ALS 00-72
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 856.25 3051104.06 118938.19 36336.01 923767.18 740623.51 454670.93 -78919.66 2221923.45 551442.84 71417.18 48491.92 73527.51 45084.73 20347.54 526408.33 16318.48 46201.21 15796.59 -38.04 19017.86 122029.8 8116.53 34615.23 5103.12 1912.55 4033.3 895.55 801.74 1276.77 1494.96 1155.18 700.23 932.51 603.44 619.46 215.81 332.06 187.39 633.99 587.62 900.04 713.06 1742 277.35 402.36 16458.83
Sample 1 1756.74 93456.39 11350.67 16900.25 148097.68 117901.51 60.52 -99060.32 1583138.97 113318.37 641.03 593.65 788.49 40083.34 124921.87 2547.64 20003.66 116913.47 94256.8 1683.18 3565.63 23917.23 28350.52 91824.55 10890.22 3378.67 6864.66 1218.52 1026.43 715.7 787.93 1472.52 916.11 965.12 765.5 874.44 319.85 545.85 288.3 1210.38 2709.83 2612.99 2236.33 5817.42 1850.54 1853.33 8741.31
Sample 2 1806.23 126536.85 14925.99 33569.08 190661.65 152167.19 682.57 -29886.36 1744005.1 129819.52 1719.53 2915.05 1205.87 38169.66 118648.95 5202.72 18740.72 104951.39 80846.09 1674.74 8016.24 53284.45 25899.44 83803.76 10564.65 3101.88 6721.95 1142.98 1020.25 939.88 1097.69 1447.06 1005.99 1114 780.33 776.64 322.47 569.5 314.21 1380.69 2998.31 2967.8 2655.21 6485.66 2190.45 1945.96 11780.55
Sample 3 2434.97 185163.29 13023.88 30987.67 171141.21 146505.15 16982.99 -20976.43 2018477.01 143747.77 6446.86 4554.84 4664.26 32760.66 125211.81 16011.39 14982.08 72913.87 57375.32 3670.18 23736.74 151412.17 19420.59 62087.53 7865.53 2486.83 5017.12 973.12 774.39 853.88 905.17 1124.42 720.54 848.11 630.79 594.89 232.05 450.65 244.23 898.11 1878.99 5266.04 4429.7 11071.88 1449.45 1491.77 16494.83
Sample 4 1818.47 133605.74 15522.89 21701.79 212870.68 171162.74 157.25 -24957.36 2215862.75 155603.12 1049.97 1162.09 1152.33 53066.55 147279.25 5159.37 22355.82 124151.04 104653.52 1763.12 10503.37 66815.41 31730.97 105291.82 12290.74 3680.83 7905.71 1276.45 1298.74 1131.29 1132.82 1681.44 1114.24 1331.79 909.46 994.8 418.2 703.55 325.34 1685.35 3858.87 3635.29 2981.13 7467.46 2352.02 2706.58 15204.71
Sample 5 2587.63 124855.14 15856.45 21910.66 198573.36 161081.3 381.65 -18638.15 2346202.36 159895.13 481.16 1340.45 1336.98 56483.85 180789.39 3687.17 28282.22 161401.43 128634.92 2399.46 4638.02 30625.11 38230.18 123001.81 15043.26 4345.83 9275.25 1515.91 1567.59 1031.93 1063.76 1961.3 1316.8 1564.34 1143.26 1113.69 472.63 800.85 460.34 2152.13 4540.73 5805.83 4672.02 11955.28 3142.37 3009.03 14337.62
