ALS 00a-172
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 498.69 1319003.07 56194.95 11436.58 573234.35 679804.72 306501.69 265956.74 1870832.1 356723.17 43021.49 33221.65 35378.08 24964.36 9824.7 266837.74 10682.84 35399.18 11536.78 497.13 10778.05 67362.68 6773.31 27089.93 3728.98 1111.86 2435.78 499.36 451.45 628.9 735.09 553.93 412.14 492.98 330.64 275.87 104.8 177.93 79.99 309.35 323.72 276.35 222.87 492.56 169.14 151.55 2843.22
Sample 1 456.02 98107.92 10329.61 2394.66 162757.59 142070.49 10437.8 10838.31 1455234.94 95422.5 2575.27 5245.4 3148.91 9306.41 28950.94 128792.58 11058.47 52391.52 42168.91 642.66 83918.15 706933.92 20347.53 55611.32 7175.67 1970.47 3875.86 627.91 551.17 878.33 1149.72 593.02 444.84 461.24 313.93 308.05 106.36 182.36 115.42 384.32 1073.82 2859.83 2333.14 5558.77 602.22 326.48 18686.96
Sample 2 715.58 347619.25 26292.02 6261.82 392079.52 407177.64 48014.61 29486.79 2404470.52 169768.57 7484.84 7161.67 6975.7 11692.94 37471.84 290510.24 21573.35 83163.51 53463.61 784.07 142089.77 1207876.49 31900.55 75743.26 10690.52 3295.93 6647.52 1090.15 983.89 1814.41 2179.96 1185.75 762.5 902.85 676.74 520.08 269.37 394.62 187.06 662.16 1456.62 12620.47 10488.1 25526.55 940.28 423.31 35765.11
Sample 3 792.82 314586.09 25656.85 6241.99 325621.25 332581.08 32760.44 39818.67 1872298.72 143048.13 6061.24 6327.32 4190.09 7110.37 29876.29 351286.33 23390.32 87299.64 46783.23 535.22 147604.2 1239973.9 32357.13 68029.2 10277.2 3274.09 6602.05 1076.62 1014.86 1820.95 2018.88 1264.9 776.82 1005.11 751.11 565.31 251.09 432.65 201.29 714 1456.09 19801.06 16657.01 40330.13 984.04 339.78 40265.35
Sample 4 766.95 155176.04 12044.09 2790.44 200193 184388.13 24651.02 9144.54 1326623.75 104645.45 4492.97 4847.82 3638.21 13900.13 29317.16 143322.43 8756.13 39755.39 34651.78 480.21 90567.88 793730.59 15300.28 46611.59 5587.51 1511.77 3026.32 479.04 448.92 899.15 1070.99 489.32 297.17 348.02 265.35 233.28 91.98 146.88 93.2 308.02 834.36 1156.42 909.19 2295.3 483.25 391.67 19822.88
Sample 5 601.98 82674.31 8630.36 2231.32 158698.75 139281.23 15692.66 15798.27 1432831.53 100682.53 3267.41 4407.03 1906.49 11838.85 37537.48 96968.41 12794.99 63039 48006.17 607.01 70024.16 577985.45 21898.28 58085.25 7260.56 2082.59 3907.43 644.47 520.29 817.92 985.78 642.76 404.76 501.31 379.53 332.22 189.38 223.4 132.62 454.78 1156.44 6457.31 5370.73 13067.2 679.85 398.97 15694.38
