ALS 00-159A
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 186.88 1654025.36 56774.4 16231.87 615077.91 493771.66 241069.52 186601.21 1167886.8 254171.09 32265.02 23199.54 27200.54 19277.87 8241.99 242280.27 8816.84 29600.88 9707.57 219.66 10674.27 66718.83 6542.67 25980.12 3361.6 1027.89 2101.55 437.6 397.7 666.07 606.53 478.88 378.62 445.29 299.7 246.72 112.51 188.31 93.44 330.47 305.7 180.05 144.15 446.11 148.72 117.95 1237.86
Sample 1 667.6 64946 4568.21 6106.01 55917.54 45932.25 117.56 7812.83 991607.35 59477.85 205.4 1583.43 313.11 7037.88 54624.39 8011.44 20187.96 139647.48 86018.04 1056.07 5782.08 37202.68 35737.55 85281.37 9721.42 2546.42 5361.63 886.34 758.06 369.35 419.95 1025.05 800.92 853.01 717.29 641.09 288.69 492.87 228.87 1200.06 2677.1 4384.98 3646.66 8995.15 1671.55 614.31 773.84
Sample 2 563.99 33293.95 4537.4 5426.55 54705.3 45899.74 99.8 8158.58 920836.56 55858.73 336.67 1780.26 979.21 6227.23 52081.1 5709.94 20675.75 135439.91 74314.4 998.31 7099.14 46544.28 32710.43 77736.93 9013.01 2448.23 4888.24 765.54 724.43 372.79 389.73 1086.87 719.17 1002.9 633 723.98 309.68 445.07 265.52 1163.37 2505.34 5146.14 4625.11 10180.96 1458.34 521.12 1108.93
Sample 3 868.93 50123.89 4470.02 5546.54 46950.48 39322.87 227.32 9015.55 1045364.36 62971.73 350.42 1440.19 698.98 5982.03 68828.86 5964.96 32948.01 218561.19 109815.45 1266.84 2197.5 13813.61 52415.41 107110.25 13033.61 3484.41 7550.23 1214.45 1009.31 418.6 453.86 1641.33 1010.87 1398.08 1079.85 1148.84 527.28 687.82 401.33 1881.51 3488.71 6214.17 4915.61 11879.16 2402.66 831.74 574.21
Sample 4 650.77 27438.58 2753 4375.44 35749.7 28193 30.07 2727.12 632747.4 41730.31 118.69 935.83 301.96 9179.28 46045.58 1599.27 12841.79 88836.53 60972.54 801.64 1238.63 8809.32 22476.04 59999.06 6276.82 1626.05 3355.76 483.74 497.92 193.03 184.07 644.72 434.11 493.89 362.97 483.34 197.96 300 166.65 795.5 1822.91 1956.64 1647.68 3916.21 973.21 546.36 409.62
Sample 5 550.54 54684.49 2987.97 3246.62 30927.89 25504.33 192.93 16939.39 567019.27 36998.84 199.45 557.65 520.46 3053.68 36245.41 4858.92 21729.48 150526.9 61227.03 712.57 1730.02 10270.25 31741 59463.43 7684.13 2136.05 4430.47 720.87 619.12 194.3 283.97 1027.57 677.15 838.35 700.99 675.7 296.52 459.95 273.46 1202.48 2021.84 11602.25 9810.44 22314.28 1524.94 489.2 375.75