Sample 6 1715.29 110392.63 12559.99 18325.72 164061.66 135708.82 1305.48 963.8 2046964.36 126111.54 1723.08 1153.18 2995.2 31008.07 120458.27 4582.96 21135.1 116724.72 85950.39 1742.57 5770.54 38844.94 28485.58 83653.18 10745.5 3313.67 6897.48 1109.19 1066.29 800.94 852.16 1449.78 964.36 1118.56 787.78 817.53 307.75 559.99 292.16 1370.77 2880.79 6632.45 5525.26 13960.47 2140.12 1670.8 12068.47
Sample 7 1376.14 96672.87 10484.45 15073.92 150589.58 121727.81 496.62 -3363.16 1238496.61 91631.64 1108.99 307.16 2616.6 35448.7 88759.83 5561.9 13580.27 72543.05 58370.73 1058.83 13722.29 89381.14 18925.3 60136.22 7359.97 2357.29 4604.54 753.7 690.19 743.22 871.78 914.29 680.06 746.6 559.75 577.07 252.98 376.32 236.05 922.18 2034.34 2422.76 1903.49 5175.44 1339.5 1418.07 13727.09
Sample 8 1892.46 180700.4 16386.8 25410.32 257564.22 224200.2 1023.36 5133.1 2134119.62 162919.11 1416.37 1537.87 3103.73 56231 148785.36 11670.69 21547.11 113430.11 129604.31 1467.4 30037.37 194331.29 30873.66 101702.53 11640.96 3503.71 7334.71 1231.39 1758.82 1257.76 1436.9 1450.28 953.81 1129.17 748.6 833.8 301.62 559.67 319.86 1245.06 2979.45 2919.32 2393.66 5840.57 1875.33 2262.35 23819.86
BHVO2 766.5 2352109.87 99652.92 27079.99 776035.01 633196.03 381082.87 281138.56 1631513.64 437220.67 55252.83 37996.35 57758.59 42553.56 18078.6 420930.29 13744.34 41414.7 13330.52 201.26 15773.75 104691.59 7526.67 30391.41 4440 1549.83 3466.21 734.07 739.4 1070.28 1273.19 955.69 677.22 728.45 592.25 399.16 190.59 304.44 172.33 526 445.11 660.9 522.31 1326.4 263.37 318.67 15989.44
Normalized Pk Intensities Select Stds
BHVO 1 0.01 25.65 1 0.31 7.77 6.23 3.82 -0.66 18.68 4.64 0.6 0.41 0.62 0.38 0.17 4.43 0.14 0.39 0.13 0 0.16 1.03 0.07 0.29 0.04 0.02 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0 0.01 0.01 0.01 0 0 0.14
Sample 1 0.15 8.23 1 1.49 13.05 10.39 0.01 -8.73 139.48 9.98 0.06 0.05 0.07 3.53 11.01 0.22 1.76 10.3 8.3 0.15 0.31 2.11 2.5 8.09 0.96 0.3 0.6 0.11 0.09 0.06 0.07 0.13 0.08 0.09 0.07 0.08 0.03 0.05 0.03 0.11 0.24 0.23 0.2 0.51 0.16 0.16 0.77
Sample 2 0.12 8.48 1 2.25 12.77 10.19 0.05 -2 116.84 8.7 0.12 0.2 0.08 2.56 7.95 0.35 1.26 7.03 5.42 0.11 0.54 3.57 1.74 5.61 0.71 0.21 0.45 0.08 0.07 0.06 0.07 0.1 0.07 0.07 0.05 0.05 0.02 0.04 0.02 0.09 0.2 0.2 0.18 0.43 0.15 0.13 0.79
Sample 3 0.19 14.22 1 2.38 13.14 11.25 1.3 -1.61 154.98 11.04 0.5 0.35 0.36 2.52 9.61 1.23 1.15 5.6 4.41 0.28 1.82 11.63 1.49 4.77 0.6 0.19 0.39 0.07 0.06 0.07 0.07 0.09 0.06 0.07 0.05 0.05 0.02 0.03 0.02 0.07 0.14 0.4 0.34 0.85 0.11 0.11 1.27