Sample 6 956.05 245474.58 21761.65 4325.34 320431.85 321548.02 34589.6 34339.1 1846912.68 140100.53 5769.97 6414.21 2817.68 10859.82 31812.99 400636.13 17154.36 70090.05 46645.16 827.11 156003.36 1273265.35 26486.67 64124.38 8511.44 2531.87 5148.42 804.28 782.99 1603.25 1838.25 898.56 579.26 673.54 502.82 460.53 213.08 277.17 153.08 546.73 1304.43 15948.14 13448.42 33155.86 791.03 334.73 37694.13
Sample 7 947.23 325666.3 25455.8 5412.5 386714.63 378508.35 37768.43 23902.2 2448282.4 175389.44 7197.05 7655.39 6260.61 14451.63 40734.65 358024.43 21144.49 88022.96 62388.35 943.78 176381.23 1471885.43 34138.42 85175.84 11485.2 3249 6802.06 1142.38 963.76 1965.19 2219.64 1168.91 754.74 906.12 705.68 563.82 262.2 394.07 220.44 755.63 1755.79 7353.68 6168.33 15102.29 1094.63 472.61 41131.85
Sample 8 446.49 72398.3 6567.05 2043.36 143413.41 121194.69 18706.11 10069.39 1132281.38 84147.47 2687.62 4656.9 4956.57 10550.98 25965.77 68717.89 7302.36 37385.57 31442.24 520.83 48654.38 376158.03 13213.96 40799.05 4451.99 1205.7 2434.04 324.68 323.24 536.96 672.89 366.82 278.79 303.18 199.57 209.24 80.95 113.85 62.48 257.87 897.34 846.8 678.67 1684.7 428.15 307.08 10148.5
BHVO2 490.03 1228052.93 51497.87 10607.16 521173.21 609975.71 292700.89 245021.88 1824457.53 315446.47 40520.41 33239.81 34051.48 24300.14 9731.5 242713.53 9463.37 32245.99 10999.41 429.71 9946.8 63067.84 6297.48 25588.73 3450.78 1091.38 2181.18 449.34 405.67 619.02 684.02 528.35 319.67 428.01 309 269.67 97 165.67 67 274.67 279.34 236 203.67 512.34 139.67 147.33 2513.61
Normalized Pk Intensities Select Stds
BHVO 1 0.01 23.47 1 0.2 10.2 12.1 5.45 4.73 33.29 6.35 0.77 0.59 0.63 0.44 0.17 4.75 0.19 0.63 0.21 0.01 0.19 1.2 0.12 0.48 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0 0 0.01 0 0 0.05
Sample 1 0.04 9.5 1 0.23 15.76 13.75 1.01 1.05 140.88 9.24 0.25 0.51 0.3 0.9 2.8 12.47 1.07 5.07 4.08 0.06 8.12 68.44 1.97 5.38 0.69 0.19 0.38 0.06 0.05 0.09 0.11 0.06 0.04 0.04 0.03 0.03 0.01 0.02 0.01 0.04 0.1 0.28 0.23 0.54 0.06 0.03 1.81
Sample 2 0.03 13.22 1 0.24 14.91 15.49 1.83 1.12 91.45 6.46 0.28 0.27 0.27 0.44 1.43 11.05 0.82 3.16 2.03 0.03 5.4 45.94 1.21 2.88 0.41 0.13 0.25 0.04 0.04 0.07 0.08 0.05 0.03 0.03 0.03 0.02 0.01 0.02 0.01 0.03 0.06 0.48 0.4 0.97 0.04 0.02 1.36
Sample 3 0.03 12.26 1 0.24 12.69 12.96 1.28 1.55 72.97 5.58 0.24 0.25 0.16 0.28 1.16 13.69 0.91 3.4 1.82 0.02 5.75 48.33 1.26 2.65 0.4 0.13 0.26 0.04 0.04 0.07 0.08 0.05 0.03 0.04 0.03 0.02 0.01 0.02 0.01 0.03 0.06 0.77 0.65 1.57 0.04 0.01 1.57