Sample 6 644.58 55861.92 3779.72 4533.99 47435.86 38921.01 10.29 11463.96 761839.96 47611.81 221.75 1748.74 283.53 4211.5 43379.95 5982.73 17961.58 119064.89 65339.83 775.51 5966.05 36395.11 28320.87 62703.14 7232.83 2084.42 4203.78 649.25 670.51 254.05 372.25 843.26 587.58 729.73 521.72 544.36 291.57 371.18 210.64 995.37 2122.64 7927.36 6895.05 15681.69 1239.11 504.9 791.07
Sample 7 791.2 48203.79 3552.42 4215.93 38799.42 31618.29 153.41 8636.65 896496.83 54454.03 366.4 1122.89 195.25 6553.21 65243.54 4053.53 26508.37 182671.43 101269.6 1081.77 1194.98 7547.1 39554.68 88124.47 10608.1 2788.42 5573.71 867.38 804.45 356.81 368.03 1077.6 750.36 1103.11 758.87 941.19 397.97 588.45 294.22 1469.82 3076.6 5866.7 4858.5 11542.6 1800.14 783.36 475.87
Sample 8 648.25 23305 2867.79 3417.27 36033.4 29074.35 138.4 8845.68 661962.1 42654.05 790.07 2068.18 240.19 5342.66 43127.67 3257.46 18064.31 122036.59 65258.25 781.93 1820.71 12334.58 27421.61 60422.55 7027.89 1907.31 3964.99 683.95 517.87 205.06 296.73 819.38 589 719.37 585.14 483.34 258.04 379.17 202.38 961.06 2010.02 5945.06 4853.48 11080.55 1031.6 378.58 379.47
BHVO2 269.5 1599523.33 55251.85 15690.58 586172.68 460708.9 228548.58 173296.51 1108367.84 229849.33 30680.29 20744.51 25072.64 17557.19 7743.55 226032.7 8166.68 27054.86 8800.41 357.62 9736.74 60243.86 6105.59 24168.34 3092.43 951.63 1884.37 370.75 323.89 531.44 638.12 528.3 354.99 450.15 250.29 286.37 64.51 179.98 73.31 246.47 257.26 157.11 215.91 391.06 102.42 90.91 1133.32
Normalized Pk Intensities Select Stds
BHVO 1 0 29.13 1 0.29 10.83 8.7 4.25 3.29 20.57 4.48 0.57 0.41 0.48 0.34 0.15 4.27 0.16 0.52 0.17 0 0.19 1.18 0.12 0.46 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0 0 0.01 0 0 0.02
Sample 1 0.15 14.22 1 1.34 12.24 10.05 0.03 1.71 217.07 13.02 0.04 0.35 0.07 1.54 11.96 1.75 4.42 30.57 18.83 0.23 1.27 8.14 7.82 18.67 2.13 0.56 1.17 0.19 0.17 0.08 0.09 0.22 0.18 0.19 0.16 0.14 0.06 0.11 0.05 0.26 0.59 0.96 0.8 1.97 0.37 0.13 0.17
Sample 2 0.12 7.34 1 1.2 12.06 10.12 0.02 1.8 202.94 12.31 0.07 0.39 0.22 1.37 11.48 1.26 4.56 29.85 16.38 0.22 1.56 10.26 7.21 17.13 1.99 0.54 1.08 0.17 0.16 0.08 0.09 0.24 0.16 0.22 0.14 0.16 0.07 0.1 0.06 0.26 0.55 1.13 1.02 2.24 0.32 0.11 0.24
Sample 3 0.19 11.21 1 1.24 10.5 8.8 0.05 2.02 233.86 14.09 0.08 0.32 0.16 1.34 15.4 1.33 7.37 48.89 24.57 0.28 0.49 3.09 11.73 23.96 2.92 0.78 1.69 0.27 0.23 0.09 0.1 0.37 0.23 0.31 0.24 0.26 0.12 0.15 0.09 0.42 0.78 1.39 1.1 2.66 0.54 0.19 0.13
Sample 4 0.24 9.97 1 1.59 12.99 10.24 0.01 0.99 229.84 15.16 0.04 0.34 0.11 3.33 16.73 0.58 4.66 32.27 22.15 0.29 0.45 3.2 8.16 21.79 2.28 0.59 1.22 0.18 0.18 0.07 0.07 0.23 0.16 0.18 0.13 0.18 0.07 0.11 0.06 0.29 0.66 0.71 0.6 1.42 0.35 0.2 0.15
