ALS 00-143B
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 567.43 3092213.46 103581.03 21626.3 1206069.87 1176948.47 538261.65 458581.92 4221531.04 709434.61 91266.08 63770.85 78525.52 49841.17 19551.08 645743.17 20581.16 67752.57 22689.95 1406.78 22196.77 143469.46 12862.53 50718.85 7441.75 2438.8 5049.84 1060.1 975.76 1426.99 1632.88 1262.55 765.61 980.57 799.28 695.43 255.49 397.8 197.22 729.09 668.17 677.62 545.76 1277.43 290.39 331.79 6200.36
Sample 1 1663.55 614343.27 46742.86 9893.66 857077.59 929733.86 101903.12 27116.07 4802200.84 354080.48 16693.89 7259.2 5088.46 49137.66 103223.42 1071125.32 34674.86 158004.48 127499.15 3250.69 168717.93 1330637.83 56585.15 171189.11 21508.05 6230.16 12440.78 2038.85 1832.46 3020.68 3528.44 2023.31 1379.69 1604.54 1152.42 1119.42 521.13 760.13 362.81 1324.1 3858.34 1702.81 1456.97 3541.64 2057.31 1519.68 39807.35
Sample 2 1539.82 500042.04 40075.73 8224.05 649884.16 706604.67 63952.01 22318.23 3917463.22 289151.82 13055.75 7057.5 4045.65 40221.2 88647.34 935031.64 31728.91 140010.26 117037.13 2905.15 148253.07 1198058.18 52485.25 160224.42 20110.74 5936.41 11906.87 1803.99 1711.41 2834.81 3359.82 1983.9 1318.82 1401.84 1063.69 1003.83 386.14 626.58 324.89 1173.54 3183.09 1411.71 1248.77 2893.64 1720.87 1289.54 33737.61
Sample 3 1723.62 518573.89 40278.97 8595.57 681089.37 774945.37 71199.89 24501.93 4090135.87 318249.2 13777.04 7198.95 4488.68 41651.88 90579.58 940175.86 29596.57 138138.16 116483.19 2721.34 146755.8 1179154.25 49883.53 151767.98 19053.3 5334.86 10681.86 1740.67 1509.18 2707.5 3111.35 1811.39 1217.09 1414.65 1014.33 944.62 431.9 606.94 274.61 1171.34 3301.28 1486.81 1186.49 3033.55 1735.32 1353.46 34021.46
Sample 4 1448.03 442430.6 34749.09 7307.16 565192.76 659811.03 60841.85 21643.87 3581451.32 278515.33 12034.44 6529.49 3723.04 36579.48 78256.93 819707.04 25836.27 120844.79 101827.12 2579.55 127095.61 1027880.67 43290.27 131571.85 16239.64 4547.03 9498.77 1531.52 1282.1 2254.94 2722 1529.94 1046.69 1203.48 805.12 829.35 287.04 543.72 290.33 992.14 2796.62 1235.38 1066.3 2532.89 1508.25 1157.83 29922.8
Sample 5 1696.94 479975.26 38894.51 8045.85 632660.92 707137.19 66333.21 20789.74 3940893 294939.37 12747.23 6822.39 4236.28 41199.1 86031.41 895498.78 29405.13 132190.51 108920.83 2632.11 136759.76 1116480.18 49209.03 151495.37 18611.77 5374.56 10998.66 1723.18 1515.07 2663.46 3032.69 1737.78 1135.56 1386.9 998.76 932.31 360.26 574.95 300.63 1131.45 3019.29 1373.34 1107.19 2817.83 1734.61 1270.64 32962.27