Sample 4 0.12 8.61 1 1.4 13.71 11.03 0.01 -1.61 142.75 10.02 0.07 0.07 0.07 3.42 9.49 0.33 1.44 8 6.74 0.11 0.68 4.3 2.04 6.78 0.79 0.24 0.51 0.08 0.08 0.07 0.07 0.11 0.07 0.09 0.06 0.06 0.03 0.05 0.02 0.11 0.25 0.23 0.19 0.48 0.15 0.17 0.98
Sample 5 0.16 7.87 1 1.38 12.52 10.16 0.02 -1.18 147.97 10.08 0.03 0.08 0.08 3.56 11.4 0.23 1.78 10.18 8.11 0.15 0.29 1.93 2.41 7.76 0.95 0.27 0.58 0.1 0.1 0.07 0.07 0.12 0.08 0.1 0.07 0.07 0.03 0.05 0.03 0.14 0.29 0.37 0.29 0.75 0.2 0.19 0.9
Sample 6 0.14 8.79 1 1.46 13.06 10.8 0.1 0.08 162.97 10.04 0.14 0.09 0.24 2.47 9.59 0.36 1.68 9.29 6.84 0.14 0.46 3.09 2.27 6.66 0.86 0.26 0.55 0.09 0.08 0.06 0.07 0.12 0.08 0.09 0.06 0.07 0.02 0.04 0.02 0.11 0.23 0.53 0.44 1.11 0.17 0.13 0.96
Sample 7 0.13 9.22 1 1.44 14.36 11.61 0.05 -0.32 118.13 8.74 0.11 0.03 0.25 3.38 8.47 0.53 1.3 6.92 5.57 0.1 1.31 8.53 1.81 5.74 0.7 0.22 0.44 0.07 0.07 0.07 0.08 0.09 0.06 0.07 0.05 0.06 0.02 0.04 0.02 0.09 0.19 0.23 0.18 0.49 0.13 0.14 1.31
Sample 8 0.12 11.03 1 1.55 15.72 13.68 0.06 0.31 130.23 9.94 0.09 0.09 0.19 3.43 9.08 0.71 1.31 6.92 7.91 0.09 1.83 11.86 1.88 6.21 0.71 0.21 0.45 0.08 0.11 0.08 0.09 0.09 0.06 0.07 0.05 0.05 0.02 0.03 0.02 0.08 0.18 0.18 0.15 0.36 0.11 0.14 1.45
BHVO2 1 0.01 23.6 1 0.27 7.79 6.35 3.82 2.82 16.37 4.39 0.55 0.38 0.58 0.43 0.18 4.22 0.14 0.42 0.13 0 0.16 1.05 0.08 0.3 0.04 0.02 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0 0.01 0.01 0.01 0 0 0.16
Average Ratio (Standards) 0.01 24.63 1 0.29 7.78 6.29 3.82 1.08 17.53 4.51 0.58 0.39 0.6 0.4 0.18 4.32 0.14 0.4 0.13 0 0.16 1.04 0.07 0.3 0.04 0.02 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0 0.01 0.01 0.01 0 0 0.15
Rel. Deviation
(%)
4.68 5.89 0 8.27 0.19 1.43 0.02 228.4 9.32 3.9 5.63 4.74 4.56 8.41 4.15 3.3 0.37 4.77 0.51 194.64 0.72 1.67 7.17 3.31 2.67 2.36 1.8 1.55 6.78 0.04 1.16 0.9 10.13 4.95 11.16 18.46 3.72 6.36 6.58 0.7 7.13 9.32 9.49 6.76 8.84 3.98 10.44
Average Intensity (Standards) 811.38 2701606.96 109295.56 31708 849901.1 686909.77 417876.9 101109.45 1926718.54 494331.75 63335 43244.14 65643.05 43819.14 19213.07 473669.31 15031.41 43807.96 14563.56 81.61 17395.8 113360.69 7821.6 32503.32 4771.56 1731.19 3749.75 814.81 770.57 1173.53 1384.07 1055.43 688.73 830.48 597.84 509.31 203.2 318.25 179.86 579.99 516.36 780.47 617.68 1534.2 270.36 360.51 16224.13
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.45 7.53 11.43 32.6 2.62 2.59 288.95 -178.24 0.18 11.38 44.71 114.72 137.29 93.11 9.51 400.13 26.33 177.79 19.43 -0.04 129.72 127.54 14.04 36.39 5.3 24.65 23.94 6.07 5.71 1.96 1.94 6.39 0.89 5.58 0.92 2.82 0.32 1.95 0.29 4.48 1.26 1.72 1.72 1.69 1.1 0.43 119.54
