ALS 00-168A
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 279.31 1617198.21 55005.65 15371.64 599211.97 456925.81 233747.84 177349.34 1099704.57 230182.68 30713.33 21054.61 24745.26 18955.03 7729.74 227693.56 7839.68 26998.19 9073.61 200.42 9878.51 61857.26 5869.43 23752.37 3105.53 923.27 2041.87 356.76 403.28 576.23 587.5 529.7 263.11 369.92 277.06 269.91 88.33 169.17 72.15 251.49 269.17 200.75 157.5 438.69 98.11 123.69 1131.53
Sample 1 450.31 27894.08 3337.89 3757.11 30891.35 25831.09 182.58 7882.01 663522.12 37175.48 279.21 1760.08 194.2 2763.67 29064.28 3471.47 13474.71 96021.62 57574.82 356.79 5068.24 31611.43 25292.82 54443.81 6704.87 1666.22 3613.21 552.3 499.82 264.58 272.86 667.07 453.53 597.64 415.44 440.87 144.76 274.58 143.24 762.69 1669.55 3352.84 2834.79 6696.57 1057.19 440.49 594.21
Sample 2 843.05 41774.21 4777.68 6205.31 41217.39 34094.93 220.51 7870.98 1192027.72 59697.09 206.54 933.39 314.02 5786.23 60975.39 4069.02 28361.91 213401.58 122847.49 1216.65 5330.3 32693.8 52822.34 120692.74 13599.09 3531.49 7321.54 1029.05 895.53 394.51 480.51 1394.58 905.03 1075.55 888.53 930.03 385.51 617.52 342.51 1515.59 4107.65 4821.93 3725.56 9725.78 2190.19 935.04 843.53
Sample 3 779.48 41525.05 4413.61 5320.49 28533.87 23808.42 566.91 16120.17 943160.22 46675.03 644.22 1084.68 378.74 3940.22 50517.59 3229.01 31535.6 245433.37 103062.41 914.81 3306.84 20282.26 57342.9 105458.48 13061.81 3489.83 7429.6 1078.97 1066.46 312.24 412.33 1550.03 933.2 1289.62 1008.29 1100.06 339.46 670.86 381.04 1866.66 3644.32 10063.95 8469.12 20487.77 2196.06 825.04 555.6
Sample 4 483.03 18599.47 2874.36 4085.13 30720.93 24982.99 8.33 2535.68 683292.07 35948.18 813.08 350.02 200.33 5418.11 36112.11 2164.35 11199.19 87276.85 60811.42 660.36 3828.81 23736.29 21191.7 54737.8 5637.36 1350.24 2785.79 454.1 330.73 204.9 254.25 463.57 389.71 509.65 362.43 367.49 172.71 236.93 152.45 678.29 1564.81 1401.72 919.15 2468.72 825.52 436.12 540.87
Sample 5 446.5 35326.92 4206.59 5433.08 57150.47 47366.95 357.1 1799.14 878193.55 48209.72 601.66 1342.63 302.21 6370.97 34254.64 6971.4 9218.74 67286.84 52351.35 584.75 12523.86 82973 20577.5 58323 6200.04 1583.33 3110.66 470.73 434.14 386.39 368.94 500.73 397.97 435.47 289.8 280.46 155.46 200.92 140.92 611.85 1438.51 855.49 738.44 1801.52 640.48 472.51 1426.78