Sample 6 1523.86 471890.45 36280.2 7959.62 595613.57 697159.79 74456.88 23545.11 3690932.19 299866.55 12661.51 6778.75 4636.13 42337.35 79649.87 811941.11 25193.99 117135.85 101076.22 2481.4 125590.09 1001859.23 43147.26 134669.84 16302.76 4773.57 9412.33 1513.66 1393.96 2247.72 2599.37 1600.54 970.46 1192.83 845.7 786.7 316.58 508.07 263.13 985.3 2694.64 1516.5 1190.2 2949.37 1518.38 1207.38 29175.32
Sample 7 1893.77 521304.32 39643.95 8130.11 674033.92 779577.94 79930.02 22089.69 4091262.33 327004.71 14409.42 7232.94 4209.77 44885.21 90396.81 902682.84 28081.09 128204.17 111944.67 2465.78 139600.9 1122322.45 47909.77 153525.91 18264.47 5292.17 10282.23 1712.06 1538.08 2569.39 3130.08 1680.85 1066.84 1256.3 896.67 857.22 351.71 489.16 276.49 1173.16 2969.42 1501.89 1138.46 2877.13 1558.11 1315.05 32791.56
Sample 8 1499.79 652164.04 40935.87 8421.61 581038.3 675381.04 76365.78 21585.56 4639273.22 302733.55 15430.34 7308.62 4564.43 45485.76 77182.6 615111.95 41370.73 216574.61 189441.81 2355.62 96054.68 746316.55 68048.12 204201.96 24838.76 7072.1 13949.71 2380.57 2110.49 2124.59 2466.32 2379.38 1592.56 1948.56 1390.55 1345.9 601.01 934.76 511.72 1930.11 4761.94 1207.21 900.43 2356.19 1936.85 1303.44 22618.14
BHVO2 766.59 2354787.04 85846.64 18428.49 985463.44 1013887.23 464626.18 512284.31 3386738.69 615699.88 70820.05 52625.17 60125.39 40138.32 15288.06 487015.74 16714.49 55735.5 18384.97 968.97 17459.02 110540.86 10822.56 42329.52 6214.8 1954.03 4053.87 829.44 787.28 1136.13 1308.78 993.96 690.73 795.04 584.66 564.98 216.56 312.13 155.45 542.91 537.69 472.4 376.88 972.54 221.97 246.24 4872.34
Normalized Pk Intensities Select Stds
BHVO 1 0.01 29.85 1 0.21 11.64 11.36 5.2 4.43 40.76 6.85 0.88 0.62 0.76 0.48 0.19 6.23 0.2 0.65 0.22 0.01 0.21 1.39 0.12 0.49 0.07 0.02 0.05 0.01 0.01 0.01 0.02 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0.01 0.01 0 0 0.06
Sample 1 0.04 13.14 1 0.21 18.34 19.89 2.18 0.58 102.74 7.58 0.36 0.16 0.11 1.05 2.21 22.92 0.74 3.38 2.73 0.07 3.61 28.47 1.21 3.66 0.46 0.13 0.27 0.04 0.04 0.06 0.08 0.04 0.03 0.03 0.02 0.02 0.01 0.02 0.01 0.03 0.08 0.04 0.03 0.08 0.04 0.03 0.85
Sample 2 0.04 12.48 1 0.21 16.22 17.63 1.6 0.56 97.75 7.22 0.33 0.18 0.1 1 2.21 23.33 0.79 3.49 2.92 0.07 3.7 29.89 1.31 4 0.5 0.15 0.3 0.05 0.04 0.07 0.08 0.05 0.03 0.03 0.03 0.03 0.01 0.02 0.01 0.03 0.08 0.04 0.03 0.07 0.04 0.03 0.84
Sample 3 0.04 12.87 1 0.21 16.91 19.24 1.77 0.61 101.55 7.9 0.34 0.18 0.11 1.03 2.25 23.34 0.73 3.43 2.89 0.07 3.64 29.27 1.24 3.77 0.47 0.13 0.27 0.04 0.04 0.07 0.08 0.04 0.03 0.04 0.03 0.02 0.01 0.02 0.01 0.03 0.08 0.04 0.03 0.08 0.04 0.03 0.84
