ALS 00-100
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Li MgO% CaO% Sc TiO2% TiO2% V Cr MnO% FeO*% Co Ni Cu Zn Rb Sr Y Zr Nb Cs Ba Ba La Ce Pr Nd Nd Sm Sm Eu Eu Gd(Dy) Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Pb Pb Th U Ba
Pk - Bg Intensities
BHVO 516.5 1562715.81 60419.48 12630.9 627720.48 731195.07 351770 329334.97 2344404.2 403901.09 51303.26 37298.26 42097.93 29026.55 11098.13 284977.46 11230.27 37783.44 12803.48 367 11378.83 73556.39 7205.6 30245.98 3901.74 1242.01 2714.27 557.79 482.32 715 790.8 609.43 380.66 494.1 313.06 287.89 124.48 164.37 98.02 314.02 334.64 301.29 249.33 658.49 130.34 174.83 3193.57
Sample 1 1794.3 311420.2 21682.45 4655.89 381256.67 358787.46 78041.33 19660.94 1707023.78 169052.18 13655.67 7716.01 11524.77 24526.14 78071.52 299815.42 13939.96 94695.13 55242.15 2480.22 59042.14 434110.42 23415.07 70508.06 7925.29 2130.44 4258.87 630.97 612.64 807.89 896.71 683.83 395.48 564.54 390.96 383.58 189.05 239.05 150 622.16 1434.14 1866.61 1513.68 3777.55 1114.34 842.42 13989.71
Sample 2 1991.08 38412.11 3849.35 3017.6 155463.99 133294.48 1625.28 7533.6 2477334.38 147396.78 603.93 4416.24 896.65 43231.35 96308.34 771.23 25544.37 160495.89 130682.55 1619.24 1542.38 9508.23 37136.68 117141.25 12543.76 3318.1 6736.46 1080.45 907.29 574.53 630.71 1082.7 818.85 1130.54 778.85 768.75 343.53 512.07 289.32 1173 3185.51 1660.72 1327.43 3315.86 1693.65 1520.11 1155.96
Sample 3 4062.76 112103.04 4520.03 3908.93 141281.39 123383.6 11061.31 20682 3349720.29 174028.71 3847.88 6364.74 10128.7 41502.96 153586.6 14336.15 47383.51 299807.34 193127.27 4913.51 8355.41 51363.31 70197.84 193655.55 22001.36 5805.06 11980.1 1842 1657.28 890.51 1031.07 2002.61 1387.6 1878.16 1505.4 1438.31 619.23 929.73 479.98 2283.33 5399.45 8089.27 6723.77 15990 3784.26 2167.55 2936.91
Sample 4 4192.45 238598.77 4179.77 5563.64 162028.54 132276.8 36031.68 48779.32 2718632.37 182373.08 10358.53 9896.61 24133.57 28983.31 138750.86 33090.92 38738.81 222088.43 134051.84 7063.21 20653.97 130505.3 54674.78 137390 16959.04 4511.53 9084.91 1397.34 1393.72 708.96 838.61 1546.97 1114.3 1447.81 1184.51 1055.58 492.18 771.47 415.53 1782.22 4178.54 18961.07 16189.62 39598.11 3339.83 1520.49 6240.64
Sample 5 2307.55 288379.13 17304.96 5038.55 316078.04 293632.77 73205.14 26016.16 1579721.11 161706.93 12608.01 8040.96 14051.64 22476.63 94766.25 231721.83 17764.27 89742.48 58963.52 3590.34 58891 424228.63 29315.1 89145.93 9786.83 2537.13 5315.37 860.66 793.69 840.51 1061.58 844.7 551.9 707.67 531.37 479.36 206.09 316.47 157.17 724.2 1524.8 2627.06 2176.95 5123.09 1528.43 965.46 12859.8
