ALS 00-146D
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 1009.26 3658374.35 118798.5 14051.78 1188593.42 1126403.21 581101.64 439408.43 4758239.73 726934.23 106308.34 72671.41 93972.4 39310.22 25105.32 734470.81 22538.51 73378.8 25370.27 350.78 33144.23 216436.99 15649.14 61889.12 10060.86 3709.27 7355.56 1649.65 1514.41 2432.37 2830.39 2233.55 1482.28 1847.78 1238.6 1180.12 468.9 746.67 326.83 1300.13 1293.89 1667.96 1397.45 3387.3 667.26 841.33 6858.56
Sample 1 4127.41 195542.25 3437.02 4268.03 92255.7 70948.74 33333.63 42759.3 1771110.8 165033.63 11794.98 10375.27 50537.89 27696.09 171615.41 31768.83 34890.64 284638.41 172181.81 7416.64 20112.77 119673.75 57225.68 177181.67 17372.93 4395.87 9034.12 1472.81 1158.05 514.95 571.03 1554.65 1063.3 1413.78 1164.08 1011.17 473.11 682.86 376.44 2103.39 4878.55 6367.09 5532.1 13523.06 4233.2 2430.5 4989.64
Sample 2 4167.42 114499.97 3114.42 3675.4 71227.96 61485.8 17617.41 26696.21 1860896.91 132920.89 7143.39 6171.61 11444.77 25887.51 167366.83 17946.48 45114.93 403787.6 208147.09 6626.22 10642.93 69480.36 69643.96 191834.75 20681.21 5376.57 10893.14 1693.3 1471.82 546.68 516.03 1901.74 1299.96 1853.72 1375.93 1405.26 587.3 951.92 486.58 3020.69 6257.46 11488.47 9591.57 22956.43 5156.07 2978.92 3350.09
Sample 3 3519.1 92826.26 2356.11 2768.78 58759.06 50629.08 17408.26 19003.49 1405401.12 108445.74 6654.15 6625.06 19290.92 21023.61 124003.29 16467.66 36568.55 260274.57 146259.34 5314.32 9516.2 61191.69 45607.09 127070.06 13487.82 3346.15 6672.69 1115.49 984.67 336.15 459.06 1279.03 985.66 1697.72 929.37 1028.81 428.77 711.78 389.34 1913.12 4065.49 4686.63 3789.98 9030.15 3600.24 2608.18 2861.22
Sample 4 1253.67 16307.79 1604.93 1176.81 34516 31009.76 1647.43 7337.32 637261.18 52262.18 1246.54 2853.17 4714.3 14227.25 63067.65 2631.7 12940.78 100963.19 65770.86 1321.4 884.65 5427.56 18786.66 58033.79 6096.14 1610.81 3174.24 477.68 422.69 122.11 133.68 529.04 370.98 479.38 390.14 380.51 164.4 258.85 145.58 753.43 1634.28 2425.59 2027.66 4993.66 974.88 769.2 687.12
Sample 5 4308.38 46820 3109.9 2837.13 56455.21 48639.81 6231.91 16649.08 1700696.61 105099.65 3080.9 4629.47 4521.34 27010.12 153571.77 12398.5 47585.34 456316.87 209011.73 5463.22 5768.06 35373.31 69244.94 172617.17 19397.7 5231.51 10077.44 1583.51 1432.27 455.06 506.81 1898.67 1321.39 1709.44 1428.97 1400.67 651.18 936.01 475.05 2998.76 6021.6 6497.91 5320.21 12857.07 5094.45 3055.36 2106.94
