ALS 00-161B
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 325.01 1927462.93 65640.95 17975.73 706538.54 572846.26 281413.12 221182.03 1365655.71 305207.99 39737.31 27814.37 34656.47 23995.16 9225.79 289134.49 10711.79 35325.81 11399.36 281.81 12757.23 79250.92 7435.62 30595.68 3724.8 1386.86 2776.01 499.3 553.94 711.45 761.81 698.23 490.37 534.3 371.79 322.15 101.43 196.43 76.43 315.72 273.58 252.86 285.72 553.94 151.43 137.14 1717.98
Sample 1 637.97 16299.87 2944.02 3956.21 14212.7 12019.45 501.47 5814.43 732927.41 42083.2 521.49 1793.33 647.48 8019.7 51804.34 1340.5 20622.12 155429.66 98347.17 691.24 1440.63 9282.72 39389.55 94802.68 10544.08 2939.79 5971 836.48 836.43 200.7 217.63 1072.94 798.89 898.15 559.4 634.23 270.66 411.28 233.82 1421.48 2868.79 2622.76 2155.05 5436.09 1405.35 611.29 464.81
Sample 2 1313.45 92548.7 5989.01 8149 54346.43 45431.96 5999.92 7939.38 1289173.51 74618.27 1790.78 2143.71 2352.46 10692.38 88066.85 24872.82 34368.97 266855.02 156171.68 1655.59 6956.2 42965.04 67120.42 160486.26 18477.08 4926.17 10205.35 1518.55 1297.58 484.33 409.19 1824.47 1139.98 1464.45 1162.46 1093.21 465.34 610.73 400.96 2318.14 4938.97 3990.06 3273.49 8419.33 2471.93 1095.65 1200.36
Sample 3 857.35 12010.33 3417.39 4882.39 17428.8 14098.25 760.02 2837.4 827386.11 49759.28 532.86 936.77 2266.89 14992.08 67218.05 1977.1 22647.75 170721.09 112980.49 1075.53 1722.89 10817.64 42840.99 111521.9 12477.92 3219.48 6722.11 867.48 869.47 272.33 253.56 1241.53 781.26 915.07 712.96 661.79 265.01 409.76 271.93 1342.28 3227.66 1870.87 1581.79 4140.94 1659.45 958.58 553.03
Sample 4 655.8 9685.08 2557.27 3438.15 12048.25 9316.52 321.68 2333.91 495287.51 30158.44 1369.68 676.01 543.47 9910.15 41511.9 737.5 12739.35 99365.04 68008.27 613.14 1074.14 7489.95 28812.81 97254.87 8822.57 2391.31 5004.48 733.51 809.77 205.96 163.81 852.58 494.45 595.59 498.02 417.08 162.73 268.3 172.49 866.53 2132.83 1123.35 857.02 1997.79 1119.59 746.38 340.74
Sample 5 874.69 14862.72 4061.21 5425.88 18404 15330.73 613.72 8492.92 862524.07 48869.06 1876.74 1669.31 1716.9 7980.91 60250.2 2070.81 26500.4 206096.75 116823.4 786.61 1806.37 11087.38 51856.42 132696.42 14274.58 3822.17 7836.01 1303.23 988.78 338.11 257.48 1524.3 952.56 1038.15 917.72 795.4 384.85 546.65 262.42 1626.21 3456.39 4238.16 3664.93 8717.23 1984.38 852.66 582.97