Sample 5 0.18 18.3 1 1.09 10.35 8.54 0.06 5.67 189.77 12.38 0.07 0.19 0.17 1.02 12.13 1.63 7.27 50.38 20.49 0.24 0.58 3.44 10.62 19.9 2.57 0.71 1.48 0.24 0.21 0.07 0.1 0.34 0.23 0.28 0.23 0.23 0.1 0.15 0.09 0.4 0.68 3.88 3.28 7.47 0.51 0.16 0.13
Sample 6 0.17 14.78 1 1.2 12.55 10.3 0 3.03 201.56 12.6 0.06 0.46 0.08 1.11 11.48 1.58 4.75 31.5 17.29 0.21 1.58 9.63 7.49 16.59 1.91 0.55 1.11 0.17 0.18 0.07 0.1 0.22 0.16 0.19 0.14 0.14 0.08 0.1 0.06 0.26 0.56 2.1 1.82 4.15 0.33 0.13 0.21
Sample 7 0.22 13.57 1 1.19 10.92 8.9 0.04 2.43 252.36 15.33 0.1 0.32 0.05 1.84 18.37 1.14 7.46 51.42 28.51 0.3 0.34 2.12 11.13 24.81 2.99 0.78 1.57 0.24 0.23 0.1 0.1 0.3 0.21 0.31 0.21 0.26 0.11 0.17 0.08 0.41 0.87 1.65 1.37 3.25 0.51 0.22 0.13
Sample 8 0.23 8.13 1 1.19 12.56 10.14 0.05 3.08 230.83 14.87 0.28 0.72 0.08 1.86 15.04 1.14 6.3 42.55 22.76 0.27 0.63 4.3 9.56 21.07 2.45 0.67 1.38 0.24 0.18 0.07 0.1 0.29 0.21 0.25 0.2 0.17 0.09 0.13 0.07 0.34 0.7 2.07 1.69 3.86 0.36 0.13 0.13
BHVO2 1 0 28.95 1 0.28 10.61 8.34 4.14 3.14 20.06 4.16 0.56 0.38 0.45 0.32 0.14 4.09 0.15 0.49 0.16 0.01 0.18 1.09 0.11 0.44 0.06 0.02 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0.01 0 0 0 0 0 0 0 0.01 0 0 0.02
Average Ratio (Standards) 0 29.04 1 0.28 10.72 8.52 4.19 3.21 20.32 4.32 0.56 0.39 0.47 0.33 0.14 4.18 0.15 0.51 0.17 0.01 0.18 1.13 0.11 0.45 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0 0.01 0.01 0 0 0.01 0 0 0.02
Rel. Deviation
(%)
27.46 0.45 0 0.48 1.48 2.98 1.85 3.31 1.78 5.19 1.64 5.98 3.84 4.69 2.49 2.99 3.49 4.44 5.01 35.6 4.58 5.29 2.97 3.19 3.98 3.53 5.79 9.78 12.56 14 5.51 8.86 2.64 2.69 10.79 12.43 36.57 1.28 15.17 18.7 10.26 7.71 30.02 7.38 24.21 16.42 4.32
Average Intensity (Standards) 228.19 1626774.34 56013.12 15961.23 600625.29 477240.28 234809.05 179948.86 1138127.32 242010.21 31472.65 21972.03 26136.59 18417.53 7992.77 234156.48 8491.76 28327.87 9253.99 288.64 10205.5 63481.34 6324.13 25074.23 3227.02 989.76 1992.96 404.17 360.8 598.76 622.33 503.59 366.8 447.72 274.99 266.54 88.51 184.15 83.37 288.47 281.48 168.58 180.03 418.59 125.57 104.43 1185.59
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 3.71 7.25 11.43 30.9 2.65 2.68 292.78 296.58 0.17 11.48 43.5 115.7 136.61 102.28 9.97 399.26 27.05 189.77 20.19 0.07 133.25 133.9 15.1 38.1 5.55 24.85 25.24 6.42 6.53 2.15 1.88 5.95 0.98 5.29 1.08 2.27 0.42 2.06 0.33 5.05 1.29 1.7 1.27 1.7 1.38 0.47 133.01