Sample 4 0.06 12.88 1 0.23 16.62 15.31 2.05 0.76 110.15 8.69 0.37 0.4 0.3 1.15 2.43 11.9 0.73 3.3 2.88 0.04 7.52 65.9 1.27 3.87 0.46 0.13 0.25 0.04 0.04 0.07 0.09 0.04 0.02 0.03 0.02 0.02 0.01 0.01 0.01 0.03 0.07 0.1 0.08 0.19 0.04 0.03 1.65
Sample 5 0.07 9.58 1 0.26 18.39 16.14 1.82 1.83 166.02 11.67 0.38 0.51 0.22 1.37 4.35 11.24 1.48 7.3 5.56 0.07 8.11 66.97 2.54 6.73 0.84 0.24 0.45 0.07 0.06 0.09 0.11 0.07 0.05 0.06 0.04 0.04 0.02 0.03 0.02 0.05 0.13 0.75 0.62 1.51 0.08 0.05 1.82
Sample 6 0.04 11.28 1 0.2 14.72 14.78 1.59 1.58 84.87 6.44 0.27 0.29 0.13 0.5 1.46 18.41 0.79 3.22 2.14 0.04 7.17 58.51 1.22 2.95 0.39 0.12 0.24 0.04 0.04 0.07 0.08 0.04 0.03 0.03 0.02 0.02 0.01 0.01 0.01 0.03 0.06 0.73 0.62 1.52 0.04 0.02 1.73
Sample 7 0.04 12.79 1 0.21 15.19 14.87 1.48 0.94 96.18 6.89 0.28 0.3 0.25 0.57 1.6 14.06 0.83 3.46 2.45 0.04 6.93 57.82 1.34 3.35 0.45 0.13 0.27 0.04 0.04 0.08 0.09 0.05 0.03 0.04 0.03 0.02 0.01 0.02 0.01 0.03 0.07 0.29 0.24 0.59 0.04 0.02 1.62
Sample 8 0.07 11.02 1 0.31 21.84 18.45 2.85 1.53 172.42 12.81 0.41 0.71 0.75 1.61 3.95 10.46 1.11 5.69 4.79 0.08 7.41 57.28 2.01 6.21 0.68 0.18 0.37 0.05 0.05 0.08 0.1 0.06 0.04 0.05 0.03 0.03 0.01 0.02 0.01 0.04 0.14 0.13 0.1 0.26 0.07 0.05 1.55
BHVO2 1 0.01 23.85 1 0.21 10.12 11.84 5.68 4.76 35.43 6.13 0.79 0.65 0.66 0.47 0.19 4.71 0.18 0.63 0.21 0.01 0.19 1.22 0.12 0.5 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0 0 0.01 0 0 0.05
Average Ratio (Standards) 0.01 23.66 1 0.2 10.16 11.97 5.57 4.75 34.36 6.24 0.78 0.62 0.65 0.46 0.18 4.73 0.19 0.63 0.21 0.01 0.19 1.21 0.12 0.49 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0 0 0.01 0 0 0.05
Rel. Deviation
(%)
4.93 1.12 0 0.85 0.56 1.49 2.91 0.37 4.4 2.52 1.94 6.21 3.47 4.26 5.5 0.53 2.4 0.42 2.8 4.13 0.5 1.51 1.02 2.14 0.69 4.86 1.63 1.29 1.39 5.05 1.08 2.83 11.77 3.82 1.39 4.56 0.71 1.12 6.35 2.23 4.25 4.99 0.2 8.94 7.36 4.18 2.54
Average Intensity (Standards) 494.36 1273528 53846.41 11021.87 547203.78 644890.21 299601.29 255489.31 1847644.82 336084.82 41770.95 33230.73 34714.78 24632.25 9778.1 254775.64 10073.1 33822.59 11268.1 463.42 10362.42 65215.26 6535.4 26339.33 3589.88 1101.62 2308.48 474.35 428.56 623.96 709.56 541.14 365.91 460.49 319.82 272.77 100.9 171.8 73.5 292.01 301.53 256.18 213.27 502.45 154.4 149.44 2678.42
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.44 7.17 11.43 30.62 2.63 2.65 283.05 289.03 0.16 11.27 42.41 106.13 129.74 96.02 9.42 392.46 26.85 184.55 19.11 0.1 128.62 127.69 14.68 36.7 5.37 23.42 24.53 6.05 6.06 1.89 1.95 6.22 1.04 5.54 0.99 2.41 0.33 2.02 0.31 4.53 1.24 1.67 1.61 1.51 1.24 0.41 131.39