Sample 6 712.63 21169.93 3757.72 5297.47 140104.54 113037.09 1399.14 4304.34 1116683.67 89405.83 466.84 1442.03 1028.44 15024.77 57962.12 2468.46 20299.98 169263.31 144599.53 841.62 2397.15 31110.81 43954.11 116729.2 13288.08 3481.44 6965.95 868.51 859.57 332.24 252.36 1253.73 825.33 971.58 679.32 743.09 339.07 447.07 239.06 1415.4 4023.19 1875.51 1476.6 3488.69 1603.07 914.75 497.9
Sample 7 810.05 10217.72 3436.69 5252.81 17576.32 14648.12 664.54 4747.43 863137.88 49783.08 562.67 1410.65 612.05 13949.49 62602.16 2089.32 22728.42 178307.89 113352.49 735.58 1790.71 11651.04 47032.67 120821.29 13856.28 3568 7224.58 1084.05 913.04 279.5 353.01 1326.07 921.04 1035.05 718.02 788.53 306.5 443.01 241 1541.6 3295.96 2818.39 2242.75 5264.28 1692.62 797.54 558.02
Sample 8 619.82 6220.1 2997.09 4254.79 17385.28 14470.29 642.54 738.1 694482.84 37840.12 961.25 1931.49 548.49 13219.2 49903.62 948.74 16758.32 131091.05 90155 861.2 1217.67 7654.24 33862.16 92416.2 10378.69 2703.35 5512.92 813.04 821.7 220.89 195.78 838.48 553.9 662.69 538.46 530.13 197.56 348.01 193.22 1018.6 2591.98 1019.06 836.92 2189.11 1358.42 755.58 398.12
BHVO2 291.52 1992970.69 68288.5 18926.86 711675.52 573625.1 269709.08 214604.74 1339111.86 310006.35 38367.7 26569.61 32294.8 22314.01 9569.31 284104.13 10320.13 34419.82 11353.76 155.03 12313.57 78479.29 7478.53 28864.28 3993 1119.86 2369.72 503.74 489.83 683.78 709.36 619.53 451.5 550.36 352.99 292.85 98.86 174.43 102.98 370.61 292.85 242.85 242.85 501.11 160.53 94.74 1710.1
Normalized Pk Intensities Select Stds
BHVO 1 0 29.36 1 0.27 10.76 8.73 4.29 3.37 20.8 4.65 0.61 0.42 0.53 0.37 0.14 4.4 0.16 0.54 0.17 0 0.19 1.21 0.11 0.47 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0 0 0 0 0.01 0 0 0.03
Sample 1 0.22 5.54 1 1.34 4.83 4.08 0.17 1.97 248.95 14.29 0.18 0.61 0.22 2.72 17.6 0.46 7 52.8 33.41 0.23 0.49 3.15 13.38 32.2 3.58 1 2.03 0.28 0.28 0.07 0.07 0.36 0.27 0.31 0.19 0.22 0.09 0.14 0.08 0.48 0.97 0.89 0.73 1.85 0.48 0.21 0.16
Sample 2 0.22 15.45 1 1.36 9.07 7.59 1 1.33 215.26 12.46 0.3 0.36 0.39 1.79 14.7 4.15 5.74 44.56 26.08 0.28 1.16 7.17 11.21 26.8 3.09 0.82 1.7 0.25 0.22 0.08 0.07 0.3 0.19 0.24 0.19 0.18 0.08 0.1 0.07 0.39 0.82 0.67 0.55 1.41 0.41 0.18 0.2
Sample 3 0.25 3.51 1 1.43 5.1 4.13 0.22 0.83 242.11 14.56 0.16 0.27 0.66 4.39 19.67 0.58 6.63 49.96 33.06 0.31 0.5 3.17 12.54 32.63 3.65 0.94 1.97 0.25 0.25 0.08 0.07 0.36 0.23 0.27 0.21 0.19 0.08 0.12 0.08 0.39 0.94 0.55 0.46 1.21 0.49 0.28 0.16
