ALS 00-159
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 453.66 1137835.31 47617 9735.71 493862.99 555694.9 275684.94 225937.25 1607166.84 290044.72 37962.65 30150.54 30860.83 22604.08 8831.24 220867.34 8652.64 29559.3 10317.68 314.74 9182.51 57611.49 5839.79 23921.77 3103.02 1001.61 2120.56 414.91 394.22 501.68 593.15 463.24 292.06 384.42 280.59 224.32 91.28 128.43 74.31 300.89 272.55 247.94 196.96 514.62 115.69 136.86 2323.37
Sample 1 1448.6 32954.18 2659.17 1585.38 51594.74 44868.6 167.59 17357.07 1397209.23 83344.09 135.84 3875.38 945.92 10275.65 72768.54 4921.65 28074.18 200833.24 125269.39 1666.1 1869.85 11762.01 41068.88 103872.92 12339.05 3138.88 6513.05 1009.81 866.02 388.99 422.49 1149.99 829.18 1081.14 781.59 788.9 352.15 521.17 293.71 1461.04 3441.32 7960.38 6682.65 16224.36 2301.24 1090.6 965.26
Sample 2 795.32 37315.35 2473.64 1570.25 42358.25 36450.92 180.27 35756 826466.08 54992.62 122.82 2984.84 1068.34 4643.83 40094.87 6716.35 20972.95 139936.92 68582.75 911.62 2975.57 18481.58 28680.8 60520.99 7780.29 2243.46 4502.29 735.53 674.45 287.51 326.9 893.86 589.97 788.78 589.03 623.69 276.51 413.51 264 1071.98 2126.26 20436.39 17642.21 42459.95 1588.47 615.87 1080.44
Sample 3 1324.98 30398.87 3230.7 1823.37 65115.84 55745.37 382.7 16337.72 1170863.46 78531.81 375.4 4561.96 2263.22 13252.68 59454.13 8350.18 20137.2 133903.58 84957.17 1228.45 9550.94 58381.78 29191.79 73573.75 8501.59 2349.45 4574.8 701.47 641.87 335.2 384.71 825.72 589.54 748.31 586.69 508.91 232.75 393.34 199.81 975.6 2282.24 6870.9 5909.16 13891.23 1458.07 769.12 2648.22
Sample 4 1085.21 33478.59 2500.79 1453.85 43605.74 37241.44 96.14 24687.41 931306.5 61714.5 279.99 3510.63 1263.16 9823.98 51886.94 4149.97 20391.35 138521.28 79666.05 1102.07 1542.77 9437.88 28168.52 66632.72 8083.27 2233.89 4435.63 722.56 685.92 263.67 306.88 815.07 564.4 802.52 624.35 557.24 271.38 340.13 198.15 1009.31 2122.89 11274.52 9436.66 22460.43 1446.4 698.51 771.54
Sample 5 1207.19 30178.54 2910.19 1565.17 53711.18 46829.3 108.74 32236.74 1330631.69 76774.31 399.01 4588.65 2348.16 10445.24 63806.45 4901.68 27123.04 188223.13 108308.16 1304.15 1073.53 6757.37 37914.19 89445.53 10915 3023.04 6066.34 914.66 885.18 324.25 387.14 1118.68 782.36 1086.79 775.76 791.84 323.89 500.82 283.09 1412.47 3052.29 16698.31 14022.13 34648.79 2089.61 886.78 663.82
