ALS 00-157A
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 434.5 2854332.35 93700.38 23227.62 912026.42 752469.06 388321.92 302292.64 1942897.73 457261.64 55422.09 31483.19 50032.3 28964.87 13058.15 437080.23 13797.7 45911 15345.15 -22.2 17934.25 114987.68 10152.14 42192.05 5436.51 1805.43 3854.31 775.66 648.16 1173.73 1103.23 959.41 615.38 770.84 491.27 440.37 161.71 246.61 158.85 609.13 487.51 560.55 387.24 946.12 231.25 221.88 2744.78
Sample 1 615.54 23829.51 3618.23 5037.59 46364.1 36628.16 377.02 4864.95 821199.69 48086.07 273.57 -141.27 206.01 6618.1 51086.64 3402.16 20051.59 129420.82 70037.98 1071.14 3597.2 22816.72 29701.27 67527.96 7948.07 2175.19 4637.85 678.02 672.52 292.5 318.01 1063.55 661.02 794.53 593.02 656.02 292 375.51 250.5 1083.55 2215.72 5715.97 4396.36 11307.66 1457.59 470.51 780.04
Sample 2 1260.51 51940.53 6552.91 8683.25 79781.02 65323.52 1105.58 10103.59 1709661.84 94133.55 992.7 1147.68 733.72 13129.43 113565.98 6402.54 44896.52 320759.36 163847.84 2135.47 5325.66 35550.41 75440.93 167119.75 20589.23 5336.87 11421.17 1870.17 1667.88 625.73 867.58 2414.11 1357.84 2066.09 1523.97 1518.06 797.99 1090.05 539.81 2826.26 5207.17 11426.75 8704.69 21883.83 3420.48 1270.07 1111.08
Sample 3 490.95 21061.74 3200.01 3441.85 33886.81 27509.07 465.68 14126.9 528482.4 34477.85 329.34 689.43 248.79 3017.01 34526.75 1841.39 19387.72 109477.91 51225.23 623.78 2106.1 14437.93 27226.03 55024.56 7326.76 1970.45 4407.24 684.71 645.2 253.17 319.67 937.27 669.19 723.74 565.63 713.1 300.44 370.74 250.1 1044.83 1722.1 10415.61 8179.5 20962.33 1283.01 402.45 360.01
Sample 4 752.09 28425.81 3970.66 5146.37 47140.02 38362.37 435.06 10544.64 803734.87 49858.05 593.34 1072.15 381.31 5624.15 51856.63 3726.23 22191.37 145768.4 77140.6 989.23 4901.76 30703.94 34004.78 75025.38 9086.15 2521.73 5170.21 824.86 723.84 367.35 378.24 998.68 737.78 876.56 770.44 759.55 296.26 473.82 301.03 1219.46 2374.76 8232.14 6838.05 16466.38 1457.58 621.79 812.62
Sample 5 934.76 51192.96 6157.4 8026.67 77078.75 62359.1 882.33 8326.5 1264350.82 77146.6 447.26 1154.37 498.55 8933.57 83721.57 9507.96 30090.26 194201 115988.92 1258.93 8905.5 56732.91 47377.8 110841 12959.86 3386.31 6876.41 987.02 836.84 536.82 567.22 1481.58 909.11 1202.87 939.38 1063.52 432.59 613.81 316.61 1779.43 3477.74 7298.82 5504.11 13526.95 2158.8 915.24 1445.34
