ALS 00-146B
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 527.19 1128357.07 46045.79 9613.73 488407.15 532962.95 266997.69 231763.85 1670153.38 301433.95 39062.92 29869.43 31179.57 22629.22 8449.21 220064.48 8698.53 29467.35 10097 355.25 8881.51 56860.24 5676.21 23394.28 3029.28 944.36 1952.01 397.5 337.51 559.8 668.98 474.95 316.21 357.3 286.54 220.23 93.22 140.01 79.94 278.25 261.32 252.05 179.31 484.23 146.08 144.92 2344.72
Sample 1 2172.52 36256.88 2224.61 2158.57 103036.65 88308.86 510.59 6554.07 2142320.69 120997.9 459.3 4581.71 1029 41264.37 116163.67 1437.48 25532.96 176846.48 136753.39 2917.26 694.53 4509.44 38754.31 123109.53 13091.05 3402 6716.13 1050.25 915.46 502.19 577.79 1134.13 834.26 1093.55 820.81 773.93 323.22 492.67 347.33 1369.22 3373.26 2079.75 1729.69 4126 2006.91 1786.05 1090.1
Sample 2 2392.57 36479.23 2205.35 2321.24 102765.38 90181.56 887.47 8351.8 2199712.71 126096.08 564.85 4358.96 1658.45 39045.23 111708.17 1495.11 23950.97 164072.33 129408.12 2802.93 743.27 4630.88 34947.89 114548.55 12007.19 3080 6113.58 959.16 862.56 523.89 503.19 1006.25 735.28 1017.1 742.2 710.26 303.43 491.68 253.42 1233.15 3182.36 1892.72 1569.31 3661.95 1904.57 1802.17 1010.04
Sample 3 2782.96 167804.22 3136.63 3519.7 91996.79 79881.66 27831.82 27060.23 1604500.8 124891.04 7490 7152.82 9083.06 23351.92 98404.78 21344.79 21768.31 122206.7 85162.14 3747.53 10478.17 65667.68 30891.04 88804.4 9809.76 2607.2 5040.07 785.9 729.26 458.89 499.7 906.64 647.64 837.87 632.84 631.82 257.04 396.32 206.04 997.94 2320.77 7336.64 6236.64 14801.73 2652.5 1395.8 2932.29
Sample 4 1662.94 42139.14 1641.54 1999.2 75199.27 65380.76 4464.61 9712.88 1763363.28 98448.72 1632.31 4584.82 3178.6 20837.75 78013.49 3498.53 19517.91 131126.52 92387.2 2522.86 2306.31 14483.18 28200.56 83084.19 9032.16 2414.24 4796.4 758.74 736.26 352.78 400.74 829.96 585.05 735.09 568.57 530.62 263.24 337.33 208.35 1029.42 2318.59 2259.37 1908.1 4549.79 1576.01 1049.21 1053.21
Sample 5 1913.26 57473.9 2349.25 2370.65 93239.67 82446.37 6214.34 14169.46 2236039.05 113148.63 2229.74 5496.09 3826.8 20643.65 89818.48 5172.85 25818.57 169618.91 115676.67 2706.73 3267.02 20324.94 43485.33 106205.04 12298.24 3192.74 6390.41 969.53 945.18 506.11 542.25 1058.59 827.92 1087.41 831.46 736.74 337.75 479.26 288.53 1233.5 2952.34 4294.29 3557.98 8510.84 2007.69 1214.5 1471.61
