ALS 00-102
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 654.42 2119531.92 79778.27 16924.54 897538.53 954564 434420.47 468561.04 2916147.82 573591.39 66842.72 47423.69 55962.81 37064.13 14292.73 444501.17 15542.25 52529.59 17382.96 522.34 16482.67 102438.68 10033.08 39032.71 5464.25 1899.96 3639.14 754.32 684.32 1065.05 1140.44 882.47 588.48 808.3 505.65 479.95 182.44 274.3 143.21 538.73 466.68 473.41 352.06 897.28 232.05 214.04 4444.71
Sample 1 2887.7 133710.05 4748.06 4343.57 141925.95 127123.7 2554.14 27838.57 4514671.84 189697.12 1521.76 5937.2 7867.61 32640.72 187730.45 4904.3 64487.42 627409.57 348056.99 3868.24 4241.55 26866.88 98637.3 267819.48 31296.88 8329.64 17035.95 2524.52 2443.93 1023.61 1052.57 2964.74 2119.54 2628.6 1986.76 1864.94 962.17 1344.26 671.83 4186.03 9810.29 6725.65 5680.11 13410.57 5829.07 3465.68 2383.09
Sample 2 1410.15 46229.62 2692.02 2345.36 80559.93 71254.55 2870.31 21375.36 2147269.91 104476.5 1065.47 4536.78 4011.18 17977.15 98304.18 5072.86 33682.77 285312.49 166071.37 2303 5063.93 31028.22 51002.73 132545.01 15767.86 4374.26 8431.56 1280.27 1212.42 529.14 589.92 1525.66 1091.9 1458.05 1065.35 1094.35 522.79 724.3 422.79 2286.05 5011.68 10463.75 8875.41 21514.26 3179.4 1775.44 2077.7
Sample 3 1835.18 38728.09 2767.62 2472.98 80504.64 69807.63 748.87 14720.06 2482035.71 125049.99 714.51 4462.98 3281.65 23235.27 111955.4 4148.46 37014.13 314659.36 184558.82 2412.99 1950.79 12193.88 56247.41 149256.86 17644.23 4763.82 9385.93 1446.65 1335.62 529.81 526.57 1616.86 1132.52 1535.64 1150.99 1091.87 507.7 807.56 419.28 2427.76 5459.71 9400.64 7689.97 18652.39 3424.65 2059.22 1299.36
Sample 4 2590.99 60135.99 3694.82 3234.81 104691.42 91825.25 3937.37 13839.51 3275625.8 143697.05 2321.16 4997.63 3939.28 32325.28 147471.7 6336.51 39384.14 365070.34 228488.27 3023.25 5297.35 32726.63 62390.76 177562.92 19890.19 5105.93 10364.34 1567.57 1375.88 627.6 674.28 1748.75 1236.67 1662.52 1327.11 1250.27 562.76 834.26 438.4 2635.56 6443.21 4478.14 3536.89 8627.61 3758.38 2626.85 2214.8
Sample 5 2044.43 39932.48 2619.34 2405.13 80838.74 69701.93 1237.06 7867.52 2248726.57 110999.95 860.94 3974.94 2067.63 30672.27 119875.86 1965.6 31437.17 289076.91 182798.62 2423.84 2002.72 12873.93 50374.06 148383.47 16560.46 4326.86 8406.54 1294.07 1215.06 518.25 533.43 1405.21 1074.64 1396.47 1058.46 1065.1 451.97 720.85 399.83 2240.04 5200.01 2453.44 2065.68 4775.62 2965.03 2229.93 1265.85