Sample 6 727.37 40300.57 4299.82 5419.1 51217.96 42846.45 1614.85 15764.79 831473.12 55244.05 414.76 1620.53 766.72 4880.85 56908 2985.55 25406.56 160733.23 75185.78 1301.84 4529.87 24798.05 37257.68 77352.98 10073.37 3094.79 6803.3 936.05 823.7 392.68 402.67 1087.73 787.7 991.72 977.72 871.38 283.67 406.34 348.01 1267.08 2740.07 13329.5 10741.91 26644.87 1575.12 331.34 745.7
Sample 7 742.6 31036.21 4849.41 6549.78 58182.91 48845.24 346.74 9701.62 1079615.36 63111.61 476.9 1215.14 603.91 6508.17 66044.16 1814.2 25690.97 166742.71 96842.51 1129.32 2539 16868.2 41449.53 94260.69 10929.58 3064.07 6475.77 1025.94 966.11 395.25 391.97 1208.4 826.82 1115.23 751.51 777.41 381.26 547.63 322.03 1331.32 2922.09 6988.3 5587.34 13437.24 1776.31 623.83 697.64
Sample 8 430.62 23835.32 3699.96 4401.89 43206.9 34595.12 308.45 16102.39 717813.84 48488.16 643.8 1974.67 291.13 4463.64 46172.35 4484.28 22568.55 148394.91 69382 969.76 4092.23 26582.47 34886.52 68467.96 8494.82 2483.22 4871.93 911.23 754.97 340.14 398.04 1037.45 710.67 786.44 774.27 705.29 318.98 487.4 287.4 1089.65 2284.05 11909.21 9387.63 22970.19 1553.32 471.07 702.99
BHVO2 316.59 1806956.04 62100.69 17680.01 656476.2 527301.53 258460.95 201344.78 1242347.15 273055.16 35601.97 24169.93 29304.2 21936.04 8843.1 259694.87 8948.91 31400.24 10367.99 118.18 10862.9 70197.88 6485.14 27384.55 3475.58 1116.19 2288.88 484.17 402.94 625.49 745.01 611.29 358.25 441.32 372.55 327.07 119.91 179.69 102.98 376.32 254.87 236.45 206.76 474.79 102.63 126.32 1474.37
Normalized Pk Intensities Select Stds
BHVO 1 0 30.46 1 0.25 9.73 8.03 4.14 3.23 20.74 4.88 0.59 0.34 0.53 0.31 0.14 4.66 0.15 0.49 0.16 0 0.19 1.23 0.11 0.45 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.03
Sample 1 0.17 6.59 1 1.39 12.81 10.12 0.1 1.34 226.96 13.29 0.08 -0.04 0.06 1.83 14.12 0.94 5.54 35.77 19.36 0.3 0.99 6.31 8.21 18.66 2.2 0.6 1.28 0.19 0.19 0.08 0.09 0.29 0.18 0.22 0.16 0.18 0.08 0.1 0.07 0.3 0.61 1.58 1.22 3.13 0.4 0.13 0.22
Sample 2 0.19 7.93 1 1.33 12.17 9.97 0.17 1.54 260.9 14.37 0.15 0.18 0.11 2 17.33 0.98 6.85 48.95 25 0.33 0.81 5.43 11.51 25.5 3.14 0.81 1.74 0.29 0.25 0.1 0.13 0.37 0.21 0.32 0.23 0.23 0.12 0.17 0.08 0.43 0.79 1.74 1.33 3.34 0.52 0.19 0.17
Sample 3 0.15 6.58 1 1.08 10.59 8.6 0.15 4.41 165.15 10.77 0.1 0.22 0.08 0.94 10.79 0.58 6.06 34.21 16.01 0.19 0.66 4.51 8.51 17.2 2.29 0.62 1.38 0.21 0.2 0.08 0.1 0.29 0.21 0.23 0.18 0.22 0.09 0.12 0.08 0.33 0.54 3.25 2.56 6.55 0.4 0.13 0.11