Sample 1 2.17 4.19 0.55 2.17 6.61 0.77 0.57 9.94 12.15 0.13 3.11 2.62 17.28 11.91 36.92 28.63 195.38 28.67 281.73 72.06 0.13 1032.88 1382.13 45.5 77.7 10.67 42.8 40.26 7.85 7.63 2.72 3.14 6.87 1.16 5.34 0.97 2.78 0.34 2.14 0.47 5.81 4.23 17.8 17.42 17.57 4.54 0.91 890.68
Sample 2 5.58 6.64 1.97 5.58 17.48 1.88 1.65 46.23 33.41 0.22 5.59 7.69 23.85 26.67 46.89 37.45 445.46 56.53 452.03 92.35 0.16 1767.76 2387.03 72.1 106.97 16.06 72.37 69.8 13.78 13.77 5.68 6.01 13.89 2 10.57 2.11 4.74 0.88 4.68 0.76 10.11 5.8 79.41 79.15 81.54 7.16 1.19 1723.09
Sample 3 4.18 5.65 1.37 4.18 13.38 1.2 1.04 24.22 34.65 0.13 3.62 4.78 16.18 12.3 21.9 22.93 413.67 47.07 364.41 62.06 0.09 1410.27 1881.87 56.16 73.78 11.86 55.21 53.23 10.45 10.91 4.38 4.28 11.38 1.57 9.04 1.8 3.95 0.63 3.94 0.63 8.37 4.45 95.68 96.54 98.93 5.76 0.73 1489.79
Sample 4 2.51 6.98 0.86 2.51 7.64 0.94 0.73 23.28 10.17 0.12 3.38 4.53 15.84 13.65 54.68 28.75 215.61 22.51 212 58.72 0.1 1105.46 1538.93 33.93 64.58 8.24 32.57 31.17 5.94 6.16 2.76 2.9 5.62 0.77 4 0.81 2.08 0.29 1.71 0.37 4.61 3.26 7.14 6.73 7.19 3.61 1.08 936.97
Sample 5 1.83 5.6 0.47 1.83 6.24 0.76 0.57 15.14 17.93 0.13 3.32 3.36 14.71 7.3 47.56 37.59 148.97 33.59 343.29 83.08 0.13 872.83 1144.39 49.59 82.19 10.93 45.82 41.1 8.16 7.29 2.57 2.72 7.54 1.06 5.88 1.19 3.03 0.62 2.65 0.54 6.96 4.61 40.71 40.61 41.82 5.19 1.12 757.56
Sample 6 4.62 8.88 1.39 4.62 12.08 1.53 1.31 33.33 38.94 0.17 4.62 5.94 21.38 10.78 43.59 31.83 614.92 44.99 381.33 80.65 0.17 1942.74 2518.69 59.92 90.65 12.8 55.65 54.11 10.18 10.97 5.03 5.08 10.53 1.52 7.89 1.57 4.2 0.7 3.29 0.63 8.36 5.2 100.44 101.59 106.01 6.03 0.94 1817.79
Sample 7 5.03 8.19 1.72 5.03 14.07 1.72 1.43 33.86 25.22 0.21 5.38 6.89 23.74 22.29 53.97 37.92 511.26 51.59 445.56 100.36 0.18 2043.57 2708.87 71.85 112.02 16.07 66.44 66.51 13.45 12.56 5.73 5.7 12.75 1.85 9.88 2.05 4.78 0.8 4.35 0.84 10.74 6.51 43.09 43.35 44.92 7.77 1.24 1845.47
Sample 8 1.39 4.15 0.41 1.39 5.71 0.69 0.49 18.03 11.42 0.1 2.77 2.76 15.52 18.97 42.35 25.98 105.47 19.15 203.4 54.36 0.11 605.88 744.07 29.89 57.67 6.69 26.5 25.58 4.11 4.53 1.68 1.86 4.3 0.73 3.55 0.62 1.91 0.26 1.35 0.26 3.94 3.58 5.33 5.13 5.39 3.27 0.86 489.39
BHVO2 11.43 4.76 7.29 11.43 30.98 2.61 2.59 294.95 290.57 0.17 10.87 43.59 115.87 136.26 101.98 10.18 389.54 25.95 183.45 19.89 0.09 129.52 130.45 14.9 37.82 5.43 25.08 23.97 5.95 5.94 2.03 1.97 6.48 0.88 5.24 1.01 2.57 0.33 2.06 0.29 4.39 1.16 1.55 1.61 1.71 1.11 0.43 126.75