Sample 6 3922.58 38059.5 2509.49 2539.12 50277.01 42486.1 6939.78 8859.39 1508997.8 99761.67 2737.33 5408.53 3859.18 30714.33 149071.63 10153.97 34886.07 334268.75 188767.77 5049.44 4735.42 28878.58 53883.19 152548.47 16217.44 3944.42 8198.43 1260.15 1095.69 384.92 400.96 1374.54 971.28 1372.89 1071.68 1064.19 435.47 716.8 365.02 2377.45 5187.77 3947.58 3292.83 8000.06 4019.49 3025 1780.33
Sample 7 5022 164144.08 4494.11 4434.18 91162.9 80034.6 27061.34 37189.84 2023287 166721.45 10399.52 8877.29 25434.25 25384.75 176147.8 32925.51 49974.11 459999.74 233814.72 7515.21 17582.55 112315.69 73943.13 200338.7 21053.33 5293.94 11179.29 1693.15 1450.45 534.25 555.93 1966.02 1429.83 1965.02 1488.63 1484.07 664.37 1004.14 529.35 3174.61 6594.57 13290.11 10778.85 26798.45 5677.08 2927.7 4854.11
Sample 8 4765.46 99168.55 3548.05 3910.33 81168.93 67650.32 18191.89 24283.8 2161611.23 145734.12 7342.42 7277.52 19862.35 33862.26 192390.51 19933.98 45466.2 407776.92 233950.82 7475.93 11729.36 72962.59 69005.13 193357.36 20437.59 5266.78 10187.22 1509.49 1440.01 493.78 488.76 1771.63 1245.25 1658.33 1341.78 1331.49 539.61 828.13 476.37 2858.4 6458.15 8160.19 6686.35 16510.89 5089.55 3492.77 3652.12
BHVO2 516.79 1252679.5 50289.58 10232.04 518251.93 580803 285659.16 260095.27 1830493.34 351255.14 41089.79 32848.84 34090.96 23917.73 9152.31 242917.68 9053.34 31062.94 10761.18 435.92 9980.72 61227.46 6134.72 24884.76 3345.77 1018.64 2199.9 411.68 407.86 582.16 654.04 499.1 339.58 391.46 307.05 239.83 90.95 135.64 77.08 287.5 257.8 277.71 231.43 528.81 157.17 176.24 2598.74
Normalized Pk Intensities Select Stds
BHVO 1 0.01 30.79 1 0.12 10.01 9.48 4.89 3.7 40.05 6.12 0.89 0.61 0.79 0.33 0.21 6.18 0.19 0.62 0.21 0 0.28 1.82 0.13 0.52 0.08 0.03 0.06 0.01 0.01 0.02 0.02 0.02 0.01 0.02 0.01 0.01 0 0.01 0 0.01 0.01 0.01 0.01 0.03 0.01 0.01 0.06
Sample 1 1.2 56.89 1 1.24 26.84 20.64 9.7 12.44 515.3 48.02 3.43 3.02 14.7 8.06 49.93 9.24 10.15 82.82 50.1 2.16 5.85 34.82 16.65 51.55 5.05 1.28 2.63 0.43 0.34 0.15 0.17 0.45 0.31 0.41 0.34 0.29 0.14 0.2 0.11 0.61 1.42 1.85 1.61 3.93 1.23 0.71 1.45
Sample 2 1.34 36.76 1 1.18 22.87 19.74 5.66 8.57 597.51 42.68 2.29 1.98 3.67 8.31 53.74 5.76 14.49 129.65 66.83 2.13 3.42 22.31 22.36 61.6 6.64 1.73 3.5 0.54 0.47 0.18 0.17 0.61 0.42 0.6 0.44 0.45 0.19 0.31 0.16 0.97 2.01 3.69 3.08 7.37 1.66 0.96 1.08
Sample 3 1.49 39.4 1 1.18 24.94 21.49 7.39 8.07 596.49 46.03 2.82 2.81 8.19 8.92 52.63 6.99 15.52 110.47 62.08 2.26 4.04 25.97 19.36 53.93 5.72 1.42 2.83 0.47 0.42 0.14 0.19 0.54 0.42 0.72 0.39 0.44 0.18 0.3 0.17 0.81 1.73 1.99 1.61 3.83 1.53 1.11 1.21