Sample 1 0.98 8.23 0.21 0.98 13.67 0.38 0.37 0.03 -201.68 0.11 2.11 0.36 1.27 1.33 74.62 52.65 1.75 29.1 405.56 104.51 1.45 21.92 22.53 44.21 87.02 10.19 39.26 36.73 7.44 6.59 0.99 0.92 7.34 1.05 5.2 1.05 3.58 0.43 2.89 0.4 7.71 5.24 4.49 4.86 5.08 6.63 1.8 57.23
Sample 2 1.45 9.5 0.32 1.45 30.49 0.55 0.54 0.44 -68.32 0.14 2.71 1.09 6.98 2.28 79.79 56.15 4 30.61 408.8 100.66 1.62 55.35 56.37 45.35 89.17 11.1 40.47 40.39 7.84 7.36 1.46 1.44 8.1 1.29 6.75 1.21 3.57 0.49 3.38 0.49 9.88 6.51 5.73 6.48 6.36 8.81 2.12 86.61
Sample 3 1.28 12.92 0.47 1.28 28.4 0.5 0.52 11.02 -48.39 0.16 3.03 4.12 11.01 8.9 69.11 59.79 12.43 24.69 286.61 72.09 3.58 165.39 161.65 34.32 66.67 8.34 32.75 30.42 6.73 5.64 1.34 1.2 6.35 0.93 5.18 0.98 2.76 0.35 2.7 0.38 6.49 4.12 10.26 10.91 10.96 5.88 1.64 122.37
Sample 4 1.54 9.76 0.34 1.54 20.12 0.62 0.62 0.1 -58.24 0.18 3.32 0.68 2.84 2.22 113.23 71.14 4.05 37.27 493.61 133 1.74 74.02 72.15 56.71 114.36 13.18 49.03 48.49 8.93 9.56 1.79 1.52 9.61 1.46 8.23 1.43 4.67 0.64 4.26 0.51 12.31 8.55 7.17 7.43 7.48 9.65 3.01 114.1
Sample 5 1.44 12.68 0.29 1.44 18.55 0.53 0.53 0.23 -39.71 0.18 3.11 0.28 2.99 2.36 110.05 79.73 2.64 43.05 585.93 149.27 2.16 29.85 30.2 62.39 121.98 14.73 52.85 51.94 9.69 10.54 1.49 1.3 10.24 1.58 8.83 1.65 4.77 0.66 4.43 0.66 14.35 9.19 10.45 10.63 10.93 11.77 3.05 98.24
Sample 6 1.21 8.95 0.27 1.21 16.52 0.47 0.48 0.83 2.19 0.16 2.61 1.08 2.74 5.62 64.32 56.56 3.5 34.25 451.17 106.19 1.67 39.54 40.78 49.49 88.33 11.21 42.91 41.13 7.55 7.63 1.23 1.11 8.06 1.23 6.72 1.21 3.73 0.46 3.3 0.45 9.73 6.21 12.71 13.38 13.59 8.54 1.8 88.04
Sample 7 0.98 6.93 0.23 0.98 13.11 0.41 0.41 0.31 -7.36 0.1 1.83 0.67 0.7 4.73 70.95 40.21 4.1 21.24 270.54 69.58 0.98 90.71 90.54 31.73 61.27 7.41 29.45 26.49 4.95 4.77 1.11 1.1 4.9 0.84 4.33 0.83 2.54 0.37 2.14 0.35 6.32 4.23 4.48 4.45 4.86 5.16 1.48 96.62
Sample 8 1.61 10.03 0.46 1.61 23.27 0.74 0.8 0.66 11.83 0.17 3.43 0.9 3.71 5.91 118.51 70.98 9.05 35.48 445.43 162.68 1.43 209.08 207.27 54.5 109.1 12.33 46.09 44.43 8.51 12.79 1.97 1.91 8.19 1.24 6.89 1.17 3.87 0.46 3.35 0.5 8.98 6.52 5.68 5.89 5.78 7.6 2.48 176.54
BHVO2 11.43 4.75 6.93 11.43 29 2.62 2.65 289.05 757.84 0.16 10.76 41.29 107.28 128.71 104.89 10.09 381.87 26.47 190.21 19.57 0.23 128.42 130.6 15.54 38.13 5.5 23.85 24.56 5.93 6.29 1.96 1.98 6.31 1.03 5.2 1.08 2.16 0.34 2.13 0.31 4.44 1.14 1.5 1.5 1.53 1.25 0.41 138.6