Sample 4 0.26 3.79 1 1.34 4.71 3.64 0.13 0.91 193.68 11.79 0.54 0.26 0.21 3.88 16.23 0.29 4.98 38.86 26.59 0.24 0.42 2.93 11.27 38.03 3.45 0.94 1.96 0.29 0.32 0.08 0.06 0.33 0.19 0.23 0.19 0.16 0.06 0.1 0.07 0.34 0.83 0.44 0.34 0.78 0.44 0.29 0.13
Sample 5 0.22 3.66 1 1.34 4.53 3.77 0.15 2.09 212.38 12.03 0.46 0.41 0.42 1.97 14.84 0.51 6.53 50.75 28.77 0.19 0.44 2.73 12.77 32.67 3.51 0.94 1.93 0.32 0.24 0.08 0.06 0.38 0.23 0.26 0.23 0.2 0.09 0.13 0.06 0.4 0.85 1.04 0.9 2.15 0.49 0.21 0.14
Sample 6 0.19 5.63 1 1.41 37.28 30.08 0.37 1.15 297.17 23.79 0.12 0.38 0.27 4 15.42 0.66 5.4 45.04 38.48 0.22 0.64 8.28 11.7 31.06 3.54 0.93 1.85 0.23 0.23 0.09 0.07 0.33 0.22 0.26 0.18 0.2 0.09 0.12 0.06 0.38 1.07 0.5 0.39 0.93 0.43 0.24 0.13
Sample 7 0.24 2.97 1 1.53 5.11 4.26 0.19 1.38 251.15 14.49 0.16 0.41 0.18 4.06 18.22 0.61 6.61 51.88 32.98 0.21 0.52 3.39 13.69 35.16 4.03 1.04 2.1 0.32 0.27 0.08 0.1 0.39 0.27 0.3 0.21 0.23 0.09 0.13 0.07 0.45 0.96 0.82 0.65 1.53 0.49 0.23 0.16
Sample 8 0.21 2.08 1 1.42 5.8 4.83 0.21 0.25 231.72 12.63 0.32 0.64 0.18 4.41 16.65 0.32 5.59 43.74 30.08 0.29 0.41 2.55 11.3 30.84 3.46 0.9 1.84 0.27 0.27 0.07 0.07 0.28 0.18 0.22 0.18 0.18 0.07 0.12 0.06 0.34 0.86 0.34 0.28 0.73 0.45 0.25 0.13
BHVO2 1 0 29.18 1 0.28 10.42 8.4 3.95 3.14 19.61 4.54 0.56 0.39 0.47 0.33 0.14 4.16 0.15 0.5 0.17 0 0.18 1.15 0.11 0.42 0.06 0.02 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0 0 0 0.01 0 0 0.03
Average Ratio (Standards) 0 29.27 1 0.28 10.59 8.56 4.12 3.26 20.21 4.59 0.58 0.41 0.5 0.35 0.14 4.28 0.16 0.52 0.17 0 0.19 1.18 0.11 0.44 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0 0 0 0.01 0 0 0.03
Rel. Deviation
(%)
10.47 0.43 0 0.85 2.28 2.7 5.8 4.93 4.18 1.69 5.27 6.03 7.78 7.92 0.21 4.04 5.43 4.63 3.08 43.59 5.3 3.49 2.39 6.91 2.12 17.82 13.94 2.17 11.47 5.6 7.83 11.23 8.62 0.7 6.46 9.52 4.61 11.17 18.19 8.53 2.02 5.65 14.24 9.87 1.33 28.56 3.12
Average Intensity (Standards) 308.27 1960216.81 66964.73 18451.3 709107.03 573235.68 275561.1 217893.39 1352383.79 307607.17 39052.51 27191.99 33475.64 23154.59 9397.55 286619.31 10515.96 34872.81 11376.56 218.42 12535.4 78865.1 7457.08 29729.98 3858.9 1253.36 2572.87 501.52 521.89 697.62 735.58 658.88 470.93 542.33 362.39 307.5 100.14 185.43 89.7 343.17 283.21 247.86 264.29 527.52 155.98 115.94 1714.04
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.94 7.25 11.43 30.61 2.66 2.67 300.85 299.9 0.17 11.2 44.6 115.73 140.32 104.55 9.81 402.16 27.41 190.03 19.92 0.13 133.9 132.25 15.04 39.08 5.32 27.31 26.64 6.09 6.49 2.04 2.07 6.85 1.02 5.42 1.05 2.66 0.34 2.2 0.26 4.19 1.18 1.68 1.77 1.72 1.16 0.51 131.92