Sample 6 4263.15 161827.35 5845.78 5735.68 190651.61 164426.97 18788.27 37894.03 4162421.62 218965.73 4928.67 7724.14 12771.86 32375.38 167214.19 26254.76 70524.93 504972.02 262904.56 7076.02 14344.78 90014.67 103222.46 258828.46 30277.22 8299.08 16769.14 2622.87 2460.28 1213.39 1515.75 2994.22 2115.41 2745.72 2062.05 2064.97 943.84 1340.79 777.74 3361.77 7034.93 16875.37 13927.38 33042.3 5364.42 2188.94 4733.15
Sample 7 3860.37 77917.1 4834.43 3528.94 166575.76 146517.71 1891.53 10987.1 4257131.45 194331.59 1702.97 5013.35 2884.61 55954.87 180401.75 8497.58 46605.08 322367.6 239960.76 4615.47 2296.12 14055.3 71686.63 223236.97 24088.7 6088.36 12275.66 1890.5 1692.7 899.32 1044.19 2009.9 1417.58 1816.43 1429.65 1372.5 617.95 904.12 481.61 2431.04 5853.43 4042.99 3476.28 8166.51 3385.56 2797.27 1734.23
Sample 8 3862.61 78854.32 5117.31 3702.2 172438.47 149697.98 1356.02 11084.32 4161237.47 197649.87 1421.8 5066.31 2555.41 63163.93 187175.38 8330.14 47403.22 325085.42 264096.79 4945.36 2019.19 12907.32 77641.08 246435.46 26161.7 6585.49 13419.01 2049.11 1826.43 949.56 1047.91 2194.81 1552.59 2006.1 1375.81 1425.37 625.9 949.44 504.31 2556.19 6718.64 4718.07 3787.65 8985.25 3834.33 3072.25 1525.29
BHVO2 527.95 1517673.69 58651.58 12344.7 615691.98 718920.25 346189.08 314954.37 2097703.69 429119.46 49487.76 38039.91 40927.66 28348.82 11083.15 284745.92 11092.59 37648.02 12861.24 445.84 11871.26 73035.29 7347.95 29473.31 3899.83 1267.5 2538.45 564.12 493.38 709.76 812.2 556.2 374.79 506.5 323.66 304.27 121.02 166.47 94.36 380.62 340.82 321.02 249.51 612.56 155.96 188.89 3008.68
Normalized Pk Intensities Select Stds
BHVO 1 0.01 25.86 1 0.21 10.39 12.1 5.82 5.45 38.8 6.68 0.85 0.62 0.7 0.48 0.18 4.72 0.19 0.63 0.21 0.01 0.19 1.22 0.12 0.5 0.06 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0 0 0.01 0 0 0.05
Sample 1 0.08 14.36 1 0.21 17.58 16.55 3.6 0.91 78.73 7.8 0.63 0.36 0.53 1.13 3.6 13.83 0.64 4.37 2.55 0.11 2.72 20.02 1.08 3.25 0.37 0.1 0.2 0.03 0.03 0.04 0.04 0.03 0.02 0.03 0.02 0.02 0.01 0.01 0.01 0.03 0.07 0.09 0.07 0.17 0.05 0.04 0.65
Sample 2 0.52 9.98 1 0.78 40.39 34.63 0.42 1.96 643.57 38.29 0.16 1.15 0.23 11.23 25.02 0.2 6.64 41.69 33.95 0.42 0.4 2.47 9.65 30.43 3.26 0.86 1.75 0.28 0.24 0.15 0.16 0.28 0.21 0.29 0.2 0.2 0.09 0.13 0.08 0.3 0.83 0.43 0.34 0.86 0.44 0.39 0.3
Sample 3 0.9 24.8 1 0.86 31.26 27.3 2.45 4.58 741.08 38.5 0.85 1.41 2.24 9.18 33.98 3.17 10.48 66.33 42.73 1.09 1.85 11.36 15.53 42.84 4.87 1.28 2.65 0.41 0.37 0.2 0.23 0.44 0.31 0.42 0.33 0.32 0.14 0.21 0.11 0.51 1.19 1.79 1.49 3.54 0.84 0.48 0.65
