ALS 00a-171
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 467.31 1178108.42 49281.65 9798.37 496846.37 578185.24 276494.56 232167.19 1739206.71 302616.53 38672.99 30306.06 32014.45 23086.05 8916.44 231667.91 8914.87 30822.95 10323.85 301.84 9425.53 59191.15 5933.24 24192.1 3242.46 1004.65 2010.46 437.43 365.08 541.39 659.6 478.88 316.53 405.21 271.27 282.33 77.49 146.61 87.43 296.78 242.53 258.27 212.94 541.36 123.57 141.67 2384.61
Sample 1 893.28 7051.6 2314.07 1066.41 25246.95 22164.44 540.11 24933.74 940902.72 58258.51 164.69 3244.97 2703.9 9475.91 46624.02 713.77 19541.22 119866.54 73370.12 928.83 654.49 4032.38 26983.41 65901.89 8302.44 2195.76 4565.17 695.47 639.77 221.87 260.17 851.88 536.87 728.39 595.32 525.29 262.34 375.18 204.14 856.83 1985.95 10994.29 9729.2 23160.25 1314.77 620.55 440.47
Sample 2 937.09 4366.67 1869.12 1155.14 26555.88 22820.5 287.2 5880.14 859141.33 56273.95 232.63 3338.07 3527.76 10340.5 48109.93 399.43 14725.85 95203.51 77577.55 810.38 363.29 2220.05 22848.18 68735.46 7578.34 1938.8 4095.6 578.71 546.24 194.08 237.96 676.53 447.32 520.73 456.13 460.37 195.08 273.01 159 714.93 1918.37 1513.69 1181.23 2829.35 943.52 668.51 461.89
Sample 3 1006.87 7239.23 2258.54 1139.98 29611.8 25295.76 489.37 23284.74 983663.37 60903.24 254.31 3555.54 901.56 9335.78 50250.68 1097.72 22396.1 138161.36 83148.66 938.54 1010.95 5848.05 30622.57 76580.3 9417.73 2605.58 5059.64 745.23 758.47 224.82 254.12 898.83 614.86 845.56 634.38 685.58 294.64 397.17 256.7 1047.37 2275.56 11981.52 10179.63 24094.5 1456.79 734.26 587.05
Sample 4 1427.38 2362.21 2220.04 1503.31 28628.52 24144.37 50.19 4974.53 1027073.05 68172.39 226.98 3311.53 2199.75 20731.25 64605.56 110.1 15848.18 103446.63 84678.21 947.97 107.74 612.23 23472.59 73966.5 8022.08 2120.09 4054.51 632.21 618.18 215.74 222.49 712.72 482.43 633.66 497.42 476.5 197.57 318.85 141.21 782.64 2065.24 1395.09 1125.98 2953.69 1133.39 953.5 556.55
Sample 5 1058.27 2583.63 1807.78 891.95 22262.55 19361.55 51.43 8683.25 864862.84 57238.31 271.97 3673.78 4409.37 10333.81 47182.29 235.66 13795.69 88891.99 69833.28 850.55 161.76 849.27 20475.52 60295 6605.35 1746.21 3456.74 505.08 480.92 162.22 196.3 592.4 385.89 522.43 407.54 388.53 158.37 244.2 120.54 634.54 1650.52 1389.53 1192.72 2693.34 894.88 636.55 443.48