Sample 6 2368.82 65595.7 2456.66 2850.34 114659.36 107270.14 9046.94 12716.77 2643064.98 149574.32 2839.62 5770.5 4787.67 40133.04 127436.27 5146.88 28501.36 191819.91 145483.84 3692.15 3851.29 23730.63 42168.58 132084.66 13900.29 3475.08 7053.29 1092.96 961.18 532.13 658.68 1202.71 944.2 1172.6 858.52 805.44 378.7 560.07 297.8 1467.67 3701.01 2656.65 2301.05 5218.31 2305.17 1740.53 1661.28
Sample 7 2406.58 59316.19 2378.92 2567.88 106563.96 92307.32 7199.14 10441.55 2361513.36 136794.12 2694.99 5649.28 4121.25 38905.12 120819.6 4141.06 25238.39 173387.6 135489.88 3501.74 2824.43 17815.48 39353.63 123736.82 13372.35 3406.7 6833.01 1038.59 916.18 487.51 508.87 1108.38 780.75 971.39 784.4 726.06 323.44 488.03 247.4 1378.2 3198.32 2422.1 1994.43 4931.11 2060.06 1792.84 1373.53
Sample 8 1864.48 43623.79 2172.09 2159.62 86197.66 74793.12 4537.45 8314.29 1803490.51 107417.22 1396.76 4467.66 2630.15 33601.62 95242.66 2843.64 22572.41 153222.08 112409.45 2660.71 1363.06 8602.92 34244.35 106651.36 11621.55 3005.8 6218.47 889.07 790.06 420.43 441.82 967.68 684.73 957.81 696.34 633.95 269.78 418.56 246.16 1205.83 2897.11 2149.58 1640.05 4218.19 1805.52 1384.47 993.7
BHVO2 497.21 1391698.49 55505.23 11450.18 565818.71 674284.43 325729.95 285495.79 2014370.49 377524.18 46068.17 36688.01 38233.59 27325.09 10772.9 265704.67 10394.27 35001.3 11815.65 441.39 11056.37 68171.92 6862.23 28398.12 3729.14 1199.87 2383.48 474.44 461.4 662.73 714.31 573.83 361.42 476.79 334.3 300.65 103.25 163.39 64.01 335.94 293.14 308.8 242.47 573.85 132.68 178.75 2750.66
Normalized Pk Intensities Select Stds
BHVO 1 0.01 24.51 1 0.21 10.61 11.57 5.8 5.03 36.27 6.55 0.85 0.65 0.68 0.49 0.18 4.78 0.19 0.64 0.22 0.01 0.19 1.23 0.12 0.51 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Sample 1 0.98 16.3 1 0.97 46.32 39.7 0.23 2.95 963.01 54.39 0.21 2.06 0.46 18.55 52.22 0.65 11.48 79.5 61.47 1.31 0.31 2.03 17.42 55.34 5.88 1.53 3.02 0.47 0.41 0.23 0.26 0.51 0.38 0.49 0.37 0.35 0.15 0.22 0.16 0.62 1.52 0.93 0.78 1.85 0.9 0.8 0.49
Sample 2 1.08 16.54 1 1.05 46.6 40.89 0.4 3.79 997.44 57.18 0.26 1.98 0.75 17.7 50.65 0.68 10.86 74.4 58.68 1.27 0.34 2.1 15.85 51.94 5.44 1.4 2.77 0.43 0.39 0.24 0.23 0.46 0.33 0.46 0.34 0.32 0.14 0.22 0.11 0.56 1.44 0.86 0.71 1.66 0.86 0.82 0.46
Sample 3 0.89 53.5 1 1.12 29.33 25.47 8.87 8.63 511.54 39.82 2.39 2.28 2.9 7.44 31.37 6.81 6.94 38.96 27.15 1.19 3.34 20.94 9.85 28.31 3.13 0.83 1.61 0.25 0.23 0.15 0.16 0.29 0.21 0.27 0.2 0.2 0.08 0.13 0.07 0.32 0.74 2.34 1.99 4.72 0.85 0.44 0.93