Sample 4 1 57.08 1 1.33 38.76 31.65 8.62 11.67 650.43 43.63 2.48 2.37 5.77 6.93 33.2 7.92 9.27 53.13 32.07 1.69 4.94 31.22 13.08 32.87 4.06 1.08 2.17 0.33 0.33 0.17 0.2 0.37 0.27 0.35 0.28 0.25 0.12 0.18 0.1 0.43 1 4.54 3.87 9.47 0.8 0.36 1.49
Sample 5 0.13 16.66 1 0.29 18.27 16.97 4.23 1.5 91.29 9.34 0.73 0.46 0.81 1.3 5.48 13.39 1.03 5.19 3.41 0.21 3.4 24.51 1.69 5.15 0.57 0.15 0.31 0.05 0.05 0.05 0.06 0.05 0.03 0.04 0.03 0.03 0.01 0.02 0.01 0.04 0.09 0.15 0.13 0.3 0.09 0.06 0.74
Sample 6 0.73 27.68 1 0.98 32.61 28.13 3.21 6.48 712.04 37.46 0.84 1.32 2.18 5.54 28.6 4.49 12.06 86.38 44.97 1.21 2.45 15.4 17.66 44.28 5.18 1.42 2.87 0.45 0.42 0.21 0.26 0.51 0.36 0.47 0.35 0.35 0.16 0.23 0.13 0.58 1.2 2.89 2.38 5.65 0.92 0.37 0.81
Sample 7 0.8 16.12 1 0.73 34.46 30.31 0.39 2.27 880.59 40.2 0.35 1.04 0.6 11.57 37.32 1.76 9.64 66.68 49.64 0.95 0.47 2.91 14.83 46.18 4.98 1.26 2.54 0.39 0.35 0.19 0.22 0.42 0.29 0.38 0.3 0.28 0.13 0.19 0.1 0.5 1.21 0.84 0.72 1.69 0.7 0.58 0.36
Sample 8 0.75 15.41 1 0.72 33.7 29.25 0.26 2.17 813.17 38.62 0.28 0.99 0.5 12.34 36.58 1.63 9.26 63.53 51.61 0.97 0.39 2.52 15.17 48.16 5.11 1.29 2.62 0.4 0.36 0.19 0.2 0.43 0.3 0.39 0.27 0.28 0.12 0.19 0.1 0.5 1.31 0.92 0.74 1.76 0.75 0.6 0.3
BHVO2 1 0.01 25.88 1 0.21 10.5 12.26 5.9 5.37 35.77 7.32 0.84 0.65 0.7 0.48 0.19 4.85 0.19 0.64 0.22 0.01 0.2 1.25 0.13 0.5 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Average Ratio (Standards) 0.01 25.87 1 0.21 10.44 12.18 5.86 5.41 37.28 7 0.85 0.63 0.7 0.48 0.19 4.79 0.19 0.63 0.22 0.01 0.2 1.23 0.12 0.5 0.07 0.02 0.04 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0.01 0.01 0.01 0 0.01 0 0 0.05
Rel. Deviation
(%)
3.65 0.03 0 0.48 0.73 0.9 0.97 1.06 5.76 6.38 0.45 3.49 0.11 0.43 2 2.04 1.23 1.85 2.42 15.79 5.09 1.6 3.48 0.27 2.07 3.54 2.64 2.9 3.7 1.58 3.99 4.36 1 3.85 4.45 6.01 0.11 3 0.59 15.64 3.39 6.58 2.15 3.01 14.73 7.56 2.12
Average Intensity (Standards) 522.22 1540194.75 59535.53 12487.8 621706.23 725057.66 348979.54 322144.67 2221053.94 416510.27 50395.51 37669.08 41512.8 28687.69 11090.64 284861.69 11161.43 37715.73 12832.36 406.42 11625.05 73295.84 7276.78 29859.65 3900.79 1254.76 2626.36 560.96 487.85 712.38 801.5 582.82 377.72 500.3 318.36 296.08 122.75 165.42 96.19 347.32 337.73 311.16 249.42 635.52 143.15 181.86 3101.12
7 26 43 45 47 49 51 52 55 58 59 60 65 66 85 88 89 90 93 133 137 138 139 140 141 145 146 147 149 151 153 160 159 163 165 166 169 172 175 178 181 206 207 208 232 238 137
Calibration Standard BHVO-2g 4.6 7.23 11.43 30.8 2.62 2.62 289 289.8 0.17 11.07 43 111 133 99 9.8 391 26.4 184 19.5 0.1 129.07 129.07 14.79 37.26 5.4 24.25 24.25 6 6 1.96 1.96 6.35 0.96 5.39 1 2.49 0.33 2.04 0.3 4.46 1.2 1.61 1.61 1.61 1.18 0.42 129.07
Final Concentrations Replicate
Samples
M043 Conc.