Sample 6 2041.76 49988.79 4129.08 2367.15 82028.01 71091.96 157.12 18907.11 2146678.43 119296.16 452.2 5084.21 1681.68 19723.86 112818.78 11859.3 35028.54 252245.36 163926.62 2243.47 3640.17 23347.69 51251.15 137619.24 15468.57 4017.33 8232.88 1249.72 1094.84 510.51 553.67 1457.95 994.49 1316.12 1014.11 942.86 408.81 618.04 378.16 1811.97 4341.05 6437.32 5366.82 13077.99 2636.2 1534.39 1655.21
Sample 7 1173.37 27473.82 2801.26 1932.89 54691.23 47050.34 160.25 19488.87 1387390.35 85002.29 454.06 5411.36 4016.65 14613.18 72720.12 6640.88 24403.37 171781.44 113683.74 1512.02 2702 16499.39 35364.65 94303.16 10872.24 2779.35 5649.06 887.01 764.79 323.48 344.01 936.57 717.24 951.14 698.99 730.75 273.31 484.05 241.82 1340.54 2953.31 6904.89 5783 14144.99 1909.29 1008.12 1131.67
Sample 8 1273.3 28729.81 3290 1651.73 55367.74 48067.78 170.91 32251.62 1433294.48 92022.97 290.73 4860.11 1191.55 8814.76 77082.11 8100.7 37305.53 268435.37 135168.34 1568.94 1694.05 10887.86 50320.36 110726.04 13994.52 4015.14 7625.08 1195.92 1120.09 481.87 476.08 1339.5 973.96 1383.71 1057.6 991.71 426.03 660.91 404.05 1863.6 3656.01 12349.45 10173.42 24338.61 2639.94 1074.43 984.97
BHVO2 465.22 1194983.6 48879.99 9790.51 502030.64 568627.62 293077.52 243610.2 1766983.81 325629.22 40533.71 33444.93 33300.96 23936.29 9057 226755.91 8819 29630.88 10239.02 572.4 9163.84 58609.81 5963.17 24873.31 3107.11 1051.8 2021 397.02 348.32 566.6 574.77 465 346.68 388.55 260.43 208.15 110.45 117.94 67.29 283.98 288.24 274.5 181.7 543.44 140.2 155.22 2374.77
Normalized Pk Intensities Select Stds
BHVO 1 0.01 23.9 1 0.2 10.37 11.67 5.79 4.74 33.75 6.09 0.8 0.63 0.65 0.47 0.19 4.64 0.18 0.62 0.22 0.01 0.19 1.21 0.12 0.5 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Sample 1 0.54 12.39 1 0.6 19.4 16.87 0.06 6.53 525.43 31.34 0.05 1.46 0.36 3.86 27.37 1.85 10.56 75.52 47.11 0.63 0.7 4.42 15.44 39.06 4.64 1.18 2.45 0.38 0.33 0.15 0.16 0.43 0.31 0.41 0.29 0.3 0.13 0.2 0.11 0.55 1.29 2.99 2.51 6.1 0.87 0.41 0.36
Sample 2 0.32 15.09 1 0.63 17.12 14.74 0.07 14.45 334.11 22.23 0.05 1.21 0.43 1.88 16.21 2.72 8.48 56.57 27.73 0.37 1.2 7.47 11.59 24.47 3.15 0.91 1.82 0.3 0.27 0.12 0.13 0.36 0.24 0.32 0.24 0.25 0.11 0.17 0.11 0.43 0.86 8.26 7.13 17.16 0.64 0.25 0.44
Sample 3 0.41 9.41 1 0.56 20.16 17.25 0.12 5.06 362.42 24.31 0.12 1.41 0.7 4.1 18.4 2.58 6.23 41.45 26.3 0.38 2.96 18.07 9.04 22.77 2.63 0.73 1.42 0.22 0.2 0.1 0.12 0.26 0.18 0.23 0.18 0.16 0.07 0.12 0.06 0.3 0.71 2.13 1.83 4.3 0.45 0.24 0.82