Sample 4 1.01 25.67 1 1.22 45.81 39.83 2.72 5.92 1074.21 59.97 0.99 2.79 1.94 12.69 47.52 2.13 11.89 79.88 56.28 1.54 1.4 8.82 17.18 50.61 5.5 1.47 2.92 0.46 0.45 0.21 0.24 0.51 0.36 0.45 0.35 0.32 0.16 0.21 0.13 0.63 1.41 1.38 1.16 2.77 0.96 0.64 0.64
Sample 5 0.81 24.46 1 1.01 39.69 35.09 2.65 6.03 951.81 48.16 0.95 2.34 1.63 8.79 38.23 2.2 10.99 72.2 49.24 1.15 1.39 8.65 18.51 45.21 5.23 1.36 2.72 0.41 0.4 0.22 0.23 0.45 0.35 0.46 0.35 0.31 0.14 0.2 0.12 0.53 1.26 1.83 1.51 3.62 0.85 0.52 0.63
Sample 6 0.96 26.7 1 1.16 46.67 43.67 3.68 5.18 1075.88 60.89 1.16 2.35 1.95 16.34 51.87 2.1 11.6 78.08 59.22 1.5 1.57 9.66 17.17 53.77 5.66 1.41 2.87 0.44 0.39 0.22 0.27 0.49 0.38 0.48 0.35 0.33 0.15 0.23 0.12 0.6 1.51 1.08 0.94 2.12 0.94 0.71 0.68
Sample 7 1.01 24.93 1 1.08 44.8 38.8 3.03 4.39 992.68 57.5 1.13 2.37 1.73 16.35 50.79 1.74 10.61 72.89 56.95 1.47 1.19 7.49 16.54 52.01 5.62 1.43 2.87 0.44 0.39 0.2 0.21 0.47 0.33 0.41 0.33 0.31 0.14 0.21 0.1 0.58 1.34 1.02 0.84 2.07 0.87 0.75 0.58
Sample 8 0.86 20.08 1 0.99 39.68 34.43 2.09 3.83 830.3 49.45 0.64 2.06 1.21 15.47 43.85 1.31 10.39 70.54 51.75 1.22 0.63 3.96 15.77 49.1 5.35 1.38 2.86 0.41 0.36 0.19 0.2 0.45 0.32 0.44 0.32 0.29 0.12 0.19 0.11 0.56 1.33 0.99 0.76 1.94 0.83 0.64 0.46
BHVO2 1 0.01 25.07 1 0.21 10.19 12.15 5.87 5.14 36.29 6.8 0.83 0.66 0.69 0.49 0.19 4.79 0.19 0.63 0.21 0.01 0.2 1.23 0.12 0.51 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Average Ratio (Standards) 0.01 24.79 1 0.21 10.4 11.86 5.83 5.09 36.28 6.67 0.84 0.65 0.68 0.49 0.19 4.78 0.19 0.64 0.22 0.01 0.2 1.23 0.12 0.51 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Rel. Deviation
(%)
17.27 1.62 0 0.85 2.81 3.42 0.85 1.53 0.04 2.7 1.55 1.33 1.21 0.12 3.97 0.11 0.62 1.04 2.1 2.14 2.28 0.38 0.21 0.49 1.49 3.72 0.91 0.7 8.89 1.28 8.57 0.16 3.76 7.18 2.31 8.79 5.98 2.29 28.53 0.11 5.08 1.15 8.11 1.2 19.88 1.63 1.92
Average Intensity (Standards) 512.2 1260027.78 50775.51 10531.95 527112.93 603623.69 296363.82 258629.82 1842261.94 339479.07 42565.54 33278.72 34706.58 24977.16 9611.05 242884.57 9546.4 32234.33 10956.32 398.32 9968.94 62516.08 6269.22 25896.2 3379.21 1072.11 2167.75 435.97 399.46 611.27 691.65 524.39 338.81 417.04 310.42 260.44 98.23 151.7 71.98 307.1 277.23 280.42 210.89 529.04 139.38 161.84 2547.69
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 5.16 7.15 11.43 30.99 2.67 2.56 287.27 286.66 0.17 10.86 43.47 109.96 131.86 98.91 9.53 390.68 26.52 185.36 19.79 0.1 126.99 129.42 14.77 37.13 5.34 23.61 24.09 6.03 5.62 1.98 2.08 6.34 0.98 5.12 1.02 2.34 0.34 2.07 0.36 4.46 1.24 1.6 1.52 1.62 1.34 0.42 130.82
