36.11 1 0.28 11.78 9.74 4.34 3.29 23.32 4.1 0.61 0.35 0.43 0.31 0.13 4.86 0.23 0.94 0.25 0.01 0.21 1.36 0.17 0.52 0.07 0.03 0.06 0.01 0.01 0.02 0.02 0.02 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0.01 0.01 0 0 0.0416
Sample 0.02 23 1 0.27 14.78 12.94 3.6 1.93 20.67 4.35 0.51 0.45 0.67 0.19 0.32 9.88 0.34 1.25 0.66 0 0.53 3.54 0.46 1 0.13 0.04 0.09 0.01 0.01 0.02 0.01 0.02 0.01 0.01 0.01 0.01 0 0.01 0 0.01 0.02 0.05 0.05 0.1 0.02 0.01 0.0569
Sample 1 0.01 21.66 1 0.23 13.72 10.59 2.52 0.87 21.08 3.75 0.44 0.4 1.16 0.22 0.32 11.78 0.25 0.93 0.88 0.01 0.9 5.54 0.62 1.63 0.19 0.05 0.13 0.02 0.02 0.02 0.03 0.03 0.02 0.02 0.01 0.01 0 0 0 0.01 0.02 0.02 0.02 0.04 0.01 0.01 0.0697
Sample 2 0.04 18.14 1 0.23 14.95 13.09 3.73 1.52 20 3.66 0.51 0.24 0.57 0.16 0.39 9.1 0.28 1.14 0.65 0.02 0.44 2.7 0.46 0.86 0.13 0.04 0.08 0.02 0.02 0.02 0.03 0.01 0 0.02 0 0.01 0 0.01 0 0.02 0.03 0.44 0.3 0.68 0.02 0 0.0434
Sample 3 0.01 22.23 1 0.28 12.45 9.87 2.92 1.67 19.39 7.04 0.43 0.3 0.39 0.17 0.2 8.67 0.23 0.77 0.45 0.01 0.39 2.54 0.31 0.73 0.11 0.04 0.07 0.01 0.01 0.02 0.03 0.02 0.01 0.02 0.01 0.01 0 0.01 0 0.01 0.02 0.09 0.06 0.14 0.01 0 0.0577
Sample 4 0.02 22.57 1 0.23 13.52 10.57 2.62 1 22.5 3.21 0.35 0.26 0.17 0.31 0.68 16.27 0.41 1.66 1.58 0.02 1.63 10.24 0.97 2.52 0.29 0.08 0.15 0.02 0.02 0.03 0.04 0.03 0.01 0.02 0.01 0.01 0.01 0.01 0 0.02 0.05 0.01 0 0.02 0.03 0.02 0.1214
Sample 5 0.03 25.16 1 0.22 20.21 16.39 2.56 0.31 48.11 4.62 0.27 0.17 0.1 0.36 0.35 20.66 0.52 1.43 1.16 0.01 2.02 12.65 1.19 3.31 0.4 0.12 0.25 0.04 0.03 0.07 0.06 0.06 0.03 0.03 0.03 0.02 0.01 0.01 0 0.01 0.05 0.01 0.01 0.03 0.03 0.02 0.1415
Sample 6 0.03 146.46 1 0.18 14.54 12.85 5.95 11.18 42.06 11.6 1.93 1.7 0.38 0.41 0.25 10.9 0.22 0.97 0.61 0 0.42 3.09 0.38 1.2 0.14 0.04 0.07 0.02 0.02 0.02 0.02 0.01 0.01 0.02 0.01 0.01 0 0 0.01 0.01 0.03 0 0 0.01 0.02 0.01 0.0465
Sample 7 0.01 16 1 0.2 18.08 13.3 5.11 0.7 21.53 4.06 0.53 0.34 0.34 0.27 0.13 13.63 0.24 0.87 0.52 0.01 0.66 4.08 0.41 1.12 0.15 0.05 0.08 0.01 0.02 0.02 0.02 0.03 0.01 0.01 0.01 0.01 0 0.01 0 0.01 0.02 0.03 0.03 0.08 0.01 0.01 0.0735
BHVO2 1 0.02 35.75 1 0.32 10.82 9.19 4.16 3.35 21.61 4.31 0.58 0.41 0.41 0.27 0.15 4.95 0.22 0.81 0.24 0 0.2 1.47 0.17 0.56 0.08 0.03 0.05 0.01 0.01 0.01 0.02 0.02 0.01 0.01 0.01 0.01 0.01 0.01 0 0.01 0.01 0 0.01 0.01 0.01 0 0.0354
Average Ratio (Standards) 0.01 35.93 1 0.3 11.3 9.47 4.25 3.32 22.46 4.2 0.59 0.38 0.42 0.29 0.14 4.91 0.23 0.87 0.24 0.01 0.21 1.41 0.17 0.54 0.08 0.03 0.06 0.01 0.01 0.01 0.02 0.02 0.01 0.01 0.01 0.01 0.01 0.01 0 0.01 0.01 0 0.01 0.01 0.01 0 0.0385
Rel. Deviation
(%)
24.28 0.71 0 8.75 6.01 4.1 2.98 1.33 5.4 3.41 2.68 10.27 3.94 8.21 9.41 1.36 2.6 10.55 3 41.71 0.94 5.16 2.71 4.98 6.12 0.55 3.11 38.24 5.75 19.6 17.19 0.51 51.95 8.03 21.42 31.59 50.01 22.49 45.33 9.21 16.8 32.09 13.94 17.71 26.92 33.98 11.4