Sample 6 936.22 6129.43 1689.26 952.71 20531.67 17296.87 -9.14 6960.74 729979.54 52890.17 175.72 2720.36 2971.46 12310.19 46457.97 368.94 12125.5 79377.33 62833.95 859.23 62.24 448.75 18089.74 56453.28 6017.6 1501.37 3159.1 436.3 448.69 154.37 138.11 490.78 348.81 459.12 351.02 341.71 145.65 223.1 108.51 571.31 1417.17 1110.78 907.48 2203.93 834.31 659.6 355.77
Sample 7 1213.19 24918.86 2740.69 1383.03 34438.35 29417.87 905.98 16054.72 1204811.83 71593.2 212.26 3699.33 1983.8 10525.39 60735.35 2220.18 22375.22 139932.54 97120.55 1126.04 2211.3 13114.23 32519.88 86491.68 10032.12 2646.3 5375.09 815.11 799.01 256.53 300.01 933.19 695.47 865.52 548.04 660.69 277.11 399.06 263.93 957.31 2444.98 7220.86 5929.03 14694.82 1454.71 878.44 925.13
Sample 8 1181.43 2452.77 1906.19 1289.76 22805 19838.06 -0.39 4754.74 917552.28 58650.31 240.13 3215.33 1156.4 11607.01 46058.38 168.45 13780.21 89302.66 68961.25 809.09 93.04 553.15 20067.97 59126.94 6570.01 1679.73 3263.66 470.84 463.06 173.46 173.95 586.99 376.86 515.82 418.44 377.65 168.81 224.15 140.5 629.37 1761.2 962.64 772.24 1872.91 1001.09 720.55 416.45
BHVO2 474.25 1255449.82 51248.84 10549.25 527867.86 626932.32 292088.48 242059.53 1776118.54 310764.78 40322.63 32609.68 33094.06 23721.87 9281.31 241894.33 9543.08 31568.41 10819.92 418.08 9561.02 59805.26 6211.02 24680.47 3346.5 1066.23 2131.25 427.17 411.67 573.84 677.18 464.03 363.73 422.85 302.16 251.87 87.16 155.88 77.35 300.59 315 275 203.04 467.07 112.06 152.26 2572.05
Normalized Pk Intensities Select Stds
BHVO 1 0.01 23.91 1 0.2 10.08 11.73 5.61 4.71 35.29 6.14 0.78 0.61 0.65 0.47 0.18 4.7 0.18 0.63 0.21 0.01 0.19 1.2 0.12 0.49 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0 0.01 0 0.01 0 0 0.05
Sample 1 0.39 3.05 1 0.46 10.91 9.58 0.23 10.77 406.6 25.18 0.07 1.4 1.17 4.09 20.15 0.31 8.44 51.8 31.71 0.4 0.28 1.74 11.66 28.48 3.59 0.95 1.97 0.3 0.28 0.1 0.11 0.37 0.23 0.31 0.26 0.23 0.11 0.16 0.09 0.37 0.86 4.75 4.2 10.01 0.57 0.27 0.19
Sample 2 0.5 2.34 1 0.62 14.21 12.21 0.15 3.15 459.65 30.11 0.12 1.79 1.89 5.53 25.74 0.21 7.88 50.93 41.5 0.43 0.19 1.19 12.22 36.77 4.05 1.04 2.19 0.31 0.29 0.1 0.13 0.36 0.24 0.28 0.24 0.25 0.1 0.15 0.09 0.38 1.03 0.81 0.63 1.51 0.5 0.36 0.25
Sample 3 0.45 3.21 1 0.5 13.11 11.2 0.22 10.31 435.53 26.97 0.11 1.57 0.4 4.13 22.25 0.49 9.92 61.17 36.82 0.42 0.45 2.59 13.56 33.91 4.17 1.15 2.24 0.33 0.34 0.1 0.11 0.4 0.27 0.37 0.28 0.3 0.13 0.18 0.11 0.46 1.01 5.3 4.51 10.67 0.65 0.33 0.26