Sample 6 1637.62 39086.92 2739.62 2758.1 89503.68 76671.64 1916.93 14856.22 2559681.7 118306.2 1013.72 4234.64 2405.38 24091.18 117052.95 3312.82 39134.04 327305.81 194640.04 2264.91 2168.28 13581.15 59208.08 155865.2 18222.06 4833.79 9983.2 1499.61 1406.26 556.82 589.08 1758.23 1227.16 1661.51 1365.44 1224.49 521.39 870.91 440.34 2518.02 5846.48 5813.29 4844.28 11340.04 3736.22 2141.72 1314.72
Sample 7 2445.54 71066.74 3704.77 3887.27 98366.92 84584.31 5893.18 25634.97 2834688.39 129947.33 2248.24 5261.7 3833.98 22538.62 122714.75 7773.05 47532.88 420623.87 207634.57 2894.42 4442.15 27449.52 69253.84 170246.4 20821.64 5751.11 11375.42 1730.35 1624.36 646.67 753.89 2164.05 1479.01 1943.6 1524.66 1439.55 639.64 1000.49 578.03 3106.04 6385.14 13168 11013.03 26654.19 4560.07 2076.55 1869.56
Sample 8 2327.74 57385.36 3842.11 4452.36 116803.22 101328.05 2280.04 19570.35 3557469.22 148812.14 1101.12 5731.4 2634.19 31268.68 152200.83 5032.12 54451.97 510127.81 270417.88 3055.54 3921.61 23480.62 82194.1 214326.87 25513.71 6893.63 13687.02 2110.47 1861.57 798.28 860.18 2366.83 1769.05 2227.55 1664.66 1713.46 789.78 1100.42 665.34 3429.43 7860.54 7978.36 6441.13 15749.31 5050.32 2690.97 2008.92
BHVO2 806.14 2055084.36 74465.62 15524.85 807636.98 881026.65 426263.74 433797.11 2866600.55 528638.48 61864.38 45459.98 51271.49 35746.83 13903.8 386080.64 14026.85 47700.68 15899.98 696 15003.43 95703.99 9070.44 36938.78 5080.06 1644.95 3260.09 708.35 604.07 955.56 1033.78 821.24 484.26 658.38 474.17 368.89 136.89 253.72 113.97 496.09 441.17 404.73 356.89 783.83 189.72 222 4215.52
Normalized Pk Intensities Select Stds
BHVO 1 0.01 26.57 1 0.21 11.25 11.97 5.45 5.87 36.55 7.19 0.84 0.59 0.7 0.46 0.18 5.57 0.19 0.66 0.22 0.01 0.21 1.28 0.13 0.49 0.07 0.02 0.05 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.06
Sample 1 0.61 28.16 1 0.91 29.89 26.77 0.54 5.86 950.85 39.95 0.32 1.25 1.66 6.87 39.54 1.03 13.58 132.14 73.31 0.81 0.89 5.66 20.77 56.41 6.59 1.75 3.59 0.53 0.51 0.22 0.22 0.62 0.45 0.55 0.42 0.39 0.2 0.28 0.14 0.88 2.07 1.42 1.2 2.82 1.23 0.73 0.5
Sample 2 0.52 17.17 1 0.87 29.93 26.47 1.07 7.94 797.64 38.81 0.4 1.69 1.49 6.68 36.52 1.88 12.51 105.98 61.69 0.86 1.88 11.53 18.95 49.24 5.86 1.62 3.13 0.48 0.45 0.2 0.22 0.57 0.41 0.54 0.4 0.41 0.19 0.27 0.16 0.85 1.86 3.89 3.3 7.99 1.18 0.66 0.77
Sample 3 0.66 13.99 1 0.89 29.09 25.22 0.27 5.32 896.81 45.18 0.26 1.61 1.19 8.4 40.45 1.5 13.37 113.69 66.69 0.87 0.7 4.41 20.32 53.93 6.38 1.72 3.39 0.52 0.48 0.19 0.19 0.58 0.41 0.55 0.42 0.39 0.18 0.29 0.15 0.88 1.97 3.4 2.78 6.74 1.24 0.74 0.47