Sample 1 0.49 9.34 0.06 0.49 6.49 0.05 0.05 0.52 7.59 0.09 1.49 0.56 7.18 2.52 33.64 53.06 1.8 50.81 804.99 165.5 0.3 14.56 14.91 76.71 116.59 14.5 55.73 55.17 9.83 9.43 0.55 0.57 10.14 1.59 8.77 1.51 5.04 0.88 4.44 0.77 18.17 11.94 16.73 12.88 16.28 10.4 2.17 34.36
Sample 2 0.64 12.28 0.21 0.64 8.54 0.13 0.13 3.94 6.62 0.1 1.68 1.24 5.49 5.86 28.65 57.62 21.28 54.09 882.8 167.87 0.46 44.9 44.09 83.49 126.07 16.23 59.65 60.23 11.39 9.34 0.85 0.68 11.01 1.45 9.13 2.01 5.55 0.96 4.21 0.84 18.92 13.13 16.26 12.49 16.11 11.68 2.48 56.68
Sample 3 0.56 12.21 0.04 0.56 7.79 0.06 0.06 0.76 3.6 0.1 1.71 0.56 3.65 8.6 61.19 66.98 2.58 54.29 860.26 184.98 0.45 16.94 16.91 81.17 133.44 16.69 59.38 60.43 9.91 9.54 0.73 0.64 11.42 1.52 8.69 1.88 5.11 0.83 4.3 0.87 16.69 13.07 11.61 9.2 12.07 11.95 3.31 39.78
Sample 4 0.44 9.77 0.04 0.44 5.74 0.04 0.04 0.34 3.1 0.06 1.09 1.51 2.76 2.16 42.33 43.29 1.01 31.96 523.94 116.52 0.27 11.05 12.25 57.13 121.77 12.35 46.15 47.08 8.77 9.29 0.58 0.44 8.2 1 5.92 1.37 3.37 0.54 2.95 0.58 11.28 9.04 7.3 5.21 6.09 8.44 2.7 25.65
Sample 5 0.67 12.55 0.05 0.67 8.72 0.07 0.07 0.62 10.87 0.1 1.69 1.99 6.55 6.56 32.81 60.48 2.72 64 1046.14 192.68 0.33 17.89 17.46 98.98 159.94 19.24 71.01 70.96 15 10.93 0.91 0.66 14.12 1.86 9.93 2.44 6.19 1.22 5.78 0.85 20.37 14.1 26.5 21.46 25.59 14.39 2.97 42.24
Sample 6 0.58 9.68 0.07 0.58 8.07 0.47 0.47 1.34 5.22 0.13 2.93 0.47 5.36 3.72 58.52 55.13 3.07 46.44 814 225.95 0.34 22.49 46.41 79.48 133.3 16.96 61.28 59.76 9.47 9 0.85 0.61 11 1.53 8.81 1.71 5.48 1.02 4.48 0.73 16.8 15.55 11.11 8.19 9.7 11.02 3.02 34.18
Sample 7 0.55 11.35 0.04 0.55 8.25 0.06 0.06 0.66 5.94 0.1 1.68 0.58 5.41 2.28 56.04 61.41 2.68 53.63 884.39 182.68 0.3 17.33 17.93 87.72 142.3 18.24 64.77 63.93 12.2 9.86 0.74 0.88 12 1.76 9.68 1.86 6 0.95 4.58 0.76 18.87 13.14 17.22 12.83 15.1 12 2.71 39.51
Sample 8 0.44 7.95 0.02 0.44 6.12 0.06 0.06 0.58 0.84 0.07 1.17 0.91 6.79 1.87 48.63 44.82 1.11 36.21 595.37 133.04 0.33 10.79 10.78 57.83 99.67 12.51 44.94 44.67 8.38 8.12 0.53 0.45 6.95 0.97 5.67 1.28 3.69 0.56 3.29 0.56 11.42 9.46 5.7 4.39 5.75 8.82 2.35 25.81
BHVO2 11.43 4.26 7.21 11.43 30.99 2.58 2.57 277.15 279.7 0.16 10.94 41.4 106.27 125.68 93.45 9.79 379.84 25.39 177.97 19.08 0.07 124.24 125.89 14.54 35.44 5.48 21.19 21.86 5.91 5.51 1.88 1.85 5.85 0.9 5.36 0.95 2.32 0.32 1.88 0.34 4.73 1.22 1.55 1.45 1.5 1.19 0.34 126.22