Sample 4 0.64 1.06 1 0.68 12.9 10.88 0.02 2.24 462.64 30.71 0.1 1.49 0.99 9.34 29.1 0.05 7.14 46.6 38.14 0.43 0.05 0.28 10.57 33.32 3.61 0.95 1.83 0.28 0.28 0.1 0.1 0.32 0.22 0.29 0.22 0.21 0.09 0.14 0.06 0.35 0.93 0.63 0.51 1.33 0.51 0.43 0.25
Sample 5 0.59 1.43 1 0.49 12.31 10.71 0.03 4.8 478.41 31.66 0.15 2.03 2.44 5.72 26.1 0.13 7.63 49.17 38.63 0.47 0.09 0.47 11.33 33.35 3.65 0.97 1.91 0.28 0.27 0.09 0.11 0.33 0.21 0.29 0.23 0.21 0.09 0.14 0.07 0.35 0.91 0.77 0.66 1.49 0.5 0.35 0.25
Sample 6 0.55 3.63 1 0.56 12.15 10.24 -0.01 4.12 432.13 31.31 0.1 1.61 1.76 7.29 27.5 0.22 7.18 46.99 37.2 0.51 0.04 0.27 10.71 33.42 3.56 0.89 1.87 0.26 0.27 0.09 0.08 0.29 0.21 0.27 0.21 0.2 0.09 0.13 0.06 0.34 0.84 0.66 0.54 1.3 0.49 0.39 0.21
Sample 7 0.44 9.09 1 0.5 12.57 10.73 0.33 5.86 439.6 26.12 0.08 1.35 0.72 3.84 22.16 0.81 8.16 51.06 35.44 0.41 0.81 4.79 11.87 31.56 3.66 0.97 1.96 0.3 0.29 0.09 0.11 0.34 0.25 0.32 0.2 0.24 0.1 0.15 0.1 0.35 0.89 2.63 2.16 5.36 0.53 0.32 0.34
Sample 8 0.62 1.29 1 0.68 11.96 10.41 0 2.49 481.36 30.77 0.13 1.69 0.61 6.09 24.16 0.09 7.23 46.85 36.18 0.42 0.05 0.29 10.53 31.02 3.45 0.88 1.71 0.25 0.24 0.09 0.09 0.31 0.2 0.27 0.22 0.2 0.09 0.12 0.07 0.33 0.92 0.51 0.41 0.98 0.53 0.38 0.22
BHVO2 1 0.01 24.5 1 0.21 10.3 12.23 5.7 4.72 34.66 6.06 0.79 0.64 0.65 0.46 0.18 4.72 0.19 0.62 0.21 0.01 0.19 1.17 0.12 0.48 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Average Ratio (Standards) 0.01 24.2 1 0.2 10.19 11.98 5.65 4.72 34.97 6.1 0.79 0.63 0.65 0.47 0.18 4.71 0.18 0.62 0.21 0.01 0.19 1.18 0.12 0.49 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Rel. Deviation
(%)
1.73 1.73 0 2.45 1.51 2.96 1.11 0.18 1.28 0.89 0.19 2.41 0.42 0.85 0.07 0.29 2.05 1.08 0.55 20.13 1.76 2.04 0.47 1.35 0.53 1.44 1.36 4.45 5.72 1.35 0.91 4.99 7.06 0.25 4.86 10.82 5.55 1.57 11.4 1.86 15.66 1.67 6.13 13.17 9.67 2.33 2.58
Average Intensity (Standards) 470.78 1216779.12 50265.25 10173.81 512357.12 602558.78 284291.52 237113.36 1757662.62 306690.65 39497.81 31457.87 32554.26 23403.96 9098.87 236781.12 9228.98 31195.68 10571.89 359.96 9493.28 59498.2 6072.13 24436.29 3294.48 1035.44 2070.85 432.3 388.38 557.61 668.39 471.45 340.13 414.03 286.71 267.1 82.32 151.25 82.39 298.69 278.77 266.63 207.99 504.21 117.81 146.96 2478.33
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.66 7.14 11.43 30.27 2.59 2.57 286.73 289.43 0.17 11.14 42.94 109.11 133.4 99.59 9.8 390.21 26.02 185.4 19.42 0.08 130.67 130.93 14.74 37.62 5.42 24 24.02 6.19 5.76 1.94 1.97 6.57 0.91 5.38 0.97 2.68 0.32 2.02 0.32 4.52 1.07 1.59 1.68 1.76 1.26 0.41 126.71