Average Intensity (Standards) 318.52 806044.18 22421.73 6703.94 254644.25 213008.11 95575.94 74350.25 505788.56 94019.45 13357.06 8456.38 9457.63 6571 3090.66 109926.59 5064.96 19777.88 5406.26 163.15 4601.92 31578.2 3787.49 12149.44 1733.17 581.94 1247.91 233.53 221.7 321.08 384.12 338.79 227.45 240 180.79 158.24 112.71 112.16 70.59 191.18 221.77 105.29 125.1 243.53 130.59 89.41 870.6
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 1 11.43 3.81 7.27 11.43 28.89 2.73 2.7 295.08 287.07 0.17 10.8 43.82 102.94 136.7 104.75 9.15 387.25 26.89 197.73 19.91 0.13 0 124.36 14.51 35.95 5.17 24.15 24.78 7.62 6.24 2.23 1.72 6.37 0.61 5.7 0.85 1.93 0.21 1.72 0.4 4.17 1.06 1.98 1.45 1.41 0.95 0.52 0
Sample 2 7.47 3.75 3.02 7.47 17.76 2.24 2.34 159.68 110.06 0.1 7.48 24.2 86.52 138.99 41.81 14.77 514.5 25.66 172.09 35.21 0 0 210.89 26.53 44.58 5.85 25.38 24.32 5.29 4.44 2.12 1.06 5.62 0.85 3.84 0.55 3.24 0.03 1.61 0.22 3.93 1.6 12.06 9.16 9.58 2.02 0.39 0
Sample 1 2 10.58 4.07 4.03 10.58 21.99 2.94 2.71 158.5 70.67 0.14 9.15 29.72 108.14 338.39 68.81 20.59 868.8 26.59 180.47 66.32 0.09 0 468.34 49.8 103.12 12.41 44.48 51.36 11.34 9.18 2.26 2.71 10.57 1.33 7.4 1.19 2.51 0.28 0.81 0.12 5.9 2.67 7.99 4.52 5.75 2.64 0.79 0
Sample 2 2 3.33 3.8 1.06 3.33 6.9 1.01 1.06 73.79 38.71 0.04 2.81 10.78 20.72 52.51 16.23 7.95 211.14 9.52 69.71 15.25 0.07 0 71.68 11.73 17.09 2.63 11.85 10.15 3.4 2.69 0.71 1.11 1.73 0.12 2.58 0.16 1.32 0.06 0.77 0.13 2.32 0.92 45.26 24.93 29.03 1.26 0.14 0
Sample 3 2 8.25 2.01 3.23 8.25 20.87 2.08 1.97 143.09 105.48 0.1 13.38 22.69 63.85 89.62 42.16 10.21 498.29 19.11 117.3 26.13 0.11 0 167.49 19.36 36.2 5.56 25.11 23.58 3.78 4.38 2.24 2.32 6.19 0.81 5.65 0.92 2.46 0.23 1.61 0.22 3.01 1.6 23.69 11.85 15.08 2.03 0.39 0
Sample 4 2 6.87 3.31 2.73 6.87 14.04 1.88 1.76 107.09 52.68 0.1 5.08 15.32 45.48 32.17 63.16 28.73 778.96 28.93 209.93 76.98 0.14 0 561.62 50.73 103.95 11.98 46.57 40.49 8.09 8.7 2.81 3.02 8.37 0.75 6.78 0.69 2.35 0.22 1.55 0.26 5.4 3.81 2.09 0.59 1.48 3.35 1.13 0
Sample 5 2 7.12 5.14 3.15 7.12 13.82 2.92 2.83 108.27 16.75 0.22 7.58 11.96 31.3 20.16 75.77 15.47 1025.49 37.61 187.57 58.76 0.11 0 719.18 64.74 141.28 17.22 68.88 68.88 15 12.26 5.69 4.2 14.85 1.92 9.04 2 4.61 0.21 2.53 0.08 4.46 3.43 2.62 1.38 2.56 3.45 1.21 0
Sample 6 2 3.96 2.76 10.21 3.96 6.23 1.17 1.23 140.03 338.18 0.11 10.58 48.46 172.09 41.56 48.62 6.21 300.78 8.78 70.41 17.13 0 0 97.75 11.43 28.46 3.41 12.9 10.29 3.37 3.21 0.81 0.91 2.04 0.33 3.29 0.35 1.12 0.1 0.32 0.2 2.53 1.12 0.43 0.35 0.41 1.44 0.31 0
Sample 7 2 9.32 3.29 2.63 9.32 17.03 3.42 3 283.39 49.5 0.13 8.72 31.52 81.21 88.1 75.32 7.63 885.54 22.98 148.36 34.62 0.14 0 303.89 29.35 62.53 8.33 36.17 28.91 5.29 9.07 1.81 1.76 9.07 0.84 3.97 1.27 2.3 0.09 1.79 0.19 3.86 2.4 9.68 6.16 10.01 2.06 0.73 0
BHVO2 1 11.43 5.39 7.19 11.43 32.71 2.51 2.54 282.92 292.53 0.16 11.34 42.18 119.06 129.3 93.25 10.45 394.75 25.91 170.27 19.09 0.07 0 133.78 15.07 38.57 5.63 24.35 23.72 4.38 5.76 1.69 2.2 6.33 1.31 5.08 1.15 3.05 0.45 2.36 0.2 4.75 1.34 1.25 1.77 1.81 1.4 0.32 0