Sample 1 0.37 14.41 0.16 0.37 4.71 0.38 0.29 0.37 5.49 0.14 2.95 0.35 11.42 2.95 122.18 88.7 1.73 52.72 753.5 181.55 0.53 6.73 6.95 68.3 132.35 15.64 57.62 56.15 10.79 10.33 1.2 1.22 10.26 1.76 10.61 1.97 5.56 0.81 4.94 1.06 14.85 10.87 8.93 9.92 9.38 12.47 3.47 41.2
Sample 2 0.33 14.03 0.14 0.33 4.48 0.34 0.26 0.57 6.19 0.13 2.72 0.38 9.61 4.2 102.24 75.44 1.59 43.73 618.23 151.93 0.45 6.37 6.31 54.47 108.91 12.69 46.13 45.2 8.72 8.61 1.11 0.94 8.05 1.37 8.72 1.58 4.51 0.67 4.36 0.68 11.83 9.07 7.19 7.96 7.36 10.47 3.1 33.76
Sample 3 0.71 24.92 0.97 0.71 10.38 0.46 0.35 27.39 30.62 0.15 4.12 7.62 24.09 35.14 93.37 101.47 34.66 60.7 703.14 152.67 0.92 137.04 136.72 73.52 128.92 15.83 59.63 56.9 10.9 11.11 1.48 1.42 11.08 1.84 10.97 2.05 6.13 0.87 5.37 0.85 14.62 10.1 42.55 48.31 45.43 22.26 3.66 149.65
Sample 4 0.3 12.1 0.2 0.3 4.79 0.31 0.23 3.57 8.93 0.13 2.64 1.35 12.55 9.99 67.71 65.38 4.62 44.23 613.15 134.6 0.5 24.51 24.51 54.54 98.03 11.84 44.87 44.01 8.56 9.12 0.93 0.93 8.24 1.35 7.82 1.5 4.18 0.72 3.71 0.7 12.26 8.2 10.65 12.01 11.35 10.75 2.24 43.68
Sample 5 0.55 17.6 0.34 0.55 7.18 0.48 0.37 6.28 16.47 0.21 3.83 2.33 19.01 15.21 84.79 95.15 8.63 73.95 1002.56 213.03 0.68 43.89 43.47 106.31 158.39 20.38 75.01 74.12 13.82 14.8 1.68 1.58 13.28 2.42 14.63 2.77 7.34 1.17 6.67 1.22 18.56 13.2 25.58 28.31 26.83 17.31 3.28 77.15
Sample 6 0.55 21.03 0.38 0.55 8.33 0.57 0.47 8.83 14.26 0.24 4.89 2.87 19.26 18.36 159.08 130.27 8.29 78.78 1094.13 258.56 0.9 49.94 48.98 99.49 190.1 22.23 78.79 78.95 15.03 14.52 1.7 1.86 14.56 2.66 15.23 2.76 7.74 1.27 7.52 1.22 21.32 15.97 15.27 17.67 15.88 19.18 4.53 84.05
Sample 7 0.4 16.15 0.26 0.4 5.67 0.4 0.3 5.31 8.85 0.16 3.38 2.06 14.25 11.95 116.56 93.36 5.04 52.73 747.55 182.01 0.64 27.68 27.79 70.18 134.61 16.17 58.38 57.81 10.8 10.46 1.18 1.08 10.15 1.66 9.53 1.91 5.28 0.82 4.95 0.76 15.13 10.43 10.53 11.58 11.34 12.95 3.53 52.53
Sample 8 0.45 15.09 0.23 0.45 5.75 0.39 0.3 4.04 8.5 0.15 3.2 1.29 13.6 9.2 121.43 88.77 4.17 56.89 796.81 182.14 0.59 16.11 16.19 73.66 139.94 16.95 62.13 63.46 11.15 10.88 1.23 1.13 10.68 1.76 11.34 2.04 5.56 0.82 5.12 0.92 15.97 11.39 11.27 11.48 11.7 13.69 3.29 45.84
BHVO2 11.43 4.04 7.31 11.43 30.61 2.57 2.68 290.73 292.94 0.17 11.28 42.53 112.04 134.14 99.09 10.07 391.32 26.28 182.64 19.21 0.1 131.15 128.72 14.81 37.39 5.46 24.89 24.41 5.97 6.38 1.94 1.84 6.36 0.93 5.66 0.98 2.64 0.32 2.01 0.24 4.46 1.16 1.62 1.7 1.6 1.01 0.43 127.32