Sample 6 414.07 23649.18 3057.76 4071.24 33198.48 28772.27 286.69 11515.39 711233.16 44823.52 1089.47 1318.41 764.97 3609.4 34378.62 3718.22 14674.79 111512.47 65051.37 604.21 5467.48 32815.85 27564.01 62837.15 7225.06 1950.23 4091.17 566.07 516.4 297.08 308.4 721.29 496.89 602.9 522.6 496.89 136.34 334.59 228.59 866.77 1949.4 5026.27 3779.95 9578.13 1026.88 521.97 799.26
Sample 7 496.44 37286.11 4170.53 5409.45 59831.26 49256.88 534.68 2412.5 865592.29 49829.95 500.16 1276.46 108.1 7055.06 34452.22 9954.03 9242.84 63547.24 48256.98 471.91 12254.32 77460.89 17136.62 48721.36 5055.16 1219.73 2638.36 396.63 429.67 367.7 437.02 458.59 312.16 420.55 253.24 258.04 90.54 192.5 100 495.55 1372.6 912.55 718.07 1676.79 635.02 393.05 1445.9
Sample 8 599.09 48627.76 5956.53 6425.21 64964.04 53667.89 358.1 10370.6 1158166.23 63758.04 386.25 1350.67 327.59 4632.23 48793.86 7125.31 22749.48 156582.55 88645.63 558.79 11529.25 73301.69 42215.02 90125.66 11195.48 2882.84 6066.54 891.87 795.9 471.49 600.81 1194.74 704.85 921.14 785.79 811.38 284.52 444.31 277.21 1311.82 2732.43 5362.44 4216.48 10919.46 1497.66 553.67 1424.79
BHVO2 294.46 1600653.97 56007.62 16107.65 595631.77 472045.76 235813.63 181947.66 1116731.6 242079.56 31166.49 21455.99 26817.32 19893.43 7868.35 237233.32 8396.14 27957.88 9138.16 301.57 9914.49 63544.29 5846.27 24484.24 2978.12 1072.57 2092.46 351.06 360.02 612.23 615.78 534.15 337.69 422.48 252.91 256.76 81.93 162.16 76.53 281.94 284.64 229.58 208.96 439.55 89.19 97.3 1119.77
Normalized Pk Intensities Select Stds
BHVO 1 0.01 29.4 1 0.28 10.89 8.31 4.25 3.22 19.99 4.18 0.56 0.38 0.45 0.34 0.14 4.14 0.14 0.49 0.16 0 0.18 1.12 0.11 0.43 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0 0.01 0.01 0 0 0 0 0 0 0 0 0.01 0 0 0.02
Sample 1 0.13 8.36 1 1.13 9.25 7.74 0.05 2.36 198.78 11.14 0.08 0.53 0.06 0.83 8.71 1.04 4.04 28.77 17.25 0.11 1.52 9.47 7.58 16.31 2.01 0.5 1.08 0.17 0.15 0.08 0.08 0.2 0.14 0.18 0.12 0.13 0.04 0.08 0.04 0.23 0.5 1 0.85 2.01 0.32 0.13 0.18
Sample 2 0.18 8.74 1 1.3 8.63 7.14 0.05 1.65 249.5 12.49 0.04 0.2 0.07 1.21 12.76 0.85 5.94 44.67 25.71 0.25 1.12 6.84 11.06 25.26 2.85 0.74 1.53 0.22 0.19 0.08 0.1 0.29 0.19 0.23 0.19 0.19 0.08 0.13 0.07 0.32 0.86 1.01 0.78 2.04 0.46 0.2 0.18
Sample 3 0.18 9.41 1 1.21 6.46 5.39 0.13 3.65 213.69 10.58 0.15 0.25 0.09 0.89 11.45 0.73 7.15 55.61 23.35 0.21 0.75 4.6 12.99 23.89 2.96 0.79 1.68 0.24 0.24 0.07 0.09 0.35 0.21 0.29 0.23 0.25 0.08 0.15 0.09 0.42 0.83 2.28 1.92 4.64 0.5 0.19 0.13