Sample 4 0.19 7.16 1 1.3 11.87 9.66 0.11 2.66 202.42 12.56 0.15 0.27 0.1 1.42 13.06 0.94 5.59 36.71 19.43 0.25 1.23 7.73 8.56 18.89 2.29 0.64 1.3 0.21 0.18 0.09 0.1 0.25 0.19 0.22 0.19 0.19 0.07 0.12 0.08 0.31 0.6 2.07 1.72 4.15 0.37 0.16 0.2
Sample 5 0.15 8.31 1 1.3 12.52 10.13 0.14 1.35 205.34 12.53 0.07 0.19 0.08 1.45 13.6 1.54 4.89 31.54 18.84 0.2 1.45 9.21 7.69 18 2.1 0.55 1.12 0.16 0.14 0.09 0.09 0.24 0.15 0.2 0.15 0.17 0.07 0.1 0.05 0.29 0.56 1.19 0.89 2.2 0.35 0.15 0.23
Sample 6 0.17 9.37 1 1.26 11.91 9.96 0.38 3.67 193.37 12.85 0.1 0.38 0.18 1.14 13.23 0.69 5.91 37.38 17.49 0.3 1.05 5.77 8.66 17.99 2.34 0.72 1.58 0.22 0.19 0.09 0.09 0.25 0.18 0.23 0.23 0.2 0.07 0.09 0.08 0.29 0.64 3.1 2.5 6.2 0.37 0.08 0.17
Sample 7 0.15 6.4 1 1.35 12 10.07 0.07 2 222.63 13.01 0.1 0.25 0.12 1.34 13.62 0.37 5.3 34.38 19.97 0.23 0.52 3.48 8.55 19.44 2.25 0.63 1.34 0.21 0.2 0.08 0.08 0.25 0.17 0.23 0.15 0.16 0.08 0.11 0.07 0.27 0.6 1.44 1.15 2.77 0.37 0.13 0.14
Sample 8 0.12 6.44 1 1.19 11.68 9.35 0.08 4.35 194.01 13.11 0.17 0.53 0.08 1.21 12.48 1.21 6.1 40.11 18.75 0.26 1.11 7.18 9.43 18.51 2.3 0.67 1.32 0.25 0.2 0.09 0.11 0.28 0.19 0.21 0.21 0.19 0.09 0.13 0.08 0.29 0.62 3.22 2.54 6.21 0.42 0.13 0.19
BHVO2 1 0.01 29.1 1 0.28 10.57 8.49 4.16 3.24 20.01 4.4 0.57 0.39 0.47 0.35 0.14 4.18 0.14 0.51 0.17 0 0.17 1.13 0.1 0.44 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0 0 0 0.01 0 0 0.02
Average Ratio (Standards) 0 29.78 1 0.27 10.15 8.26 4.15 3.23 20.37 4.64 0.58 0.36 0.5 0.33 0.14 4.42 0.15 0.5 0.17 0 0.18 1.18 0.11 0.45 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0 0 0 0.01 0 0 0.03
Rel. Deviation
(%)
6.7 3.24 0 9.77 5.83 3.94 0.3 0.35 2.53 7.36 2.21 10.38 8.73 9.42 1.53 7.72 1.53 2.22 1.36 181.64 6.36 5.81 2.6 1.48 2.55 4.91 7.76 4.24 4.53 15.36 1.33 2.79 9.16 10.33 9.51 8.04 7.93 6.7 1.56 4.96 16.7 31.42 15.23 19.54 27.98 10.73 14.8
Average Intensity (Standards) 375.55 2330644.19 77900.54 20453.81 784251.31 639885.29 323391.44 251818.71 1592622.44 365158.4 45512.03 27826.56 39668.25 25450.45 10950.63 348387.55 11373.3 38655.62 12856.57 47.99 14398.57 92592.78 8318.64 34788.3 4456.05 1460.81 3071.6 629.92 525.55 899.61 924.12 785.35 486.81 606.08 431.91 383.72 140.81 213.15 130.91 492.72 371.19 398.5 297 710.45 166.94 174.1 2109.58
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.38 7.4 11.43 28.67 2.51 2.55 288.39 289.08 0.17 11.65 43.67 102.86 141.21 92.41 9.69 412.34 26.69 181.11 19.31 -0.03 134.88 134.37 15.06 37.65 5.5 25.09 25.58 6.18 6.19 2.17 1.94 6.48 1.02 5.78 0.93 2.35 0.31 1.94 0.3 4.62 1.34 1.97 1.78 1.83 1.41 0.45 142.58