Sample 4 0.04 12.73 1 0.21 16.26 18.99 1.75 0.62 103.07 8.02 0.35 0.19 0.11 1.05 2.25 23.59 0.74 3.48 2.93 0.07 3.66 29.58 1.25 3.79 0.47 0.13 0.27 0.04 0.04 0.06 0.08 0.04 0.03 0.03 0.02 0.02 0.01 0.02 0.01 0.03 0.08 0.04 0.03 0.07 0.04 0.03 0.86
Sample 5 0.04 12.34 1 0.21 16.27 18.18 1.71 0.53 101.32 7.58 0.33 0.18 0.11 1.06 2.21 23.02 0.76 3.4 2.8 0.07 3.52 28.71 1.27 3.9 0.48 0.14 0.28 0.04 0.04 0.07 0.08 0.04 0.03 0.04 0.03 0.02 0.01 0.01 0.01 0.03 0.08 0.04 0.03 0.07 0.04 0.03 0.85
Sample 6 0.04 13.01 1 0.22 16.42 19.22 2.05 0.65 101.73 8.27 0.35 0.19 0.13 1.17 2.2 22.38 0.69 3.23 2.79 0.07 3.46 27.61 1.19 3.71 0.45 0.13 0.26 0.04 0.04 0.06 0.07 0.04 0.03 0.03 0.02 0.02 0.01 0.01 0.01 0.03 0.07 0.04 0.03 0.08 0.04 0.03 0.8
Sample 7 0.05 13.15 1 0.21 17 19.66 2.02 0.56 103.2 8.25 0.36 0.18 0.11 1.13 2.28 22.77 0.71 3.23 2.82 0.06 3.52 28.31 1.21 3.87 0.46 0.13 0.26 0.04 0.04 0.06 0.08 0.04 0.03 0.03 0.02 0.02 0.01 0.01 0.01 0.03 0.07 0.04 0.03 0.07 0.04 0.03 0.83
Sample 8 0.04 15.93 1 0.21 14.19 16.5 1.87 0.53 113.33 7.4 0.38 0.18 0.11 1.11 1.89 15.03 1.01 5.29 4.63 0.06 2.35 18.23 1.66 4.99 0.61 0.17 0.34 0.06 0.05 0.05 0.06 0.06 0.04 0.05 0.03 0.03 0.01 0.02 0.01 0.05 0.12 0.03 0.02 0.06 0.05 0.03 0.55
BHVO2 1 0.01 27.43 1 0.21 11.48 11.81 5.41 5.97 39.45 7.17 0.82 0.61 0.7 0.47 0.18 5.67 0.19 0.65 0.21 0.01 0.2 1.29 0.13 0.49 0.07 0.02 0.05 0.01 0.01 0.01 0.02 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.06
Average Ratio (Standards) 0.01 28.64 1 0.21 11.56 11.59 5.3 5.2 40.1 7.01 0.85 0.61 0.73 0.47 0.18 5.95 0.2 0.65 0.22 0.01 0.21 1.34 0.13 0.49 0.07 0.02 0.05 0.01 0.01 0.01 0.02 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.06
Rel. Deviation
(%)
33.88 5.98 0 1.96 1.01 2.73 2.88 20.95 2.3 3.26 4.65 0.3 5.6 2.03 4.11 6.66 1.44 0.53 1.6 13.05 3.7 5.16 1.07 0.49 0.54 2.39 2.25 4.07 1.9 2.84 2.37 3.63 6 1.55 8.82 1.41 1.59 3.87 3.55 7.56 2.08 12.2 12.87 6 5.72 7.8 3.76
Average Intensity (Standards) 667.01 2723500.25 94713.84 20027.39 1095766.66 1095417.85 501443.91 485433.11 3804134.86 662567.25 81043.06 58198.01 69325.45 44989.74 17419.57 566379.45 18647.82 61744.03 20537.46 1187.87 19827.9 127005.16 11842.55 46524.18 6828.27 2196.42 4551.86 944.77 881.52 1281.56 1470.83 1128.26 728.17 887.81 691.97 630.21 236.02 354.97 176.34 636 602.93 575.01 461.32 1124.98 256.18 289.01 5536.35
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 3.5 7.54 11.43 30.37 2.64 2.57 283.12 246.86 0.17 10.81 44.42 111.24 138.26 100.42 10.08 409.42 26.67 184.69 19.72 0.11 132.44 133.78 14.68 37.13 5.38 24.66 24.64 6.17 6.08 2 1.99 6.51 0.92 5.45 1.06 2.51 0.33 2.1 0.31 4.7 1.22 1.75 1.76 1.68 1.22 0.44 132.51