Sample 4 0.17 6.47 1 1.42 10.69 8.69 0 0.88 237.72 12.51 0.28 0.12 0.07 1.88 12.56 0.75 3.9 30.36 21.16 0.23 1.33 8.26 7.37 19.04 1.96 0.47 0.97 0.16 0.12 0.07 0.09 0.16 0.14 0.18 0.13 0.13 0.06 0.08 0.05 0.24 0.54 0.49 0.32 0.86 0.29 0.15 0.19
Sample 5 0.11 8.4 1 1.29 13.59 11.26 0.08 0.43 208.77 11.46 0.14 0.32 0.07 1.51 8.14 1.66 2.19 16 12.45 0.14 2.98 19.72 4.89 13.86 1.47 0.38 0.74 0.11 0.1 0.09 0.09 0.12 0.09 0.1 0.07 0.07 0.04 0.05 0.03 0.15 0.34 0.2 0.18 0.43 0.15 0.11 0.34
Sample 6 0.14 7.73 1 1.33 10.86 9.41 0.09 3.77 232.6 14.66 0.36 0.43 0.25 1.18 11.24 1.22 4.8 36.47 21.27 0.2 1.79 10.73 9.01 20.55 2.36 0.64 1.34 0.19 0.17 0.1 0.1 0.24 0.16 0.2 0.17 0.16 0.04 0.11 0.07 0.28 0.64 1.64 1.24 3.13 0.34 0.17 0.26
Sample 7 0.12 8.94 1 1.3 14.35 11.81 0.13 0.58 207.55 11.95 0.12 0.31 0.03 1.69 8.26 2.39 2.22 15.24 11.57 0.11 2.94 18.57 4.11 11.68 1.21 0.29 0.63 0.1 0.1 0.09 0.1 0.11 0.07 0.1 0.06 0.06 0.02 0.05 0.02 0.12 0.33 0.22 0.17 0.4 0.15 0.09 0.35
Sample 8 0.1 8.16 1 1.08 10.91 9.01 0.06 1.74 194.44 10.7 0.06 0.23 0.05 0.78 8.19 1.2 3.82 26.29 14.88 0.09 1.94 12.31 7.09 15.13 1.88 0.48 1.02 0.15 0.13 0.08 0.1 0.2 0.12 0.15 0.13 0.14 0.05 0.07 0.05 0.22 0.46 0.9 0.71 1.83 0.25 0.09 0.24
BHVO2 1 0.01 28.58 1 0.29 10.63 8.43 4.21 3.25 19.94 4.32 0.56 0.38 0.48 0.36 0.14 4.24 0.15 0.5 0.16 0.01 0.18 1.13 0.1 0.44 0.05 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0 0.01 0.01 0 0 0.01 0 0 0.02
Average Ratio (Standards) 0.01 28.99 1 0.28 10.76 8.37 4.23 3.24 19.97 4.25 0.56 0.38 0.46 0.35 0.14 4.19 0.15 0.5 0.16 0 0.18 1.13 0.11 0.43 0.05 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0 0 0 0 0 0.01 0 0 0.02
Rel. Deviation
(%)
2.46 2 0 2.03 1.7 1.03 0.65 0.53 0.19 2.29 0.24 0.06 4.41 2.14 0.02 1.63 3.57 1.19 0.78 27.27 1.02 0.63 1.56 0.87 4.24 9.31 0.45 2.42 9.29 3.01 2.05 0.69 16.3 8.11 7.72 4.81 6.59 4.27 2.89 6.8 2.67 8.2 18.61 1.14 8.01 18.14 2.02
Average Intensity (Standards) 286.88 1608926.09 55506.64 15739.64 597421.87 464485.79 234780.74 179648.5 1108218.08 236131.12 30939.91 21255.3 25781.29 19424.23 7799.05 232463.44 8117.91 27478.03 9105.89 251 9896.5 62700.77 5857.85 24118.31 3041.83 997.92 2067.17 353.91 381.65 594.23 601.64 531.93 300.4 396.2 264.99 263.34 85.13 165.67 74.34 266.71 276.9 215.16 183.23 439.12 93.65 110.49 1125.65
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.52 7.33 11.43 30.36 2.65 2.6 290.34 288.71 0.17 10.89 43.07 110.95 128.85 97.5 9.8 386.51 25.73 182.45 19.61 0.08 130 128.5 14.95 37.03 5.56 22.65 24.17 6.1 6.39 1.92 1.93 6.38 0.85 5.08 1.05 2.57 0.35 2.1 0.29 4.25 1.18 1.52 1.4 1.62 1.24 0.47 130.91