Sample 1 0.5 7.03 0.07 0.5 7.04 0.14 0.14 0.32 5.27 0.08 1.39 0.24 -0.52 0.66 23.89 42.92 3.63 43.89 577.78 99.75 1.5 30.62 30.17 49.87 68.2 9.1 34.21 34.83 6.11 7.27 0.61 0.63 8.12 1.24 6.75 1.27 3.96 0.64 3.35 0.54 9.29 6.9 22.72 22.93 24.8 10.04 1.09 45.86
Sample 2 0.25 4.03 0.04 0.25 3.39 0.07 0.07 0.26 3.06 0.05 0.76 0.25 1.19 0.66 13.26 26.7 1.91 27.49 400.64 65.29 0.84 12.68 13.15 35.44 47.22 6.59 23.49 24 4.72 5.05 0.37 0.48 5.16 0.71 4.91 0.92 2.56 0.49 2.72 0.33 6.78 4.54 12.71 12.7 13.43 6.59 0.82 18.28
Sample 3 0.47 5.96 0.07 0.47 5.11 0.11 0.11 0.42 16.25 0.06 1.06 0.31 2.71 0.84 11.58 30.83 2.09 45.1 519.45 77.54 0.93 19.05 20.29 48.59 59.06 8.91 32.94 35.18 6.56 7.41 0.56 0.68 7.61 1.33 6.53 1.29 4.57 0.7 3.51 0.57 9.52 5.7 44 45.34 48.87 9.39 0.99 22.49
Sample 4 0.49 7.73 0.08 0.49 6.47 0.13 0.13 0.33 10.28 0.07 1.29 0.48 3.57 1.1 18.29 39.24 3.58 43.74 586.04 98.94 1.25 37.57 36.57 51.42 68.23 9.36 35.72 34.97 6.7 7.05 0.69 0.68 6.87 1.25 6.7 1.49 4.13 0.58 3.81 0.59 9.42 6.66 29.47 32.11 32.52 9.04 1.29 43.02
Sample 5 0.71 8.87 0.12 0.71 9.32 0.2 0.2 0.62 7.49 0.1 1.85 0.33 3.55 1.32 26.82 58.49 8.44 54.77 720.96 137.38 1.47 63.03 62.39 66.15 93.08 12.33 44.29 42.95 7.4 7.52 0.94 0.94 9.41 1.42 8.49 1.68 5.34 0.78 4.55 0.57 12.69 9.01 24.13 23.87 24.67 12.37 1.76 70.66
Sample 6 0.17 2.43 0.03 0.17 2.22 0.05 0.05 0.4 5 0.02 0.47 0.11 1.75 0.72 5.16 14 0.93 16.28 210.13 31.36 0.53 11.29 9.6 18.32 22.88 3.38 14.26 14.96 2.47 2.61 0.24 0.23 2.43 0.43 2.47 0.62 1.54 0.18 1.06 0.22 3.18 2.5 15.52 16.4 17.11 3.18 0.22 12.84
Sample 7 0.71 9.03 0.1 0.71 9.75 0.19 0.2 0.31 11.19 0.11 1.94 0.45 4.79 2.06 25.03 59.12 2.06 59.91 793.06 146.95 1.69 23.02 23.77 74.15 101.41 13.33 51.35 51.82 9.86 11.13 0.88 0.83 9.83 1.65 10.09 1.72 5 0.89 5.2 0.74 12.17 9.7 29.6 31.04 31.4 13.04 1.53 43.69
Sample 8 0.52 5.03 0.07 0.52 6.29 0.14 0.14 0.27 17.83 0.07 1.43 0.59 7.47 0.95 16.49 39.69 4.9 50.54 677.83 101.11 1.39 35.64 35.97 59.93 70.75 9.95 39.96 37.44 8.41 8.35 0.73 0.81 8.11 1.36 6.83 1.7 4.36 0.71 4.45 0.64 9.56 7.28 48.44 50.09 51.55 10.95 1.11 42.29
BHVO2 11.43 4.82 7.06 11.43 32.93 2.73 2.69 289.61 290.52 0.16 10.49 42.33 119.14 124.79 105.59 9.91 369.66 26.11 186.89 19.69 0.22 123.26 123.77 14.52 36.87 5.3 23.41 22.92 5.82 5.81 1.75 1.98 6.22 0.9 5 1.07 2.63 0.35 2.14 0.3 4.3 1.06 1.25 1.44 1.39 0.94 0.39 115.56