BHVO 11.43 4.48 7.23 11.43 30.7 2.61 2.6 287.02 291.97 0.17 10.57 43.14 108.26 132.9 98.7 9.66 385.35 26.17 181.6 19.17 0.09 124.42 127.61 14.43 37.19 5.32 23.64 24.7 5.88 5.84 1.94 1.9 6.55 0.95 5.24 0.97 2.38 0.33 2 0.3 3.97 1.17 1.54 1.59 1.65 1.05 0.4 131
Sample 1 3.01 11.41 1.06 3.01 8.3 1.16 0.94 46.68 12.78 0.09 3.24 8.42 16.42 26.67 61.14 49.82 297.22 23.82 333.67 60.63 0.43 473.3 552.14 34.37 63.56 7.92 29.73 28.41 4.87 5.44 1.61 1.58 5.38 0.72 4.39 0.89 2.33 0.37 2.13 0.34 5.76 3.68 6.98 7.06 6.92 6.6 1.41 420.71
Sample 2 0.44 10.34 0.11 0.44 4.39 0.39 0.28 0.79 4 0.11 2.31 0.3 7.67 1.69 88 50.19 0.62 35.63 461.77 117.11 0.23 10.1 9.87 44.51 86.22 10.24 37.81 36.7 6.81 6.58 0.93 0.91 6.96 1.22 7.18 1.44 3.81 0.54 3.72 0.53 8.87 6.67 5.07 5.06 4.96 8.19 2.07 28.39
Sample 3 0.86 35.28 0.52 0.86 9.51 0.59 0.44 9.03 18.35 0.25 4.56 3.24 18.49 32.01 141.26 133.83 19.4 110.53 1442.35 289.39 1.15 91.45 89.2 140.67 238.34 30.03 110.62 109.13 19.43 20.1 2.42 2.49 21.53 3.47 19.95 4.66 11.92 1.64 11.31 1.48 28.87 18.92 41.28 42.82 39.99 30.59 4.94 120.59
Sample 4 0.8 36.91 1.12 0.8 13.72 0.68 0.48 29.83 43.88 0.2 4.84 8.84 29.15 77.3 99.99 122.55 45.4 91.6 1083.03 203.61 1.68 229.14 229.72 111.06 171.4 23.47 87.14 83.89 14.94 17.13 1.95 2.05 16.86 2.83 15.59 3.72 8.87 1.32 9.51 1.3 22.84 14.84 98.08 104.52 100.39 27.36 3.51 259.74
Sample 5 3.32 20.32 1.35 3.32 12.43 1.33 1.06 60.61 23.4 0.12 4.29 10.76 23.68 45.02 77.56 83.71 317.97 42.01 437.7 89.57 0.85 653.46 746.87 59.56 111.23 13.54 49.01 49.09 9.2 9.76 2.31 2.59 9.21 1.4 7.62 1.67 4.03 0.55 3.9 0.49 9.28 5.42 13.59 14.06 12.99 12.52 2.23 535.31
Sample 6 1.12 37.53 0.76 1.12 14.14 0.8 0.59 15.56 34.09 0.31 5.82 4.21 22.75 40.91 111.71 147.71 36.03 166.77 2462.81 399.36 1.68 159.16 158.47 209.7 322.93 41.9 160.31 154.86 28.04 30.24 3.34 3.7 32.63 5.36 29.57 6.47 17.35 2.54 16.53 2.43 43.09 24.98 87.3 89.93 83.78 43.96 5.06 197.02
Sample 7 0.93 33.94 0.37 0.93 8.69 0.7 0.53 1.56 9.87 0.32 5.15 1.45 14.74 9.23 192.79 159.13 11.64 110.05 1569.95 363.98 1.09 25.44 24.71 145.42 278.12 33.29 117.44 113.2 20.18 20.78 2.47 2.55 21.87 3.59 19.53 4.48 11.52 1.66 11.13 1.5 31.12 20.76 20.89 22.41 20.68 27.7 6.46 72.08
Sample 8 0.95 33.06 0.36 0.95 8.87 0.71 0.53 1.09 9.69 0.3 5.1 1.18 14.5 7.96 211.84 160.71 11.11 108.96 1541.09 389.94 1.14 21.78 22.09 153.31 298.86 35.19 123.65 120.45 21.29 21.82 2.54 2.49 23.25 3.83 21 4.2 11.64 1.64 11.38 1.53 31.85 23.19 23.72 23.77 22.14 30.54 6.9 61.71
BHVO2 11.43 4.72 7.23 11.43 30.9 2.63 2.64 290.98 287.63 0.16 11.57 42.86 113.74 133.1 99.3 9.94 396.65 26.63 186.4 19.83 0.11 133.72 130.53 15.15 37.33 5.48 24.86 23.8 6.12 6.16 1.98 2.02 6.15 0.96 5.54 1.03 2.6 0.33 2.08 0.3 4.95 1.23 1.69 1.64 1.58 1.3 0.44 127.14