Sample 1 0.88 12.7 0.27 0.88 11.15 0.23 0.24 0.14 11.91 0.14 2.58 0.27 7.57 1.51 35.81 63.38 12.66 59.4 858.57 171.58 0.33 69.22 71.6 79.1 119.94 15.4 59.05 61.76 12.46 11.94 1.15 1.25 12.22 1.98 9.71 2.47 5.66 1.02 5.17 0.78 17.59 10.81 39.68 30.78 32.78 14.83 2.35 79.74
Sample 2 0.73 8.89 0.12 0.73 8.21 0.19 0.2 0.1 10.31 0.11 2 0.36 7.06 3.91 26.26 50.09 7.48 50.43 690.25 122.87 0.26 70.45 74.26 60.01 90.62 11.83 47.06 46.67 8.92 9.46 0.96 0.96 10.74 1.47 9.47 1.81 5.3 0.91 3.87 0.75 14.13 8.38 38.6 32.37 30.75 10.73 1.65 94.72
Sample 3 0.84 16.01 0.2 0.84 9.81 0.19 0.2 0.26 13.31 0.14 2.64 0.44 6.67 3.26 29.48 77.35 9.13 93.89 1301.37 212.14 0.39 25.48 25.75 112.35 145.89 19.99 78.25 84.23 16.54 15.4 1.26 1.31 18.95 2.42 15.42 3.6 9.82 1.81 6.98 1.33 26.7 13.64 54.45 40.19 41.92 20.65 3.08 57.3
Sample 4 0.54 12.67 0.12 0.54 8.18 0.15 0.15 0.04 4.26 0.09 1.85 0.16 4.58 1.49 47.81 54.7 2.59 38.68 559.15 124.51 0.26 15.18 17.36 50.93 86.38 10.18 38.6 39.57 6.96 8.03 0.61 0.56 7.87 1.1 5.76 1.28 4.37 0.72 3.22 0.58 11.93 7.53 18.12 14.24 14.61 8.84 2.14 43.21
Sample 5 0.32 5.89 0.13 0.32 3.33 0.07 0.07 0.13 14.51 0.04 0.9 0.14 1.5 1.41 8.73 23.64 4.32 35.94 520.19 68.65 0.13 11.64 11.11 39.49 47.01 6.84 27.84 28.69 5.7 5.48 0.34 0.48 6.88 0.94 5.37 1.36 3.35 0.59 2.71 0.52 9.9 4.59 59.01 46.55 45.7 7.61 1.05 21.76
Sample 6 0.77 12.96 0.25 0.77 8.75 0.21 0.21 0.01 18.47 0.11 2.18 0.3 8.84 1.44 22.65 53.2 9.99 55.86 773.72 137.75 0.26 75.49 74.04 66.25 93.21 12.11 51.09 51.18 9.65 11.16 0.83 1.17 10.62 1.54 8.78 1.9 5.08 1.09 4.11 0.76 15.42 9.06 75.81 61.52 60.4 11.62 2.04 86.16
Sample 7 0.69 15.14 0.2 0.69 7.74 0.16 0.17 0.18 13.24 0.12 2.37 0.48 5.4 0.95 33.54 76.15 6.44 78.46 1129.75 203.2 0.34 14.39 14.61 88.07 124.67 16.9 65.04 64.58 12.27 12.75 1.11 1.1 12.92 1.87 12.64 2.63 8.36 1.42 6.21 1.01 21.67 12.5 53.4 41.26 42.31 16.07 3.01 49.33
Sample 8 0.59 13.04 0.1 0.59 6.6 0.16 0.16 0.17 14.25 0.1 1.95 1.08 10.46 1.22 28.74 52.9 5.44 56.19 793.15 137.6 0.26 23.04 25.1 64.16 89.83 11.77 46.75 48.28 10.16 8.62 0.67 0.93 10.32 1.54 8.66 2.13 4.51 0.97 4.2 0.73 14.89 8.58 56.86 43.31 42.68 9.68 1.53 41.34
BHVO2 11.43 5.49 7.21 11.43 30.7 2.59 2.56 285.22 283.02 0.16 10.66 42.5 106.3 129.39 95.72 9.63 382.74 25.75 178.23 18.81 0.12 124.89 124.24 14.48 36.42 5.25 23.65 23.26 5.58 5.47 1.77 2.04 6.75 0.94 5.49 0.92 2.71 0.24 2.02 0.27 3.87 1.11 1.52 1.95 1.53 0.97 0.37 125.13