Sample 4 0.43 13.39 1 0.58 17.44 14.89 0.04 9.87 372.4 24.68 0.11 1.4 0.51 3.93 20.75 1.66 8.15 55.39 31.86 0.44 0.62 3.77 11.26 26.64 3.23 0.89 1.77 0.29 0.27 0.11 0.12 0.33 0.23 0.32 0.25 0.22 0.11 0.14 0.08 0.4 0.85 4.51 3.77 8.98 0.58 0.28 0.31
Sample 5 0.41 10.37 1 0.54 18.46 16.09 0.04 11.08 457.23 26.38 0.14 1.58 0.81 3.59 21.93 1.68 9.32 64.68 37.22 0.45 0.37 2.32 13.03 30.74 3.75 1.04 2.08 0.31 0.3 0.11 0.13 0.38 0.27 0.37 0.27 0.27 0.11 0.17 0.1 0.49 1.05 5.74 4.82 11.91 0.72 0.3 0.23
Sample 6 0.49 12.11 1 0.57 19.87 17.22 0.04 4.58 519.89 28.89 0.11 1.23 0.41 4.78 27.32 2.87 8.48 61.09 39.7 0.54 0.88 5.65 12.41 33.33 3.75 0.97 1.99 0.3 0.27 0.12 0.13 0.35 0.24 0.32 0.25 0.23 0.1 0.15 0.09 0.44 1.05 1.56 1.3 3.17 0.64 0.37 0.4
Sample 7 0.42 9.81 1 0.69 19.52 16.8 0.06 6.96 495.27 30.34 0.16 1.93 1.43 5.22 25.96 2.37 8.71 61.32 40.58 0.54 0.96 5.89 12.62 33.66 3.88 0.99 2.02 0.32 0.27 0.12 0.12 0.33 0.26 0.34 0.25 0.26 0.1 0.17 0.09 0.48 1.05 2.46 2.06 5.05 0.68 0.36 0.4
Sample 8 0.39 8.73 1 0.5 16.83 14.61 0.05 9.8 435.65 27.97 0.09 1.48 0.36 2.68 23.43 2.46 11.34 81.59 41.08 0.48 0.51 3.31 15.29 33.66 4.25 1.22 2.32 0.36 0.34 0.15 0.14 0.41 0.3 0.42 0.32 0.3 0.13 0.2 0.12 0.57 1.11 3.75 3.09 7.4 0.8 0.33 0.3
BHVO2 1 0.01 24.45 1 0.2 10.27 11.63 6 4.98 36.15 6.66 0.83 0.68 0.68 0.49 0.19 4.64 0.18 0.61 0.21 0.01 0.19 1.2 0.12 0.51 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Average Ratio (Standards) 0.01 24.17 1 0.2 10.32 11.65 5.89 4.86 34.95 6.38 0.81 0.66 0.66 0.48 0.19 4.64 0.18 0.61 0.21 0.01 0.19 1.2 0.12 0.51 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Rel. Deviation
(%)
0.07 1.61 0 1.45 0.69 0.22 2.47 3.47 4.85 6.33 2.78 5.48 3.53 2.2 0.07 0.01 0.5 1.68 2.39 39.37 1.99 0.64 0.37 0.91 1.76 1.61 5.25 4.97 10.59 6.75 4.08 1.58 10.25 1.1 7.12 7.13 11.6 7.87 8.86 5.94 2.11 5.34 7.55 2 11.71 7.04 0.3
Average Intensity (Standards) 459.44 1166409.45 48248.5 9763.11 497946.82 562161.26 284381.23 234773.72 1687075.33 307836.97 39248.18 31797.73 32080.9 23270.19 8944.12 223811.62 8735.82 29595.09 10278.35 443.57 9173.18 58110.65 5901.48 24397.54 3105.06 1026.71 2070.78 405.96 371.27 534.14 583.96 464.12 319.37 386.48 270.51 216.23 100.86 123.18 70.8 292.43 280.4 261.22 189.33 529.03 127.94 146.04 2349.07
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.6 7.15 11.43 31.12 2.63 2.62 283.94 282.68 0.16 10.57 42.15 106.7 129.68 97.46 9.8 390.97 26.49 186.19 19.83 0.07 130.89 129.65 14.83 37.02 5.47 23.97 25.15 6.21 6.45 1.87 2.02 6.42 0.89 5.43 1.05 2.62 0.3 2.15 0.32 4.65 1.18 1.55 1.7 1.59 1.08 0.4 129.35