Sample 1 0.65 6.82 0.12 0.65 6.94 0.13 0.14 0.21 12 0.09 1.65 0.37 8.67 0.95 13.3 34.47 5.51 41.37 606.88 116.36 0.13 62.38 61.42 60.26 79.38 11.23 38.24 40 8.84 7.41 0.82 0.84 7.52 1.37 7.68 1.48 3.93 0.53 3.19 0.55 12.04 6.83 23.7 23.55 23.18 12.51 1.58 64.29
Sample 2 0.91 12.49 0.17 0.91 11.22 0.17 0.18 0.25 11.73 0.17 2.59 0.27 4.5 1.5 27.25 70.79 6.32 85.24 1320.45 243.06 0.43 64.23 62.19 123.22 172.29 22.3 79.34 79.36 16.12 13 1.2 1.45 15.38 2.67 13.53 3.1 8.12 1.38 7.02 1.28 23.43 16.45 33.38 30.3 32.97 25.38 3.29 89.36
Sample 3 0.52 7.12 0.11 0.52 5.93 0.07 0.08 0.4 14.81 0.08 1.25 0.51 3.23 1.11 11.44 36.16 3.09 58.44 936.34 125.73 0.2 24.57 23.79 82.47 92.82 13.21 48.34 49.65 10.42 9.55 0.59 0.77 10.54 1.7 10 2.17 5.92 0.75 4.7 0.88 17.79 9 42.95 42.47 42.82 15.69 1.79 36.29
Sample 4 0.57 7.45 0.08 0.57 7.69 0.13 0.14 0.01 3.94 0.1 1.62 1.09 1.76 0.99 26.58 43.66 3.5 35.05 562.41 125.3 0.24 48.05 47.02 51.48 81.38 9.63 31.59 31.45 7.41 5 0.65 0.8 5.32 1.2 6.68 1.32 3.34 0.64 2.81 0.59 10.92 6.53 10.1 7.79 8.71 9.96 1.6 59.67
Sample 5 0.83 6.86 0.15 0.83 10.18 0.24 0.26 0.42 2.78 0.13 2.16 0.8 6.71 1.49 31.1 41.22 11.23 28.71 431.48 107.35 0.22 156.4 163.56 49.74 86.28 10.54 36.86 34.94 7.64 6.53 1.22 1.15 5.72 1.22 5.68 1.05 2.54 0.58 2.37 0.54 9.8 5.97 6.14 6.22 6.33 7.69 1.72 156.64
Sample 6 0.62 6.58 0.11 0.62 7.9 0.14 0.16 0.35 18.42 0.11 2.08 1.5 6.83 3.91 18.24 42.83 6.2 47.32 740.33 138.1 0.23 70.69 66.97 68.99 96.24 12.71 47.01 47.58 9.51 8.04 0.97 1 8.54 1.57 8.14 1.95 4.66 0.52 4.08 0.91 14.38 8.38 37.33 32.99 34.83 12.77 1.97 90.84
Sample 7 0.86 7.96 0.17 0.86 10.59 0.26 0.28 0.66 3.89 0.13 2.34 0.7 6.67 0.56 35.96 43.29 16.74 30.07 425.56 103.34 0.18 159.81 159.46 43.26 75.27 8.97 29.66 30.95 6.72 6.75 1.21 1.42 5.47 1 5.72 0.96 2.44 0.35 2.37 0.4 8.29 5.95 6.84 6.32 6.15 7.96 1.5 165.77
Sample 8 1.23 9.6 0.22 1.23 12.57 0.28 0.3 0.44 16.72 0.17 2.99 0.54 7.05 1.69 23.6 61.28 11.98 73.96 1048.09 189.73 0.22 150.28 150.82 106.52 139.17 19.86 70.06 71.13 15.11 12.5 1.55 1.96 14.25 2.25 12.53 2.96 7.67 1.1 5.47 1.12 21.94 11.84 40.15 37.1 40.04 18.77 2.11 163.27
BHVO2 11.43 4.68 7.13 11.43 31.24 2.59 2.64 287.66 290.89 0.17 11.25 42.93 111.05 137.15 100.5 9.8 395.49 27.07 185.55 19.39 0.12 128.14 129.64 14.63 37.49 5.24 25.85 24.33 5.9 5.61 2 1.99 6.32 1.07 5.7 0.95 2.41 0.31 1.98 0.31 4.67 1.22 1.7 1.82 1.6 1.11 0.37 127.23