Sample 4 0.7 16.28 1 0.88 28.33 24.85 1.07 3.75 886.55 38.89 0.63 1.35 1.07 8.75 39.91 1.71 10.66 98.81 61.84 0.82 1.43 8.86 16.89 48.06 5.38 1.38 2.81 0.42 0.37 0.17 0.18 0.47 0.33 0.45 0.36 0.34 0.15 0.23 0.12 0.71 1.74 1.21 0.96 2.34 1.02 0.71 0.6
Sample 5 0.78 15.25 1 0.92 30.86 26.61 0.47 3 858.51 42.38 0.33 1.52 0.79 11.71 45.77 0.75 12 110.36 69.79 0.93 0.76 4.91 19.23 56.65 6.32 1.65 3.21 0.49 0.46 0.2 0.2 0.54 0.41 0.53 0.4 0.41 0.17 0.28 0.15 0.86 1.99 0.94 0.79 1.82 1.13 0.85 0.48
Sample 6 0.6 14.27 1 1.01 32.67 27.99 0.7 5.42 934.32 43.18 0.37 1.55 0.88 8.79 42.73 1.21 14.28 119.47 71.05 0.83 0.79 4.96 21.61 56.89 6.65 1.76 3.64 0.55 0.51 0.2 0.22 0.64 0.45 0.61 0.5 0.45 0.19 0.32 0.16 0.92 2.13 2.12 1.77 4.14 1.36 0.78 0.48
Sample 7 0.66 19.18 1 1.05 26.55 22.83 1.59 6.92 765.15 35.08 0.61 1.42 1.03 6.08 33.12 2.1 12.83 113.54 56.05 0.78 1.2 7.41 18.69 45.95 5.62 1.55 3.07 0.47 0.44 0.17 0.2 0.58 0.4 0.52 0.41 0.39 0.17 0.27 0.16 0.84 1.72 3.55 2.97 7.19 1.23 0.56 0.5
Sample 8 0.61 14.94 1 1.16 30.4 26.37 0.59 5.09 925.92 38.73 0.29 1.49 0.69 8.14 39.61 1.31 14.17 132.77 70.38 0.8 1.02 6.11 21.39 55.78 6.64 1.79 3.56 0.55 0.48 0.21 0.22 0.62 0.46 0.58 0.43 0.45 0.21 0.29 0.17 0.89 2.05 2.08 1.68 4.1 1.31 0.7 0.52
BHVO2 1 0.01 27.6 1 0.21 10.85 11.83 5.72 5.83 38.5 7.1 0.83 0.61 0.69 0.48 0.19 5.18 0.19 0.64 0.21 0.01 0.2 1.29 0.12 0.5 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.06
Average Ratio (Standards) 0.01 27.08 1 0.21 11.05 11.9 5.58 5.85 37.52 7.14 0.83 0.6 0.7 0.47 0.18 5.38 0.19 0.65 0.22 0.01 0.2 1.28 0.12 0.49 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.06
Rel. Deviation
(%)
19.49 2.69 0 1.23 2.59 0.8 3.53 0.58 3.66 0.9 0.6 1.88 1.32 2.31 2.92 5.09 2.38 1.95 1.43 24.91 1.78 0.06 2.26 0.97 0.28 5.32 2.9 0.43 3.95 2.8 2.07 0.21 8.9 9.62 0.33 13.69 15.38 0.64 11.25 0.96 0.9 6.21 5.83 4.68 9.35 7.45 1.13
Average Intensity (Standards) 730.28 2087308.14 77121.95 16224.7 852587.75 917795.33 430342.11 451179.08 2891374.18 551114.94 64353.55 46441.84 53617.15 36405.48 14098.27 415290.91 14784.55 50115.14 16641.47 609.17 15743.05 99071.33 9551.76 37985.74 5272.15 1772.45 3449.61 731.33 644.19 1010.3 1087.11 851.86 536.37 733.34 489.91 424.42 159.66 264.01 128.59 517.41 453.92 439.07 354.47 840.55 210.89 218.02 4330.12
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 3.97 7.09 11.43 31.07 2.67 2.63 281.78 290.98 0.16 11.14 43.18 109.52 134.24 97.38 9.6 405.07 26.84 186.53 19.7 0.08 130.69 129.01 15.03 37 5.41 25.16 24.75 5.98 6.17 2 1.99 6.36 1.02 5.76 1 2.73 0.37 2.05 0.32 4.49 1.19 1.68 1.54 1.66 1.25 0.4 128.04