Sample 1 5.54 11.01 1.61 5.54 14.92 2.01 2.18 57.56 15.67 0.21 5.8 8.72 13.6 9.62 106.31 57.18 729.27 48.25 462.5 118.99 0.26 1081.03 1332.32 69.34 134.57 16.7 67.65 65.18 12.75 12.26 4.54 4.62 11.21 1.78 9.57 1.64 4.35 0.71 4.3 0.61 9.16 7.55 4.72 5.04 5 9.3 2.18 913.51
Sample 2 4.65 9.99 1.28 4.65 12.15 1.5 1.62 35.39 12.64 0.17 4.64 6.68 12.95 7.49 85.25 48.1 623.66 43.25 401.49 107.01 0.23 930.58 1175.17 63.01 123.39 15.29 63.15 61.11 11.05 11.22 4.18 4.31 10.77 1.66 8.2 1.49 3.82 0.52 3.47 0.53 7.96 6.1 3.84 4.23 4 7.62 1.82 758.46
Sample 3 4.86 11.62 1.38 4.86 13.2 1.63 1.85 40.96 14.43 0.18 5.31 7.33 13.73 8.64 91.79 51.1 652 41.95 411.85 110.73 0.22 957.77 1202.57 62.26 121.52 15.06 59 57 11.09 10.29 4.15 4.15 10.22 1.6 8.6 1.47 3.74 0.6 3.5 0.47 8.26 6.58 4.2 4.18 4.36 7.99 1.98 795.22
Sample 4 4.19 9.76 1.18 4.19 11.22 1.35 1.58 34.99 12.74 0.16 4.64 6.4 12.45 7.17 80.59 44.14 568.31 36.61 360.2 96.77 0.21 829.25 1048.02 54.02 105.32 12.84 50.28 50.67 9.75 8.74 3.45 3.63 8.63 1.37 7.31 1.17 3.28 0.4 3.13 0.5 6.99 5.57 3.49 3.75 3.64 6.94 1.69 699.24
Sample 5 4.69 11.44 1.28 4.69 12.36 1.51 1.69 38.16 12.24 0.17 4.92 6.78 13.02 8.16 90.79 48.54 620.98 41.67 394.1 103.54 0.22 892.48 1138.59 61.42 121.3 14.71 59.44 58.69 10.97 10.33 4.08 4.05 9.8 1.49 8.43 1.45 3.69 0.5 3.31 0.51 7.97 6.02 3.88 3.9 4.05 7.99 1.86 770.43
Sample 6 4.16 9.77 1.2 4.16 11.62 1.36 1.58 40.72 13.18 0.15 4.75 6.41 12.3 8.49 88.7 42.72 535.32 33.95 332.02 91.35 0.19 779.24 971.4 51.2 102.52 12.25 50.19 47.75 9.16 9.03 3.27 3.3 8.59 1.21 6.89 1.17 2.96 0.42 2.78 0.43 6.6 5.11 4.07 3.99 4.03 6.65 1.68 648.34
Sample 7 4.46 11.91 1.3 4.46 11.65 1.5 1.74 42.91 12.14 0.17 5.09 7.16 12.88 7.56 92.29 47.59 584.08 37.13 356.64 99.29 0.19 850.07 1067.97 55.8 114.7 13.47 54.61 51.19 10.17 9.78 3.67 3.9 8.85 1.3 7.12 1.22 3.16 0.46 2.63 0.44 7.72 5.52 3.96 3.74 3.86 6.69 1.8 715.16
Sample 8 4.83 9.88 1.7 4.83 12.64 1.36 1.58 42.94 12.42 0.2 4.93 8.03 13.63 8.59 97.98 42.56 416.96 57.31 631.17 176.03 0.19 612.76 743.99 83.02 159.82 19.2 76.45 72.76 14.82 14.06 3.18 3.22 13.12 2.04 11.58 1.98 5.2 0.82 5.27 0.85 13.3 9.28 3.33 3.1 3.31 8.72 1.86 516.77
BHVO2 11.43 5.7 6.92 11.43 31.23 2.6 2.67 294.88 332.74 0.16 11.33 41.58 110.76 127.74 97.58 9.52 372.58 26.13 183.31 19.28 0.09 125.7 124.36 14.9 37.39 5.42 23.84 23.86 5.83 5.92 1.92 1.93 6.19 1 5.33 0.94 2.47 0.33 1.98 0.29 4.22 1.18 1.47 1.46 1.54 1.13 0.4 125.63