Sample 4 0.78 10.16 1 0.73 21.51 19.32 1.03 4.57 397.06 32.56 0.78 1.78 2.94 8.86 39.3 1.64 8.06 62.91 40.98 0.82 0.55 3.38 11.71 36.16 3.8 1 1.98 0.3 0.26 0.08 0.08 0.33 0.23 0.3 0.24 0.24 0.1 0.16 0.09 0.47 1.02 1.51 1.26 3.11 0.61 0.48 0.43
Sample 5 1.39 15.06 1 0.91 18.15 15.64 2 5.35 546.87 33.8 0.99 1.49 1.45 8.69 49.38 3.99 15.3 146.73 67.21 1.76 1.85 11.37 22.27 55.51 6.24 1.68 3.24 0.51 0.46 0.15 0.16 0.61 0.42 0.55 0.46 0.45 0.21 0.3 0.15 0.96 1.94 2.09 1.71 4.13 1.64 0.98 0.68
Sample 6 1.56 15.17 1 1.01 20.03 16.93 2.77 3.53 601.32 39.75 1.09 2.16 1.54 12.24 59.4 4.05 13.9 133.2 75.22 2.01 1.89 11.51 21.47 60.79 6.46 1.57 3.27 0.5 0.44 0.15 0.16 0.55 0.39 0.55 0.43 0.42 0.17 0.29 0.15 0.95 2.07 1.57 1.31 3.19 1.6 1.21 0.71
Sample 7 1.12 36.52 1 0.99 20.28 17.81 6.02 8.28 450.21 37.1 2.31 1.98 5.66 5.65 39.2 7.33 11.12 102.36 52.03 1.67 3.91 24.99 16.45 44.58 4.68 1.18 2.49 0.38 0.32 0.12 0.12 0.44 0.32 0.44 0.33 0.33 0.15 0.22 0.12 0.71 1.47 2.96 2.4 5.96 1.26 0.65 1.08
Sample 8 1.34 27.95 1 1.1 22.88 19.07 5.13 6.84 609.24 41.07 2.07 2.05 5.6 9.54 54.22 5.62 12.81 114.93 65.94 2.11 3.31 20.56 19.45 54.5 5.76 1.48 2.87 0.43 0.41 0.14 0.14 0.5 0.35 0.47 0.38 0.38 0.15 0.23 0.13 0.81 1.82 2.3 1.88 4.65 1.43 0.98 1.03
BHVO2 1 0.01 24.91 1 0.2 10.31 11.55 5.68 5.17 36.4 6.98 0.82 0.65 0.68 0.48 0.18 4.83 0.18 0.62 0.21 0.01 0.2 1.22 0.12 0.49 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Average Ratio (Standards) 0.01 27.85 1 0.16 10.16 10.52 5.29 4.44 38.23 6.55 0.86 0.63 0.73 0.4 0.2 5.51 0.18 0.62 0.21 0.01 0.24 1.52 0.13 0.51 0.08 0.03 0.05 0.01 0.01 0.02 0.02 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0.01 0.02 0 0.01 0.05
Rel. Deviation
(%)
13.42 14.94 0 37.44 2.09 13.9 10.55 23.49 6.76 9.34 6.43 4.64 10.89 25.37 10.55 17.36 3.71 0 0.14 69.55 23.85 28.12 5.43 3.64 16.98 30.13 24.32 36.52 31.44 39.26 41.54 43.7 42.1 47.08 36.96 49.68 52.55 56.49 40.22 44.37 50.9 61.58 61.88 65.22 40.3 47.79 7.83
Average Intensity (Standards) 763.02 2455526.92 84544.04 12141.91 853422.68 853603.1 433380.4 349751.85 3294366.54 539094.69 73699.06 52760.12 64031.68 31613.97 17128.82 488694.25 15795.92 52220.87 18065.72 393.35 21562.48 138832.22 10891.93 43386.94 6703.31 2363.95 4777.73 1030.66 961.14 1507.26 1742.22 1366.33 910.93 1119.62 772.82 709.97 279.92 441.16 201.96 793.81 775.84 972.83 814.44 1958.05 412.21 508.78 4728.65
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.16 7.99 11.43 22.65 2.58 2.36 267.44 241.67 0.17 10.34 44.95 107.36 143.24 81.24 10.53 439.01 27.09 184 19.48 0.05 150.84 154.74 15.36 38.22 6.05 29.42 28.42 7.55 7.33 2.5 2.54 8.31 1.24 7.18 1.26 3.36 0.45 2.85 0.39 5.86 1.63 2.31 2.32 2.35 1.51 0.56 136.22