Sample 1 0.52 8.68 0.04 0.52 3.21 0.13 0.1 0.55 30.33 0.09 2.09 0.18 11.4 10.99 39.89 49.98 1.17 55.65 703.56 134.7 0.25 8.85 8.7 65.42 99.99 13.54 51.19 53.22 9.6 9.84 0.78 0.76 11.41 1.51 9.44 2.07 4.87 1.05 5.04 0.74 12.73 8.53 66.13 74.94 73.52 13.03 1.77 22.84
Sample 2 0.34 7.4 0.02 0.34 2.83 0.11 0.08 0.24 5.81 0.07 1.64 0.2 9.52 11.64 35.34 41.87 0.53 34.04 453.61 115.62 0.18 3.99 3.89 44.97 84.66 10.04 36.69 38.76 6.49 6.82 0.55 0.56 7.36 1.02 5.48 1.29 3.46 0.63 2.98 0.47 8.62 6.69 7.39 7.39 7.29 7.59 1.55 19.44
Sample 3 0.5 9.61 0.04 0.5 3.37 0.15 0.11 0.49 27.8 0.09 2.15 0.27 12.26 3.6 38.57 52.87 1.77 62.6 795.99 149.84 0.25 13.42 12.39 72.87 114.05 15.08 59.63 57.89 10.1 11.46 0.77 0.73 11.82 1.69 10.75 2.16 6.23 1.15 5.23 0.91 15.27 9.59 70.74 76.96 75.07 14.17 2.05 29.88
Sample 4 0.41 11.33 0.01 0.41 3.7 0.12 0.09 0.04 4.94 0.08 2 0.2 9.5 7.3 71.27 56.56 0.15 36.86 495.84 126.96 0.21 1.19 1.08 46.47 91.65 10.69 40.36 38.6 7.13 7.77 0.62 0.53 7.8 1.11 6.7 1.41 3.61 0.64 3.5 0.42 9.5 7.24 6.85 7.08 7.66 9.18 2.22 23.57
Sample 5 0.21 5.18 0.01 0.21 1.35 0.06 0.04 0.03 5.32 0.04 1.04 0.15 6.5 9.03 21.91 25.47 0.2 19.79 262.76 64.57 0.11 1.1 0.92 25 46.07 5.43 20.5 20.29 3.51 3.73 0.29 0.29 4 0.55 3.41 0.71 1.81 0.32 1.65 0.22 4.75 3.57 4.21 4.63 4.31 4.47 0.91 11.58
Sample 6 0.33 7.97 0.03 0.33 2.52 0.09 0.07 -0.01 7.42 0.06 1.66 0.17 8.37 10.58 45.4 43.63 0.53 30.25 408.15 101.06 0.2 0.74 0.85 38.42 75.04 8.6 30.66 32.26 5.28 6.05 0.47 0.35 5.76 0.86 5.21 1.07 2.77 0.51 2.62 0.34 7.44 5.33 5.85 6.12 6.13 7.25 1.65 16.16
Sample 7 0.61 11.5 0.14 0.61 4.07 0.17 0.12 0.89 19.05 0.11 2.51 0.22 12.68 7.87 43.22 63.5 3.56 62.15 801.12 173.92 0.29 29.18 27.61 76.9 128 15.96 60.18 61.12 10.98 11.99 0.88 0.85 12.19 1.9 10.94 1.86 5.97 1.08 5.23 0.93 13.87 10.24 42.36 44.54 45.5 14.07 2.44 46.79
Sample 8 0.37 9.87 0.01 0.37 3.34 0.1 0.07 0 4.97 0.07 1.81 0.22 9.7 4.04 41.97 42.41 0.24 33.71 450.27 108.76 0.19 1.08 1.03 41.79 77.07 9.21 33.64 32.68 5.58 6.12 0.52 0.44 6.75 0.91 5.74 1.25 3.01 0.58 2.59 0.44 8.03 6.5 4.97 5.11 5.11 8.52 1.76 18.55
BHVO2 11.43 4.54 7.32 11.43 31.33 2.65 2.67 291.27 290.17 0.17 11 43.06 112.89 132.6 98.41 9.8 391.79 26.78 182.6 19.58 0.11 127.47 127.21 14.84 36.9 5.38 24.5 24.48 5.81 6.24 1.98 1.95 6.13 1.01 5.4 1.03 2.3 0.34 2.06 0.28 4.4 1.33 1.63 1.54 1.46 1.09 0.43 131.43