Sample 1 0.31 8.09 0.21 0.31 3.69 0.2 0.16 0.77 7.99 0.12 1.7 0.45 6.34 8.73 39.66 58.29 2.07 51.51 1030.24 182.38 0.27 15.55 15.65 68.31 117.41 14.33 51.01 53.57 9.26 10.19 0.89 0.85 9.88 1.7 8.66 1.81 4.91 0.89 4.64 0.7 16.13 11.59 11.05 11.52 11.5 14.55 2.98 31.75
Sample 2 0.24 5.23 0.09 0.24 2.64 0.15 0.12 1.14 8.12 0.07 1.24 0.42 6.41 5.89 28.91 40.4 2.83 35.61 620.1 115.18 0.21 24.58 23.92 46.75 76.91 9.56 35.46 35.09 6.21 6.69 0.61 0.63 6.73 1.16 6.36 1.29 3.81 0.64 3.31 0.59 11.66 7.84 22.75 23.83 24.43 10.51 2.02 36.63
Sample 3 0.27 7.55 0.09 0.27 3.08 0.16 0.13 0.33 6.21 0.09 1.65 0.31 7 5.34 41.44 51.03 2.57 43.4 758.46 141.96 0.25 10.5 10.42 57.18 96.05 11.86 42.82 43.33 7.79 8.17 0.67 0.62 7.91 1.33 7.42 1.54 4.22 0.69 4.1 0.64 13.74 9.47 22.67 22.9 23.49 12.55 2.6 25.41
Sample 4 0.54 16.14 0.21 0.54 6.1 0.32 0.26 2.62 8.83 0.19 2.87 1.54 11.86 9.71 87.28 101.77 5.93 69.91 1332.23 266.08 0.47 43.16 42.36 96.03 172.99 20.24 69.49 72.43 12.78 12.74 1.21 1.21 12.95 2.2 12.17 2.69 7.31 1.16 6.41 1.02 22.57 16.92 16.35 15.95 16.45 20.85 5.03 65.57
Sample 5 0.39 12.87 0.14 0.39 4.59 0.25 0.2 0.83 5.08 0.13 2.24 0.58 9.54 5.15 83.71 83.62 1.86 56.4 1066.31 215.17 0.38 16.5 16.84 78.37 146.12 17.03 59.52 59.39 10.66 11.38 1.01 0.97 10.52 1.93 10.33 2.17 6.3 0.94 5.59 0.94 19.39 13.8 9.05 9.41 9.2 16.63 4.31 37.88
Sample 6 0.37 9.24 0.12 0.37 4.71 0.25 0.2 1.16 8.59 0.13 2.14 0.61 9.1 5.37 58.92 73.16 2.81 62.92 1081.85 205.3 0.32 16 15.92 82.54 137.54 16.8 59.59 63.19 11.07 11.8 0.97 0.96 11.79 1.98 11.01 2.51 6.49 0.97 6.06 0.93 19.54 13.9 19.22 19.78 19.58 18.77 3.71 35.25
Sample 7 0.3 8.5 0.14 0.3 4.09 0.17 0.13 2.19 9.13 0.09 1.45 0.83 6.97 5.28 33.97 47.27 4.06 47.1 856.83 134.97 0.25 20.21 19.83 59.5 92.59 11.83 43.69 44.38 7.87 8.4 0.7 0.75 8.95 1.47 7.94 1.73 4.7 0.74 4.29 0.75 14.85 9.36 26.83 27.72 28.36 14.12 2.22 30.9
Sample 8 0.37 9.51 0.13 0.37 5.51 0.23 0.19 1 8.19 0.13 1.95 0.48 8.92 4.26 55.37 68.89 3.09 63.39 1220.98 206.54 0.31 20.96 19.93 82.97 136.95 17.03 61.54 62.74 11.28 11.31 1.01 1.01 11.5 2.06 10.69 2.21 6.57 1.07 5.54 1.01 19.27 13.54 19.1 19.05 19.69 18.38 3.38 39.01
BHVO2 11.43 5.23 7.37 11.43 30.53 2.57 2.61 296.22 288.62 0.17 11 42.82 112.48 131.76 100.62 10 376.93 25.96 181.47 19.3 0.11 127.45 129.13 14.55 37.52 5.39 23.34 23.75 6.02 5.83 1.92 1.93 6.34 0.9 5.02 1 2.25 0.29 2.03 0.28 4.43 1.21 1.54 1.68 1.56 1.1 0.44 130.1