Sample 1 0.34 17.73 0.44 0.34 7.16 0.21 0.15 15.97 24.48 0.07 2.44 5.19 15.96 80.19 59.58 74.94 19.77 43.66 743 137.63 1.08 95.29 89.07 58.46 113.9 10.87 36.29 36.34 7.02 5.84 0.55 0.53 6.02 0.93 5.72 1.23 3 0.48 2.72 0.46 9.87 6.41 9.19 9.54 9.78 9.97 1.69 103.16
Sample 2 0.37 21.32 0.31 0.37 7.35 0.19 0.16 10.06 18.21 0.08 2.34 3.75 11.31 21.64 66.35 87.07 13.3 67.26 1255.75 198.22 1.15 60.07 61.61 84.77 146.92 15.42 52.88 52.2 9.61 8.84 0.7 0.57 8.78 1.35 8.94 1.74 4.97 0.7 4.51 0.71 16.88 9.79 19.75 19.71 19.79 14.47 2.47 82.52
Sample 3 0.31 19.58 0.27 0.31 6.02 0.17 0.14 10.8 14.09 0.07 2.08 3.79 13.2 39.65 58.59 70.14 13.27 59.28 880.08 151.44 1 58.4 58.99 60.36 105.81 10.93 35.78 34.77 6.88 6.43 0.47 0.55 6.42 1.11 8.9 1.28 3.96 0.56 3.67 0.62 11.63 6.91 8.76 8.47 8.46 10.99 2.35 76.63
Sample 4 0.22 7.25 0.05 0.22 2.66 0.11 0.09 1.06 5.66 0.03 1.04 0.74 5.91 10.08 41.23 37.1 2.21 21.81 355.02 70.82 0.26 5.65 5.44 25.85 50.26 5.14 17.91 17.2 3.07 2.87 0.18 0.17 2.76 0.44 2.61 0.56 1.52 0.22 1.39 0.24 4.76 2.89 4.72 4.71 4.87 3.09 0.72 19.14
Sample 5 0.34 20.25 0.12 0.34 5.21 0.14 0.12 3.27 10.43 0.07 1.7 1.48 7.79 7.85 63.59 73.38 8.44 65.16 1303.44 182.82 0.87 29.9 28.81 77.41 121.43 13.28 47.26 44.36 8.26 7.9 0.53 0.52 8.05 1.26 7.57 1.66 4.55 0.72 4.08 0.64 15.39 8.65 10.26 10.04 10.18 13.13 2.33 47.67
Sample 6 0.33 22.24 0.11 0.33 5.62 0.15 0.12 4.39 6.7 0.08 1.95 1.59 10.98 8.08 87.22 85.93 8.34 57.62 1151.77 199.17 0.97 29.61 28.37 72.66 129.45 13.4 42.98 43.53 7.92 7.29 0.54 0.49 7.03 1.12 7.34 1.5 4.17 0.58 3.77 0.59 14.72 8.99 7.52 7.5 7.64 12.5 2.78 48.59
Sample 7 0.61 29.16 0.5 0.61 10.06 0.28 0.24 17.53 28.78 0.1 3.34 6.19 18.46 54.56 73.82 103.98 27.69 84.53 1623.2 252.65 1.48 112.61 113 102.12 174.1 17.81 59.08 60.79 10.9 9.88 0.77 0.7 10.3 1.69 10.75 2.13 5.95 0.9 5.4 0.88 20.13 11.7 25.93 25.14 26.21 18.08 2.76 135.67
Sample 8 0.48 27.6 0.3 0.48 8.85 0.25 0.2 11.75 18.75 0.11 2.91 4.36 15.09 42.51 98.24 113.3 16.73 76.73 1435.52 252.2 1.47 74.94 73.23 95.07 167.63 17.25 58.64 55.26 9.7 9.79 0.71 0.61 9.26 1.47 9.05 1.92 5.33 0.73 4.45 0.79 18.09 11.44 15.88 15.56 16.11 16.17 3.28 101.83
BHVO2 11.43 5.04 6.47 11.43 38.95 2.66 2.88 310.56 337.93 0.16 11.8 41.05 114.64 122.76 116.76 9.07 342.99 25.71 184 19.52 0.14 107.3 103.4 14.22 36.3 4.75 19.08 20.08 4.45 4.67 1.42 1.38 4.39 0.67 3.6 0.74 1.62 0.21 1.23 0.21 3.06 0.77 0.91 0.91 0.87 0.84 0.28 121.92