Sample 1 0.62 14.2 0.2 0.62 4.89 0.27 0.2 0.17 20.98 0.14 2.94 0.15 13.25 3.84 42.8 78.04 8.42 83.04 1222 232.58 0.36 25.75 25.57 100.74 155.29 21 72.58 74.62 14.6 13.69 1.4 1.39 15.4 2.44 14.76 2.83 8.89 1.13 8.44 1.22 21.8 14.42 48.08 55.62 48.37 20.71 3.08 51.91
Sample 2 0.59 7.95 0.23 0.59 4.95 0.22 0.17 0.18 44.1 0.08 1.98 0.13 10.41 4.43 19.74 43.88 11.72 63.3 868.81 129.93 0.2 41.81 41 71.79 92.32 13.51 52.93 52.63 10.85 10.88 1.05 1.1 12.21 1.77 10.99 2.17 7.17 0.9 6.83 1.12 16.32 9.09 125.94 149.83 129.16 14.59 1.77 59.29
Sample 3 0.77 13.28 0.19 0.77 5.76 0.34 0.26 0.39 20.19 0.12 2.83 0.41 15.95 9.4 56.45 65.21 14.6 60.91 833.21 161.31 0.27 134.49 129.79 73.23 112.48 14.8 55.56 53.6 10.37 10.37 1.23 1.29 11.31 1.77 10.45 2.17 5.86 0.76 6.52 0.85 14.89 9.78 42.44 50.3 42.35 13.42 2.22 145.65
Sample 4 0.59 10.89 0.21 0.59 4.6 0.23 0.17 0.1 30.56 0.09 2.23 0.31 12.29 5.25 41.91 57 7.27 61.78 863.36 151.51 0.24 21.76 21.02 70.78 102.04 14.09 52.91 52.06 10.7 11.1 0.97 1.03 11.18 1.7 11.22 2.31 6.43 0.89 5.64 0.84 15.43 9.11 69.75 80.45 68.59 13.33 2.02 42.5
Sample 5 0.69 12.08 0.19 0.69 4.94 0.28 0.22 0.11 39.79 0.13 2.76 0.44 16.02 9.73 44.43 69.89 8.56 81.93 1169.64 205.36 0.28 15.1 15 94.98 136.57 18.97 71.39 70.98 13.51 14.29 1.19 1.3 15.3 2.35 15.15 2.86 9.11 1.06 8.28 1.2 21.52 13.06 103 119.19 105.5 19.2 2.56 36.46
Sample 6 0.98 20.43 0.31 0.98 7.46 0.43 0.33 0.16 23.33 0.21 4.29 0.5 17.75 6.97 83.88 123.55 20.71 105.8 1567.17 310.76 0.49 51.18 51.83 128.37 210.08 26.88 94.85 96.31 18.45 17.67 1.87 1.86 19.93 2.98 18.34 3.74 10.84 1.34 10.22 1.6 27.6 18.57 39.7 45.61 39.81 24.22 4.42 90.89
Sample 7 0.66 11.71 0.17 0.66 6.08 0.29 0.22 0.16 23.99 0.14 3.05 0.5 18.84 16.6 61.98 79.42 11.56 73.51 1064.42 214.94 0.33 37.89 36.53 88.34 143.57 18.84 65.45 65.91 13.06 12.31 1.18 1.15 12.77 2.15 13.22 2.57 8.38 0.89 7.98 1.02 20.37 12.6 42.47 49.02 42.94 17.5 2.9 61.98
Sample 8 0.78 12.72 0.18 0.78 5.2 0.29 0.22 0.17 39.72 0.14 3.3 0.32 16.93 4.93 37.42 84.25 14.12 112.45 1664.5 255.74 0.34 23.77 24.12 125.79 168.69 24.27 94.61 89.03 17.62 18.04 1.76 1.59 18.28 2.92 19.25 3.9 11.38 1.39 10.91 1.71 28.34 15.61 76.01 86.29 73.94 24.21 3.09 53.98
BHVO2 11.43 4.6 7.31 11.43 30.48 2.61 2.62 294.06 296.92 0.17 11.57 43.85 115.3 136.32 100.54 9.8 391.03 26.31 181.81 19.17 0.12 127.25 128.49 14.75 37.5 5.33 24.53 23.35 5.79 5.55 2.05 1.9 6.28 1.03 5.35 0.95 2.36 0.36 1.93 0.28 4.27 1.22 1.67 1.53 1.63 1.27 0.44 128.79